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Stabilisation and functional enhancement of a metal-organic framework purinate-glass composite

14 March 2025, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

The development of metal-organic framework (MOF) crystal-glass composites (CGCs) has been hindered by the scarcity of MOF glass matrices with low glass transition temperatures (Tgs). Here, we investigate a CGC consisting of a low-Tg MOF glass, (agZIF-UC-7) and UiO-66. Powder X-ray diffraction and stability tests in phosphate buffer saline solution showed UiO-66 was stabilised in the glass matrix. Additionally, the composite exhibited enhanced dye uptake and gas adsorption relative to agZIF-UC-7.

Keywords

MOF-glass composites
MOF composites
ZIF-glasses

Supplementary materials

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Supplementary Information includes details of scanning electron microscopy, pH stability tests, DSC, PXRD, PDF, FTIR, TGA, gas sorption isotherms and UV-vis.
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Version History

Mar 14, 2025 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2025-7bfzh
D O I: 10.26434/chemrxiv-2025-7bfzh [opens in a new tab]

Funding

Leverhulme Trust
RPG-2020-005
Diamond Light Source
CY29957
r

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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