Abstract
Plastic waste is a global challenge, with polystyrene (PS) among the least recycled polymers despite its widespread use in laboratories. Conventional recycling routes for PS remain economically and technically limited, creating an urgent need for accessible, sustainable alternatives. Here, we introduce RECOMPENSE, a student-led open science initiative designed to upcycle PS waste into polystyrene sulfonic acid (u-PSSA), a heterogeneous catalyst for green organic synthesis. Developed through MSc research projects at UCL, RECOMPENSE combines technical innovation with educational engagement, offering detailed protocols and video resources freely available online. We report a reproducible method for sulfonating expanded PS under simple laboratory conditions, yielding u-PSSA with up to 45% sulfonation. Its catalytic performance was validated in Friedel–Crafts reactions using biobased substrates, achieving quantitative yields of a biofuel precursor under mild conditions. Comparative studies with commercial PSSA confirmed the viability of waste-derived catalysts, while additional tests with aromatic aldehydes demonstrated broad applicability. Beyond experimental results, RECOMPENSE exemplifies co-creation in sustainable chemistry education. By involving students in research and resource development, the project fosters practical skills, systems thinking, and global collaboration. demonstrating how academic labs can transform plastic waste into valuable resources while preparing future scientists to lead sustainability transitions.
Supplementary materials
Title
Supplementary Information
Description
Supplementary information: general procedures, full characterization of both the catalyst and the synthesized compounds. General procedures and video recorded protocols are also freely available on the RECOMPENSE project website: https://recompenseproject.com/ and YouTube channel: https://www.youtube.com/@RECOMPENSEproject
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Title
The RECOMPENSE project
Description
RECOMPENSE stands for REcyclable Catalysts frOM PolystyrENe waStE. The RECOMPENSE project is co-created with chemistry students at UCL and is funded by an RSC Sustainable Laboratories Grant.
The RECOMPENSE project addresses the challenge of recycling polystyrene (PS) waste generated in laboratories, which contributes significantly to global plastic pollution. With only 1% of PS being recycled, the project aims to develop accessible and affordable protocols to upcycle PS into polystyrene sulfonic acid (PSSA) resins for reuse as catalysts in organic synthesis.
Key actions of the RECOMPENSE project include:
-Optimising sulfonation processes to obtain PSSA from waste PS
-Testing PSSA’s catalytic efficiency in Organic Synthesis
Creating a database of applications of PSSA in the literature.
-Sharing findings through this Open Science platform and our YouTube channel
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