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Abstract
A method of C-H functionalization of the N-protected alkyl 1,2,3-triazole-4-carboxylates with various C-, P- and S-electrophiles using an in situ generated turbo-Hauser base, has been developed. The resulting compounds underwent N- and O-deprotection giving rise to the corresponding NH-5-substituted 1,2,3-triazole-4-carboxylates, which possess multiple sites for further functionalization.
Supplementary materials
Title
SUPPLEMENTARY_INFORMATION_1_Experimental_Section
Description
Experimental section, containing the procedures for synthesized compounds and their characteristics.
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Title
SUPPLEMENTARY_INFORMATION_2_NMR_spectra_of_compounds
Description
Copies of 1H and 13C NMR spectra of the synthesized compounds.
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