How to Submit
Browse
Events
Communities
About

2,6-Bis[[bis(1,1-dimethylethyl)phosphino-κP]methyl]phenyl-κC]chlorohydro(phenylphosphine)iridium

26 May 2022, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

The molecular structure of an iridium complex featuring a phenylphosphine ligand is described. Reaction of (POCOP)IrHCl (1, POCOP = 2,6-(tBu2PO)2C6H3–) with phenylphosphine gives (POC-OP)IrHCl(PH2Ph) (2) under mild conditions. Structural features are consistent with a classic pseudo-octahedral iridium compound with three neutral phosphine donors. Compound 1 is un-reactive at elevated temperature and unreactive toward excess phenylphosphine under condi-tions sampled.

Supplementary materials

Title
Description
Actions
Title
Supporting information
Description
spectra and label scheme
Actions
Title
Checkcif report
Description
IUCr report on uploaded data
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting and Discussion Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III) [opens in a new tab]
Neil T. Mucha, Rory Waterman journal article
Molbank , Volume 2022, Issue 2
Online publication date: Jun 17, 2022

Version History

May 26, 2022 Version 1

Metrics

851
277
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-zzfqs
D O I: 10.26434/chemrxiv-2022-zzfqs [opens in a new tab]

Funding

National Science Foundation
CHE-2101766
National Science Foundation
CHE-1565658

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share