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Synthesis and Structural Insights into Homoleptic and Heteroleptic Cationic Germylene Gold(I) Complexes

16 December 2024, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Novel homoleptic and heteroleptic cationic germylene-gold(I) complexes were synthesized through the insertion of dialkyl- and acyclic diamino- germylenes into Au-Cl bonds. Structural characterization and DFT calculations revealed the distinct π-back donation and dihedral angles, providing quantitative insights into the stability of germylene ligands in gold(I) complexes and expanding the boundaries of coordination chemistry.

Keywords

Germylene
Gold Complexes
Electron-donating Ability

Supplementary materials

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Description
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Title
Synthesis and Structural Insights into Homoleptic and Heteroleptic Cationic Germylene Gold(I) Complexes
Description
Experimental details are provided in this Supplementary Information.
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Version History

Dec 16, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-kkvbx
D O I: 10.26434/chemrxiv-2024-kkvbx [opens in a new tab]

Funding

National Natural Science Foundation of China
22101068
Natural Science Foundation of Zhejiang Province
LQ21B020007

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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