Hostname: page-component-7dd5485656-npwhs Total loading time: 0 Render date: 2025-10-31T07:08:10.217Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of host rocks on composition of colloid particles in groundwater at the Karachai Lake site

Published online by Cambridge University Press:  09 July 2018

V. I. Malkovsky ,
YU. P. Dikov ,
EN. E. Asadulin  and
V. V. Krupskaya
V. I. Malkovsky
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), Staromonetny per. 35, Moscow 119017, Russia
YU. P. Dikov
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), Staromonetny per. 35, Moscow 119017, Russia
EN. E. Asadulin
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), Staromonetny per. 35, Moscow 119017, Russia
V. V. Krupskaya
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), Staromonetny per. 35, Moscow 119017, Russia
Get access Rights & Permissions [Opens in a new window]

Abstract

The radioactive contaminant plume in groundwater at the Karachai Lake site has been examined further. The source of pollution is the Karachai Lake which was used as a reservoir for liquid radioactive waste (LRW) from the Radiochemical Production Association “Mayak” (South Urals, Russia). Taking into account that colloid-facilitated transport of radionuclides can substantially increase the contaminant migration velocity, the composition and structure of colloid particles from the groundwater within the contaminant plume were studied. Sampling of groundwater was carried out in the observation well within the contaminant plume. Different fractions of colloid particles were extracted from the groundwater samples by sequential filtration through membranes with decreasing pore size. Chemical and mineralogical compositions of the colloid particles were determined by X-ray photoelectron spectroscopy in combination with ion etching of the particle surfaces. The host rocks were studied using characteristic samples from the surface outcrop nearest to the observation well. The analysis showed that the colloid particles consisted of an inorganic core with a discontinuous organic cover. The inorganic core was close in composition to the host rocks along the flow path with a predominance of layered hydrosilicates.

Keywords

aquiferliquid radioactive waste (LRW)colloidradioactive contaminationradionuclidesKarachai LakeRussia

Information

Type
Research Papers
Information
Clay Minerals , Volume 47 , Issue 3 , September 2012 , pp. 391 - 400
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Alexakhin, A.I., Glagolev, A.V., Drozhko, E.G., Zinin, A.I., Zinina, G.A., Ivanov, I.A., Mokrov, Yu.G., Orlova, E.I., Samsonov, B.G., Samsonova, L.M. & Stukalov, P.M. (2009) Reservoir-9 as a repository of liquid radioactive waste and its influence on geological medium. Moscow, Ozersk: Rosatom 250 pp. (in Russian).Google Scholar
Amirbahman, A. & Olson, T.M. (1993) Transport of humic matter-coated hematite in packed beds. Environmental Science & Technology, 27, 2807–2813.Google Scholar
Briggs, D. & Seah, M.P. (1983) Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy. John Wiley & Sons.Google Scholar
Buck, E.C. & Bates, J.K. (1999) Microanalysis of colloids and suspended particles from nuclear waste glass alteration. Applied Geochemistry, 14, 635–653.Google Scholar
Drozhko, E.G., Ivanov, I.A., Alexakhin, A.I., Samsonova, L.M. & Glagolev, A.V. (1996) Current state of the underground hydrosphere in the region of Production Association “Mayak”. Voprosy Radiatsionnoi Bezopasnosti (Problems of Radiation Safety), no. 1, 11–19.(in Russian).Google Scholar
Fortner, J.A., Mertz, C.J., Wolf, S.F. & Jemian, P.R. (2003) Natural groundwater colloids from the USGS J-13 well in Nye county, NV: a study using SAXS and TEM. Pp. 483–488. in: Proceedings of Materials Research Society Symposium “Scientific Basis for Nuclear Waste Management XXVI” (December 2–5. 2002, Boston, U.S.A.), 757 (Finch, R.J. & Bullen, D.B., editors). Warrendale: Materials Research Society.Google Scholar
Honeyman, B.D. (1999) Colloidal culprits in contamination. Nature, 397, 23–24.Google Scholar
Inagaki, Y., Sakata, H., Idemitsu, K., Arima, T., Banda, T., Maeda, T., Matsumoto, S., Tamura, Y. & Kikkawa, S. (1998) Effects of water redox conditions and presence of magnetite on leaching of Pu and Np from HLW glass. Pp. 177–184. in: Proceedings of Materials Research Society Symposium “Scientific Basis for Nuclear Waste Management XXI” (September 28 – October 3, 1997, Davos, Switzerland), 506 (McKinley, I.G. & McCombie, C., editors). Warrendale: Materials Research Society.Google Scholar
De Marsily, G. (1986) Quantitative Hydrogeology. Orlando, Florida: Academic Press.Google Scholar
Kersting, A.B., Efurd, D.W., Finnegan, D.L., Rokop, D.J., Smith, D.K. & Thompson, J.L. (1999) Migration of plutonium in ground water at the Nevada test site. Nature, 397, 56–59.Google Scholar
Keswick, B.H. & Gerba, C.P. (1980) Viruses in groundwater. Environmental Science & Technology, 14, 1290–1297.Google Scholar
Kretzschmar, R. & Schäfer, Th. (2005) Metal retention and transport on colloidal particles in the environment. Elements, 1, 205–210.Google Scholar
Kretzschmar, R. & Sticher, H. (1997) Transport of humiccoated iron oxide colloids in a sandy soil: influence of Ca2+ and trace metals. Environmental Science & Technology, 31, 3497–3504.Google Scholar
McCarthy, J., Czerwinski, K.R. Sanford, W.E. Jardine, P.M. & Marsh, J.D. (1998) Mobilization of transuranic radionuclides from disposal trenches by natural organic matter. Journal of Contaminant Hydrology, 30, 49–77.Google Scholar
Malkovsky, V.I. & Pek, A. A. (2009) Effect of elevated velocity of particles in groundwater flow and its role in colloid-facilitated transport of radionuclides in underground medium. Transport in Porous Medium. 78. 277–294.Google Scholar
Malkovsky, V.I., Dikov, Yu.P., Kalmykov, S.N. & Buleev, M.I. (2009) Structure of colloid particles in groundwaters on the territory of the Mayak Production Association and its impact on the colloid transport of radionuclides in subsoil environments. Geochemistry International, 47, 1100–1106.Google Scholar
Morel, F.M.M. & Gschwend, P.M. (1987) The role of colloids in the partitioning of solutes in natural waters. Chapter 15 in: Aquatic Surface Chemistry (Stumm, W., editor). Wiley, New York.Google Scholar
Novikov, A.P., Kalmykov, S.N., Utsunomiya, S., Ewing, R., Horreard, F., Merkulov, A., Clark, S.B., Tkachev, V.V. & Myasoedov, B.F. (2006) Colloid transport of plutonium in the far-field of the Mayak Production Association, Russia. Science, 314, 638–641.Google Scholar
Nyhan, J.W., Drennon, B.J., Abeele, W.V., Wheeler, M.L., Purtymun, W.D., Trujillo, G., Herrera, W.J. & Booth, J.W. (1985) Distribution of plutonium and americium beneath a 33-yr-old liquid waste disposal site. Journal of Environment Quality, 14, 501–509.Google Scholar
Penrose, W.R., Polzer, W.L., Essington, E.H., Nelson, D.M. & Orlandini, K.A. (1990) Mobility of plutonium and americium through a shallow aquifer in a semiarid region. Environmental Science & Technology, 24, 228–234.CrossRefGoogle Scholar
Rybalchenko, A.I., Pimenov, M.K., Kostin, P.P., Balukova, V.D., Nosukhin, A.V., Mikerin, E.I., Egorov, N.N., Kaimin, E.P., Kosareva, I.M. & Kurochkin, V.M. (1998) Deep injection disposal of liquid radioactive waste in Russia. Battelle Press, Richland, Washington, USA.Google Scholar
Short, S.A. & Lowson, R.T. (1988) 234U/238U and 230Th/234U activity ratios in the colloidal phases of aquifers in lateritic weathered zones. Geochimica et Cosmochimica Acta, 52, 2555–2563.Google Scholar
Solodov, I.N., Zotov, A.V., Khoteev, A.D., Mukhamet-Galeev, A.P., Tagirov, B.R. & Apps, J.A. (1998) Geochemistry of natural and contaminated subsurface waters in fissured bed rocks of the Karachai lake area, Southern Urals, Russia. Applied Geochemistry, 13, 921–939.Google Scholar
Tipping, E. (1981) The adsorption of aquatic humic substances by iron oxides. Geochimica et Cosmochimica Acta, 45, 191–199.Google Scholar
Vilks, P., Miller, H.G. & Doern, D.C. (1991) Natural colloids and suspended particles in the Whiteshell research area, Manitoba, Canada, and their potential effect on radiocolloid formation. Applied Geochemistry, 6, 565–574.CrossRefGoogle Scholar
Zachara, J.M., Smith, S.C., Liu, Ch., McKinley, J.P., Serne, R.J. & Gassman, P.L. (2002) Sorption of Cs+ to micaceous subsurface sediments from the Hanford site, USA. Geochimica et Cosmochimica Acta, 66, 199–211.Google Scholar