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Oxygen semi-permeation properties of La1−xSrxFeO3−δ perovskite membranes under high oxygen gradient

Published online by Cambridge University Press:  28 August 2020

Eva Deronzier ,
Thierry Chartier  and
Pierre-Marie Geffroy
Eva Deronzier*
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
Thierry Chartier
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
Pierre-Marie Geffroy
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
*
a)Address all correspondence to this author. e-mail: eva.deronzier@unilim.fr
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Abstract

This work is focused on the evaluation of oxygen semi-permeation and electrochemical performances under high oxygen gradient of free cobalt perovskite membrane materials; La1−xSrxFeO3−δ perovskite. For a better understanding of oxygen transport through La1−xSrxFeO3−δ perovskite membranes, the oxygen diffusion, oxygen incorporation, and desorption coefficients were determined under high oxygen gradient in relation to the temperature for La1−xSrxFeO3−δ (with x = 0.1, 0.3, 0.5, and 0.7) by a specific method based on oxygen semi-permeation. The best electrochemical performances were obtained for La0.3Sr0.7FeO3−δ (LSF37) and La0.5Sr0.5FeO3−δ (LSF55) perovskite membranes with oxygen fluxes of 1.7 × 10−3 and 1.2 × 10−3 mol/m2 s at 900 °C, respectively. The oxygen incorporation and desorption coefficients of LSF55 were two times lower than those of LSF37 and similar to those of La0.5Sr0.5Fe0.7Ga0.3O3−δ. The values of these coefficients are discussed and compared with the data reported in the literature by isotopic exchange for the similar material compositions.

Keywords

LSF perovskiteoxygen diffusionoxygen desorption coefficient

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Journal of Materials Research , Volume 35 , Issue 18 , 28 September 2020 , pp. 2506 - 2515
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Copyright © Materials Research Society 2020

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