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Effective slip lengths for immobilized superhydrophobic surfaces

Published online by Cambridge University Press:  24 July 2017

Darren G. Crowdy*
Affiliation:
Department of Mathematics, Imperial College London, 180 Queen’s Gate, London, SW7 2AZ, UK
*
Email address for correspondence: d.crowdy@imperial.ac.uk

Abstract

Analytical solutions are found for both longitudinal and transverse shear flow, at zero Reynolds number, over immobilized superhydrophobic surfaces comprising a periodic array of near-circular menisci penetrating into a no-slip surface and where the menisci are no longer shear-free but are taken to be no-slip zones. Explicit formulae for the associated longitudinal and transverse effective slip lengths are derived; these are then compared with analogous results for superhydrophobic surfaces of the same characteristic geometry but where the menisci are shear-free. The new formulae give results that are consistent with recent experimental observations that have prompted suggestions that menisci that are assumed to be free of shear have in fact been immobilized. Significantly, for transverse shear flow, it is found that at critical downward meniscus protrusion angles of around $47^{\circ }$ , for many surface geometries, it is impossible to distinguish, purely from the effective slip length, between a no-shear and a no-slip boundary condition. We also find that immobilized menisci bowing into the grooves at supercritical angles just below $90^{\circ }$ can be almost twice as slippery to transverse shear as no-shear menisci. The results are relevant to recent discussion as to whether surface immobilization, due to contamination by surfactants or other physical mechanisms, is compromising drag reduction properties expected from an assumed no-shear condition.

Information

Type
Rapids
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
© 2017 Cambridge University Press
Figure 0

Figure 1. Downward protruding circular meniscus in a period-$L$ superhydrophobic surface. This paper compares effective slip lengths when the meniscus is both no-shear and no-slip.

Figure 1

Figure 2. Surface shapes with period $L=1$ described by (1.3) and (1.4) for $c=d=0.5,0.3$ and $0.1$ (this is the case $\unicode[STIX]{x1D719}=90^{\circ }$; other protrusion angle choices with $c\neq d$ can be taken). The menisci are very close to being semicircular with near-flat inter-groove spacing of length approximately $L-2d$. The broken lines show exactly semicircular menisci of radius $d$ separated by straight lines along $y=0$; these broken lines are barely visible except near mildly smoothed-out corners, indicating the accuracy of the approximation.

Figure 2

Figure 3. Conformal mapping from the unit $\unicode[STIX]{x1D701}$-disc with logarithmic branch cut to a single period of the surface. Points labelled by the same letter correspond under the mapping (1.3). The area $A_{g}$ beneath $y=0$ is also indicated. Point $A$ in the physical plane is at $z=0$.

Figure 3

Figure 4. Normalized longitudinal slip length for grooves of aspect ratio $2c/L=0.5$ as a function of downward protrusion angle $\unicode[STIX]{x1D719}$. The no-shear results are based on a slip length formula of Crowdy (2016); the no-slip results are from (1.5). Data points for $\unicode[STIX]{x1D719}=0.1870$ and $\unicode[STIX]{x1D719}=0.1$ corresponding to estimates of the meniscus geometries of experiments M1 and M2 of Bolognesi et al. (2014) are shown. The no-slip results show behaviour consistent with the experiments.

Figure 4

Figure 5. Normalized transverse slip length for grooves of aspect ratio $2c/L=0.2$ as a function of downward protrusion angle $\unicode[STIX]{x1D719}$. The no-shear results are based on the slip length formula of Davis & Lauga (2009); the no-slip results are from (1.6). Cross-over occurs at a critical angle of $\unicode[STIX]{x1D719}\approx 46.8^{\circ }$