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Influence of laser surface melting on glass formation and tribological behaviors of Zr55Al10Ni5Cu30 alloy

Published online by Cambridge University Press:  15 September 2011

Bingqing Chen
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
Yan Li
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
Ran Li
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
Shujie Pang
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
Yan Cai
Affiliation:
School of Aeronautic Science and Engineering, Beihang University, 100191 Beijing, China
Hui Wang
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
Tao Zhang*
Affiliation:
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, 100191 Beijing, China
*
a)Address all correspondence to this author. e-mail: zhangtao@buaa.edu.cn
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Abstract

A gradient structure was synthesized on the surface of Zr55Al10Ni5Cu30 alloy with high glass-forming ability by laser surface melting (LSM). Along the laser incident direction, the surface remelted alloy exhibits gradient microstructure distributed in the sequence of amorphous structure, nanocrystal- reinforced amorphous matrix composite (transitional layer A), dendrites–amorphous phase composite (transitional layer B), and crystalline phases from the top surface to the substrate. The formation mechanism of this gradient structure is discussed based on the experimental results of the microstructure together with the finite volume simulation of the process of LSM treatment. The friction coefficient of the transitional layer A is ∼2.5 times lower than those of the other layers under the same sliding friction condition, and possible reasons for this phenomenon are discussed in connection with the rolling motion and material transfer mechanism. The transitional layer B exhibits the best wear resistance among all the structures studied here, which is related to the optimized ratio of microhardness to reduced Young’s modulus (H/Er).

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Articles
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Greer, A.L.: Metallic glass. Science 267, 1947 (1995).CrossRefGoogle Scholar
2.Peter, A. and Johnson, W.L.: A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl. Phys. Lett. 63, 2342 (1993).Google Scholar
3.Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
4.Zhang, T., Inoue, A., and Masumoto, T.: Amorphous Zr-Al-TM (TM=Co, Ni, Cu) alloys with significant supercooled liquid region of over 100 K. Mater. Trans., JIM 32, 1005 (1991).CrossRefGoogle Scholar
5.Zhang, T. and Men, H.: Plastic deformability and precipitation of nanocrystallites during compression for a Cu–Zr–Ti–Sn bulk metallic glass. J. Alloy. Comp. 1012, 434 (2007).Google Scholar
6.Hofmann, D.C., Suh, J.Y., Wiest, A., Duan, G., Lind, M.L., Demetriou, M.D., and Johnson, W.L.: Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085 (2008).CrossRefGoogle ScholarPubMed
7.Yavari, A.R., Lewandowski, J.J., and Eckert, J.: Mechanical properties of bulk metallic glasses. MRS Bull. 32, 635 (2007).CrossRefGoogle Scholar
8.Inoue, A. and Nishiyama, N.: Applications as magnetic-sensing, chemical, and structural materials. MRS Bull. 32, 651 (2007).CrossRefGoogle Scholar
9.Kumar, G., Tang, H.X., and Schroers, J.: Nanomoulding with amorphous metals. Nature 457, 868 (2009).Google Scholar
10.Zberg, B., Uggowitzer, P.J., and Löffler, J.F.: MgZnCa glasses without clinically observable hydrogen evolution for biodegradable implants. Nat. Mater. 8, 887 (2009).CrossRefGoogle ScholarPubMed
11.Audebert, F., Colaco, R., Vilar, R., and Sirkin, H.: Production of glassy metallic layers by laser surface treatment. Scr. Mater. 48, 281 (2003).CrossRefGoogle Scholar
12.Inoue, A.: Bulk Amorphous Alloys (Trans Tech Publications, Zurich, 1998), p. 27.Google Scholar
13.Wu, X., Xu, B., and Hong, Y.: Synthesis of thick Ni66Cr5Mo4Zr6P15B4 amorphous alloy coating and large glass-forming ability by laser cladding. Mater. Lett. 56, 838 (2002).CrossRefGoogle Scholar
14.Yue, T.M., Su, Y.P., and Yang, H.O.: Laser cladding of Zr65Al7.5Ni10Cu17.5 amorphous alloy on magnesium. Mater. Lett. 61, 209 (2007).CrossRefGoogle Scholar
15.Jiang, S-W., Jiang, B., Li, Y., Li, Y-R., Yin, G-F., and Zheng, C-Q.: Friction and wear study of diamond-like carbon gradient coatings on Ti6Al4V substrate prepared by plasma source ion implant-ion beam enhanced deposition. Appl. Surf. Sci. 236, 285 (2004).CrossRefGoogle Scholar
16.Fu, X.Y., Kasai, T., Falk, M.L., and Rigney, D.A.: Sliding behavior of metallic glass-part I: Experimental investigations. Wear 250, 409 (2001).CrossRefGoogle Scholar
17.Parlar, Z., Bakkal, M., and Shih, A.J.: Sliding tribological characteristics of Zr-based bulk metallic glass. Intermetallics 16, 34 (2008).CrossRefGoogle Scholar
18.Blau, P.J.: Friction and wear of a Zr-based amorphous metal alloy under dry and lubricated conditions. Wear 250, 431 (2001).CrossRefGoogle Scholar
19.Matthews, D.T.A., Ocelík, V., and de Hosson, J.Th.M.: Tribological and mechanical properties of high power laser surface-treated metallic glasses. Mater. Sci. Eng., A 471, 155 (2007).Google Scholar
20.Matthews, D.T.A., Ocelík, V., and de Hosson, J.Th.M.: Scratch test induced shear banding in high power laser remelted metallic glass layers. J. Mater. Res. 22, 460 (2007).Google Scholar
21.Fleury, E., Lee, S.M., Ahn, H.S., Kim, W.T., and Kim, D.H.: Tribological properties of bulk metallic glasses. Mater. Sci. Eng., A 375377, 276 (2004).Google Scholar
22.Yavari, A.R., Le Moulec, A., Botta F., W.J., Inoue, A., Rejmankova, P., and Kvick, A.: In situ crystallization of Zr55Cu30Al10Ni5 bulk glass forming from the glassy and undercooled liquid states using synchrotron radiation. J. Non-Cryst. Solids 247, 31 (1999).CrossRefGoogle Scholar
23.Tariq, N.H., Hasan, B.A., and Akhter, J.I.: Evolution of microstructure in Zr55Cu30Al10Ni5 bulk amorphous alloy by high power pulsed Nd:YAG laser. J. Alloy. Comp. 485, 212 (2009).Google Scholar
24.Li, P., Hao, J.Y., Tan, J.L., and Wang, Q.: Influence of annealing on the elastic properties and microstructure of Cu58.1Zr35.9Al6 bulk metallic glass. Mater. Sci. Eng., A 527, 3416 (2010).Google Scholar
25.Wang, L., Nie, X., Housden, J., Spain, E., Jiang, J.C., Meletis, E.I., Leyland, A., and Mattews, A.: Material transfer phenomena and failure mechanisms of a nanostructured Cr-Al-N coating in laboratory wear tests and an industrial punch tool application. Surf. Coat. Tech. 203, 816 (2008).Google Scholar
26.Kim, J.H., Lee, C., Lee, D.M., Sun, J.H., Shin, S.Y., and Bae, J.C.: Pulsed Nd: YAG laser welding of Cu54Ni6Zr22Ti18 bulk metallic glass. Mater. Sci. Eng., A 449451, 872 (2007).CrossRefGoogle Scholar
27.Li, B., Li, Z.Y., Xiong, J.G., Xing, L., Wang, D., and Li, Y.: Laser welding of Zr45Cu48Al7 bulk glassy alloy. J. Alloy. Comp. 413, 118 (2006).CrossRefGoogle Scholar
28.Basu, A., Samant, A.N., Harimkar, S.P., Dutta Majumdar, J., Manna, I., and Dahotre, N.B.: Laser surface coating of Fe–Cr–Mo–Y–B–C bulk metallic glass composition on AISI 4140 steel. Surf. Coat. Tech. 202, 2623 (2008).CrossRefGoogle Scholar
29.Lei, Y.P., Murakawa, H., Shi, Y.W., and Li, X.Y.: Numerical analysis of the competitive influence of Marangoni flow and evaporation on heat surface temperature and molten pool shape in laser surface remelting. Comput. Mater. Sci. 21, 276 (2001).CrossRefGoogle Scholar
30.Zhang, Q.S., Guo, D.Y., Wang, A.M., Zhang, H.F., Ding, B.Z., and Hu, Z.Q.: Preparation of bulk Zr55Al10Ni5Cu30 metallic glass ring by centrifugal casting method. Intermetallics 10, 1197 (2002).Google Scholar
31.Yamasaki, M., Kagao, S., and Kawamura, Y.: Thermal diffusivity and conductivity of Zr55Al10Ni5Cu30 bulk metallic glass. Scr. Mater. 53, 63 (2005).CrossRefGoogle Scholar
32.Aydiner, C.C., Üstündag, E., Prime, M.B., and Peker, A.: Modeling and measurement of residual stresses in a bulk metallic glass plate. J. Non-Cryst. Solids 316, 82 (2003).CrossRefGoogle Scholar
33.Zappel, J. and Sommer, F.: Heat capacity and non-isothermal viscous flow of Al7.5Cu17.5Ni10Zr65 glassy alloy in the glass transition range. J. Non-Cryst. Solids 205207, 494 (1996).CrossRefGoogle Scholar
34.Luo, J., Duan, H.P., Ma, C.L., Pang, S.J., and Zhang, T.: Effects of yttrium and erbium additions on glass-forming ability and mechanical properties of bulk glassy Zr-Al-Ni-Cu alloys. Mater. Trans. JIM 47, 450 (2006).CrossRefGoogle Scholar
35.Kim, J., Lee, D., Shin, S., and Lee, C.: Phase evolution in Cu54Ni6Zr22Ti18 bulk metallic glass Nd:YAG laser weld. Mater. Sci. Eng., A 434, 194 (2006).CrossRefGoogle Scholar
36.Maddala, D.R., Mubarok, A., and Hebert, R.J.: Sliding wear behavior of Cu50Hf41.5Al8.5 bulk metallic glass. Wear 269, 572 (2010).Google Scholar
37.Bhatt, J., Kumar, S., Dong, C., and Murty, B.S.: Tribological behaviour of Cu60Zr30Ti10 bulk metallic glass. Mater. Sci. Eng., A 458, 290 (2007).CrossRefGoogle Scholar
38.Vilt, S.G., Martin, N., McCabe, C., and Jennings, G.K.: Frictional performance of silica microspheres. Tribol. Int. 44, 180 (2011).Google Scholar
39.Braun, O.M. and Tosatti, E.: Molecular rolling friction: The cogwheel model. J. Phys. Condens. Matter 20, 354007 (2008).CrossRefGoogle Scholar
40.Liu, Y., Zhu, Y.T., Luo, X.K., and Liu, Z.M.: Wear behavior of a Zr-based bulk metallic glass and its composites. J. Alloy. Comp. 503, 138 (2010).CrossRefGoogle Scholar
41.Donnet, C., Belin, M., Auge, J.C., Martin, J.M., Grill, A., and Patel, V.: Tribochemistry of diamond-like carbon coatings in various environments. Surf. Coat. Tech. 6869, 626 (1994).Google Scholar
42.Pei, Y.T., Galvan, D., and De Hosson, J.Th.M.: Nanostructure and properties of TiC/aC: H composite coatings. Acta Mater. 53, 4505 (2005).Google Scholar
43.Hernandez Battez, A., Viesca, J.L., Gonzalez, R., Blanco, D., Asedegbega, E., and Osorio, A.: Friction reduction properties of a CuO nanolubricant used as lubricant for a NiCrBSi coating. Wear 268, 325 (2010).CrossRefGoogle Scholar
44.Hernandez Battez, A., Gonzalez, R., Viesca, J.L., Fernandez, J.E., Diaz Fernandez, J.M., Machado, A., Chou, R., and Riba, J.: CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants. Wear 265, 422 (2008).Google Scholar
45.Leyland, A. and Matthews, A.: On the significance of the H/E ration in wear control: A nanocomposite coating approach to optimized tribological behaviour. Wear 246, 1 (2000).CrossRefGoogle Scholar
46.Leyland, A. and Matthews, A.: Design criteria for wear-resistant nanostructured and glassy-metal coatings. Surf. Coat. Tech. 177178, 317 (2004).Google Scholar