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Fabrication of metal oxide–diamond composite films by electrophoretic deposition and anodic dissolution

Published online by Cambridge University Press:  31 January 2011

Kai Kamada ,
Keita Maehara ,
Maki Mukai ,
Shintaro Ida  and
Yasumichi Matsumoto
Kai Kamada
Affiliation:
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
Keita Maehara
Affiliation:
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
Maki Mukai
Affiliation:
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
Shintaro Ida
Affiliation:
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
Yasumichi Matsumoto
Affiliation:
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
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Abstract

Electrochemical codeposition of diamond particles and refractory metal hydroxide films was conducted by combining electrophoretic deposition and anodic dissolution. Anodic corrosion of metal proceeded under the influence of iodide ions, and then metal ions were released to the solvent. Positively charged diamond particles were suspended in the solvent and electrophoretically deposited on the cathode surface at the same time as electrochemical deposition of the metal ions. As a result, diamond dispersed metal hydroxide film was produced. The diamond content of the film was easily controlled by varying the quantity of suspension in the solvent. This codeposition mechanism is investigated in detail.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 12 , December 2003 , pp. 2826 - 2831
Copyright
Copyright © Materials Research Society 2003

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