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Phase equilibria and structural chemistry in the ternary systems M–Si–N and M–B–N (M = Al, Cu, Zn, Ag, Cd, In, Sn, Sb, Au, Tl, Pb, Bi)

Published online by Cambridge University Press:  31 January 2011

F. Weitzer ,
K. Remschnig ,
J. C. Schuster  and
P. Rogl
F. Weitzer
Affiliation:
Institut für Physikalische Chemie der Universität Wien, Währingerstraβe 42, A-1090 Wien, Austria
K. Remschnig
Affiliation:
Institut für Physikalische Chemie der Universität Wien, Währingerstraβe 42, A-1090 Wien, Austria
J. C. Schuster
Affiliation:
Institut für Physikalische Chemie der Universität Wien, Währingerstraβe 42, A-1090 Wien, Austria
P. Rogl
Affiliation:
Institut für Physikalische Chemie der Universität Wien, Währingerstraβe 42, A-1090 Wien, Austria
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Abstract

Phase equilibria in the ternary systems M–Si–N and M–B–N (M = Cu, Ag, Au, Zn, Cd, Al, In, Tl, Sn, Pb, Sb, and Bi) at temperatures 50–100 °C below the melting point of the metal components were investigated by means of x-ray powder analysis and are represented in the form of isothermal sections. No ternary compound formation was observed in any of the combinations M–Si–N and M–B–N. Silicon nitride and boron nitride, respectively, coexist with all metals investigated and with all binary compounds stable at the chosen temperatures. From unit cell dimensions negligible mutual solid solubilities are indicated between Si3N4 or BN and the metal components.

Type
Articles
Information
Journal of Materials Research , Volume 5 , Issue 10 , October 1990 , pp. 2152 - 2159
Copyright
Copyright © Materials Research Society 1990

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References

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