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HgTe, the Most Tunable Colloidal Material: from the Strong Confinement Regime to THz Material

Published online by Cambridge University Press:  29 April 2018

Clément Livache Open the ORCID record for Clément Livache [Opens in a new window] ,
Nicolas Goubet ,
Bertille Martinez ,
Eva Izquierdo ,
Charlie Greboval ,
Sandrine Ithurria  and
Emmanuel Lhuillier
Clément Livache
Affiliation:
Sorbonne Université, UPMC Univ. Paris 06, CNRS-UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005Paris, France Laboratoire de Physique et d’Étude des Matériaux, ESPCI-Paris, PSL Research University, Sorbonne Université UPMC Univ Paris 06, CNRS, 10 rue Vauquelin 75005 Paris, France.
Nicolas Goubet
Affiliation:
Sorbonne Université, UPMC Univ. Paris 06, CNRS-UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005Paris, France Laboratoire de Physique et d’Étude des Matériaux, ESPCI-Paris, PSL Research University, Sorbonne Université UPMC Univ Paris 06, CNRS, 10 rue Vauquelin 75005 Paris, France.
Bertille Martinez
Affiliation:
Sorbonne Université, UPMC Univ. Paris 06, CNRS-UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005Paris, France Laboratoire de Physique et d’Étude des Matériaux, ESPCI-Paris, PSL Research University, Sorbonne Université UPMC Univ Paris 06, CNRS, 10 rue Vauquelin 75005 Paris, France.
Eva Izquierdo
Affiliation:
Laboratoire de Physique et d’Étude des Matériaux, ESPCI-Paris, PSL Research University, Sorbonne Université UPMC Univ Paris 06, CNRS, 10 rue Vauquelin 75005 Paris, France.
Charlie Greboval
Affiliation:
Sorbonne Université, UPMC Univ. Paris 06, CNRS-UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005Paris, France
Sandrine Ithurria
Affiliation:
Laboratoire de Physique et d’Étude des Matériaux, ESPCI-Paris, PSL Research University, Sorbonne Université UPMC Univ Paris 06, CNRS, 10 rue Vauquelin 75005 Paris, France.
Emmanuel Lhuillier*
Affiliation:
Sorbonne Université, UPMC Univ. Paris 06, CNRS-UMR 7588, Institut des NanoSciences de Paris, 4 place Jussieu, 75005Paris, France
*
*(Email: el@insp.upmc.fr)
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Abstract

HgTe nanocrystals are extremely interesting materials to obtain a highly tunable absorption spectrum in the infrared range. Here, we discuss the two extreme cases of strongly confined and barely confined HgTe nanocrystals. We discuss the synthesis and optoelectronic properties of HgTe 2D nanoplatelets where the confinement energy can be as large as 1.5 eV. This material presents enhanced (mostly narrower) light emitting properties compared to spherical nanocrystals emitting at the same wavelength. Moreover, absorption spectra, majority carriers and time response can be tuned by carefully choosing the surface chemistry and applying a well-chosen gate bias. HgTe can also be used to explore the effect of vanishing confinement and to obtain quasi bulk properties with tunable absorption in the THz, up to 150 µm.

Keywords

2D materialsquantum dotinfrared (IR) spectroscopyoptoelectronic
Type
Articles
Information
MRS Advances , Volume 3 , Issue 47-48: Nanomaterials , 2018 , pp. 2913 - 2921
Copyright
Copyright © Materials Research Society 2018 

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