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High-performance elastocaloric materials for the engineering of bulk- and micro-cooling devices

  • Jan Frenzel (a1), Gunther Eggeler (a2), Eckhard Quandt (a3), Stefan Seelecke (a4) and Manfred Kohl (a5)...
Abstract

Pseudoelastic NiTi-based shape-memory alloys (SMAs) have recently received attention as candidate materials for solid-state refrigeration. The elastocaloric effect in SMAs exploits stress-induced martensitic transformation, which is associated with large latent heat. Most importantly, cyclic mechanical loading/unloading provides large adiabatic temperature drops exceeding 25 K at high process efficiencies. This article summarizes the underlying principles, important material parameters and process requirements, and reviews recent progress in the development of pseudoelastic SMAs with large coefficients of performance, as well as very good functional fatigue resistance. The application potential of SMA film and bulk materials is demonstrated for the case of cyclic tensile loading/unloading in prototypes ranging from miniature-scale devices to large-scale cooling units.

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1.Fähler, S., Rößler, U.K., Kastner, O., Eckert, J., Eggeler, G., Emmerich, H., Entel, P., Müller, S., Quandt, E., Albe, K., Adv. Eng. Mater. 14, 10 (2012).
2.Mañosa, L., Planes, A., Acet, M., J. Mater. Chem. A 1, 4925 (2013).
3.Bonnot, E., Romero, R., Mañosa, L., Vives, E., Planes, A., Phys. Rev. Lett. 100, 125901 (2008).
4.Miyazaki, S., Otsuka, K., ISIJ Int. 29, 353 (1989).
5.Otsuka, K., Ren, X., Prog. Mater. Sci. 50, 511 (2005).
6.Hornbogen, E., in Advanced Structural and Functional Materials, Bunk, W.G.J., Ed. (Springer Verlag, Köln, Germany, 1991), p. 133.
7.Goetzler, W., Zogg, R., Young, J., Johnson, C., “Energy Savings Potential and RD&D Opportunities for Non-Vapor Compression HVAC Technologies” (Prepared for the US Department of Energy by Navigant Consulting Inc., 2014).
8.Bhattacharya, K., Microstructure of Martensite: Why It Forms and How It Gives Rise to the Shape-Memory Effect (Oxford University Press, Oxford, UK, 2004).
9.Qian, S., Geng, Y., Wang, Y., Ling, J., Hwang, Y., Radermacher, R., Takeuchi, I., Cui, J., Int. J. Refrig. 64, 1 (2016).
10.Wieczorek, A., Frenzel, J., Schmidt, M., Maaß, B., Seelecke, S., Schütze, A., Eggeler, G., Funct. Mater. Lett. 10, 1740001 (2017).
11.Sehitoglu, H., Wu, Y., Ertekin, E., Scr. Mater. (2017), doi.org/10.1016/j.scriptamat.2017.05.017.
12.Wu, Y., Ertekin, E., Sehitoglu, H., Acta Mater. 135, 158 (2017).
13.Ossmer, H., Lambrecht, F., Gultig, M., Chluba, C., Quandt, E., Kohl, M., Acta Mater. 81, 9 (2014).
14.Kim, Y., Jo, M.-G., Park, J.-W., Park, H.-K., Han, H.N., Scr. Mater. 144, 48 (2018).
15.Luo, D., Feng, Y., Verma, P., Energy 130, 500 (2017).
16.Tusek, J., Engelbrecht, K., Eriksen, D., Dall’Olio, S., Tusek, J., Pryds, N., Nat. Energy 1, 16134 (2016).
17.Schmidt, M., Schütze, A., Seelecke, S., Int. J. Refrig. 54, 88 (2015).
18.Ossmer, H., Wendler, F., Gueltig, M., Lambrecht, F., Miyazaki, S., Kohl, M., Smart. Mater. Struct. 25, 085037 (2016).
19.Chluba, C., Ge, W.W., de Miranda, R.L., Strobel, J., Kienle, L., Quandt, E., Wuttig, M., Science 348, 1004 (2015).
20.Rahim, M., Frenzel, J., Frotscher, M., Pfetzing-Micklich, J., Steegmüller, R., Wohlschlögel, M., Mughrabi, H., Eggeler, G., Acta Mater. 61, 3667 (2013).
21.Waitz, T., Kazykhanov, V., Karnthaler, H.P., Acta Mater. 52, 137 (2004).
22.Delville, R., Malard, B., Pilch, J., Sittner, P., Schryvers, D., Int. J. Plast. 27, 282 (2011).
23.Frenzel, J., Wieczorek, A., Opahle, I., Maaß, B., Drautz, R., Eggeler, G., Acta Mater. 90, 213 (2015).
24.Frenzel, J., George, E.P., Dlouhy, A., Somsen, C., Wagner, M.F.X., Eggeler, G., Acta Mater. 58, 3444 (2010).
25.Cui, J., Chu, Y.S., Famodu, O.O., Furuya, Y., Hattrick-Simpers, J., James, R.D., Ludwig, A., Thienhaus, S., Wuttig, M., Zhang, Z.Y., Takeuchi, I., Nat. Mater. 5, 286 (2006).
26.Zarnetta, R., Takahashi, R., Young, M.L., Savan, A., Furuya, Y., Thienhaus, S., Maass, B., Rahim, M., Frenzel, J., Brunken, H., Chu, Y.S., Srivastava, V., James, R.D., Takeuchi, I., Eggeler, G., Ludwig, A., Adv. Funct. Mater. 20, 1917 (2010).
27.Jaeger, S., Maaß, B., Frenzel, J., Schmidt, M., Seelecke, S., Kastner, O., Eggeler, G., Int. J. Mater. Res. 106, 1029 (2015).
28.Zhang, Z.Y., James, R.D., Müller, S., Acta Mater. 57, 4332 (2009).
29.Ball, J.M., James, R.D., Philos. Trans. R. Soc. A 338, 389 (1992).
30.Schmidt, M., Ullrich, J., Wieczorek, A., Frenzel, J., Schütze, A., Eggeler, G., Seelecke, S., Shape Mem. Superelast. 1, 132 (2015).
31.Gu, H., Bumke, L., Chluba, C., Quandt, E., James, A.D., Mater. Today, https://doi.org/10.1016/j.mattod.2017.10.002.
32.Song, Y.T., Chen, X., Dabade, V., Shield, T.W., James, R.D., Nature 502, 85 (2013).
33.Ni, X.Y., Greer, J.R., Bhattacharya, K., James, R.D., Chen, X., Nano Lett. 16, 7621 (2016).
34.Chluba, C., Ge, W., Dankwort, T., Bechtold, C., de Miranda, R.L., Kienle, L., Wuttig, M., Quandt, E., Philos. Trans. R. Soc. A 374 (2016).
35.Qian, S.X., Geng, Y.L., Wang, Y., Muehlbauer, J., Ling, J.Z., Hwang, Y.H., Radermacher, R., Takeuchi, I., Sci. Technol. Built Environ. 22, 500 (2016).
36.Schmidt, M., Schütze, A., Seelecke, S., 2013 Proc. ASME Conf. Smart Mater. Adaptive Struct. Intell. Syst., Johnson, N., Ed. (ASME, New York, 2014), p. V001T04A014.
37.Schmidt, M., Schütze, A., Seelecke, S., 2014 Proc. ASME Conf. Smart Mater. Adaptive Struct. Intell. Syst., Zagrai, A., Ed. (ASME, New York, 2014), p. V002T04A013.
38.Schmidt, M., Kirsch, S.M., Seelecke, S., Schütze, A., Sci. Technol. Built Environ. 22, 475 (2016).
39.Schmidt, M., Schütze, A., Seelecke, S., APL Mater. 4, 064107 (2016).
40.Ossmer, H., Chluba, C., Gueltig, M., Quandt, E., Kohl, M., Shape Mem. Superelast. 1, 142 (2015).
41.Wendler, F., Ossmer, H., Chluba, C., Quandt, E., Kohl, M., Acta Mater. 136, 105 (2017).
42.Bruederlin, F., Ossmer, H., Wendler, F., Miyazaki, S., Kohl, M., J. Phys. D Appl. Phys. 50, 424003 (2017).
43.Ossmer, H., Kohl, M., Nat. Energy 1, 16159 (2016).
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MRS Bulletin
  • ISSN: 0883-7694
  • EISSN: 1938-1425
  • URL: /core/journals/mrs-bulletin
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