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Automated diffraction tomography combined with electron precession: a new tool for ab initio nanostructure analysis

  • Ute Kolb (a1), Tatiana Gorelik (a2) and Enrico Mugnaioli (a3)
Abstract

Three-dimensional electron diffraction data was collected with our recently developed module for automated diffraction tomography and used to solve inorganic as well as organic crystal structures ab initio. The diffraction data, which covers nearly the full relevant reciprocal space, was collected in the standard nano electron diffraction mode as well as in combination with the precession technique and was subsequently processed with a newly developed automated diffraction analysis and processing software package. Non-precessed data turned out to be sufficient for ab initio structure solution by direct methods for simple crystal structures only, while precessed data allowed structure solution and refinement in all of the studied cases.

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1.O'Keefe, M. A., Microscopy and Microanalysis 10 (Suppl 2), 972 (2004).
2.Zou, X., Hovmöller, A. and Hovmöller, S., Ultramicroscopy, 98, 187 (2004); J. Jansen, D. Tang, H. W. Zandbergen and H. Schenk, Acta Cryst. A54, 91 (1998); R. Kilaas, L. D. Marks and C. S. Own Ultramicroscopy 102, 233 (2005).
3.Kolb, U., Gorelik, T., in: Weirich, Th. et al. (Eds.), Electron Crystallography, vol. 211, Kluwer Academic Publishers, Netherlands, NATO ASI Series E: Applied Sciences, 2005, p. 421.
4.Vainshtein, B. K., Structure Analysis by Electron Diffraction, Plenum, 1964.
5.Vincent, R., Midgley, P. A., Ultramicroscopy 53, 271 (1994).; C.S.Own, System design and verification of the precession electron diffraction technique, Ph. D. Dissertation, Northwestern University Evanston Illinois, 2005 /http://www.numis.northwestern.edu/Research/Current/precessions; A. Avilov, K. Kuligin, S. Nicolopoulos, M. Nickolskiy, K. Boulahya, J. Portillo, G. Lepeshov, B. Sobolev, J. P. Collette, N. Martin, A. C. Robins, P. Fischione, Ultramicroscopy 107, 431 (2007); M. Gemmi, S. Nicolopoulos, Ultramicroscopy 107, 483 (2007).
6.Weirich, T. E., Rameau, R., Simon, A., Hovmöller, S., Zou, X. D., Nature 382, 144146, (1996); I. G. Voigt-Martin, Z. X. Zhang, U. Kolb, C. Gilmore, Ultramicroscopy 68, 43-59 (1997); D. L. Dorset, Structural Electron Crystallography, Plenum Press, New York, 1995.
7.Kolb, U., Gaelic, T., Keble, C., Otten, M. T. and Hubert, D., Ultramicroscopy 107, 507 (2007)
8.Kolb, U., Gaelic, T., Otten, M. T., Ultramicroscopy 108, 763 (2008).
9.Dιéz, D. Castano, Seybert, A., Frangakis, A. S., J. Struct. Biol. 154, 195 (2006).
10.Maslen, E. N., Streltsov, V. A., Streltsova, N. R. and Ishizawa, N., Acta Cryst. B51, 929 (1995).
11.Jacobsen, S. D., Smyth, J. R., Swope, J., Can Miner. 36, 1053 (1998).
12.Mozharivsky, Y., Pecharsky, A. O., Bud’ko, S., and Miller, G. J.: Chem. Mater. 16, 1580 (2004).
13.Rozhdestvenskaya, I. V., Kogure, T., and Drits, V. A., Abstracts of Meeting “Crystal chemistry and X-ray diffraction of Minerals”, Miass 2007, p. 4849.
14.Schmidt, M. U., Brühne, S., Wolf, A. K., Rech, A., Brüning, J., Alig, E., Fink, L., Buchsbaum, Ch., Glinnemann, J., Streek, J. van de, Gozzo, F., Brunelli, M., Stowasser, F., Gorelik, T., Mugnaioli, E. and Kolb, U. Acta Cryst. B65, 189 (2009).
15.Kolb, U. and Matveeva, G. N., Zeitschrift für Kristallographie 218(4), 259 (2003), Special issue: Electron Crystallography.
16.Gorelik, T., Kolb, U., Matveeva, G., Schleuß, T., Kilbinger, A. F. M., Streek, J. van de, in preparation.
17.Basolite A100 purchased from Sigma Aldrich 688738.
18.Tahir, M. N. and Tremel, W., unpublished results.
19.Hielscher USA, Inc., 19, Forest Rd., NJ 07456, Ringwood, USA.
20.MRC: basic file format of the Medical Research Council, extended with additional headers for up to 1024 images.
21.UCSF Chimera package from the Resource for Biocomputing, Visualization, and Informatics at the University of California, San Francisco (supported by NIH P41 RR-01081).
22.Pettersen, E. F., Goddard, T. D., Huang, C. C., Couch, G. S., Greenblatt, D. M., Meng, E. C., and Ferrin, T. E., J. Comput. Chem. 25, 1605 (2004).
23.Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., L. De Caro, Giacovazzo, C., Polidori, G., Diliqi, S., Spagna, R.: J. Appl. Cryst. 40, 609 (2007).
24.Sheldrick, G. M., Acta Crystallogr. A64, 112122 (2008).
25.Jacobsen, S. D., Smyth, J. R. and Swope, J., Can. Miner. 36 (1998) 1053
26.Mugnaioli, E., Gorelik, T., Kolb, U., Ultramicroscopy, 109, 758 (2009).
27.Mugnaioli, E., Gorelik, T., Panthoefer, M., Schade, Ch., Tremel, W. and Kolb, U., A combination of electron diffraction tomography and precession applied to Zn1+xSb nanophases, to be published
28.Putz, H., Schoen, J. C., Jansen, M., J. Appl. Cryst,. 32, 864 (1999).
29.Schmidt, M. U., Hofmann, D. W. M., Buchsbaum, Ch., and Metz, H. J., Angew. Chem. Int. Ed,. 45, 1313 (2006).
30.Georgieva, D. and Abrahams, J.-P., Leiden University, unpublished results.
31.Burla, M. C., Carrozzini, B., Cascarano, G. L., Giacovazzo, C. & Polidori, G. Z. Kristallogr. 217, 629 (2002).
32.Wilson, A. J. C. Acta Cryst.. 3, 397 (1950).
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