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NMR Studies of Hydrofluorocarbon-Cation Interactions and Cation Migrations on Adsorption of Hydrofluorocarbon-134 on Zeolites NaY and CsY

Published online by Cambridge University Press:  10 February 2011

Clare P. Grey ,
Faiza I. Poshni ,
Yong Ba  and
David R. Corbin
Clare P. Grey
Affiliation:
Chemistry Department, SUNY Stony Brook, Stony Brook, NY 11794-3400, USA
Faiza I. Poshni
Affiliation:
Chemistry Department, SUNY Stony Brook, Stony Brook, NY 11794-3400, USA
Yong Ba
Affiliation:
Chemistry Department, SUNY Stony Brook, Stony Brook, NY 11794-3400, USA
David R. Corbin
Affiliation:
DuPont Central Research and Development, Wilmington, DE 19880-0262, USA
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Abstract

23Na and 23Na/19F double resonance MAS NMR methods have been used to study the binding of hydrofluorocarbon-134 (CF2HCF2H) in zeolites NaY and CsY. The interaction of HFC- 134 with the sodium cations is so strong that the sodium cations in the sodalite cages (site I') migrate into the supercages to bind to the hydrofluorocarbon molecules.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 431: Symposium P – Microporous and Macroporous Materials , 1996 , 177
Copyright
Copyright © Materials Research Society 1996

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