Skip to main content
×
×
Home

SEMICONDUCTOR BEHAVIOR OF 2, 5-AROMATIC DISUBSTITUTED PYROLLES, AN EXPERIMENTAL AND THEORETICAL STUDY

  • L. Fomina (a1), C. Y. León Valdivieso (a1), G. Zaragoza Galán (a1), M. Bizarro (a1), I. P. Zaragoza (a1), J. Godínez Sánchez (a1), R. Salcedo (a1) and A. Baeza (a2)...
Abstract

Theoretical calculations were performed on 2, 5-aromatic substituted pyrroles which have a nitro-benzene or a cyano-benzene link to the nitrogen atom of the pyrrol fragment. The molecules manifested interesting semiconductor behavior that was confirmed when thin films were prepared and their corresponding electrical characterization undertaken. The reason for this behavior is discussed, with reference to the electron withdrawing feature of the substituents in the benzene chain.

Copyright
References
Hide All
1. Brédas, J.L., Beljonne, D., Coropceanu, V., Cornil, J., Chem. Rev. 104, 4971 (2004).
2. Facchetti, A., Beverina, L., van der Boom, M.E., Dutta, E.G., Pagani, G.A., Marks, T.J.J., Am. Chem. Soc. 128, 2142 (2006).
3. Brédas, J.L., Street, G.B., Thémans, B., André, J.M., J. Chem. Phys. 83, 1323 (1985).
4. Roncali, J., Chem. Rev. 97, 173 (1997).
5. a) Salzner, U., Lagowski, J.B., Pickup, P.G., Poirier, R.A., J. Org. Chem. 64, 7419 (1999). b) R. Salcedo, J. Mol. Model. 13, 1027 (2007).
6. Salzner, U., Synth. Metal. 101, 482 (1999).
7. Schulte, K.E., Reisch, J., Walker, H., Chem. Ber. 98, 98(1965).
8. Huerta, G., Fomina, L., Rumsh, L., Zolotukhin, M.G., Polymer Bulletin 57, 433 (2006).
9. Dirlikov, S., Chen, Z., Wang, D., Polymer 34, 705 (1993).
10. Becke, A.D., Phys. Rev. 38, 3098 (1988).
11. Perdew, J.P., Wang, Y., Phys. Rev. B 45, 13244 (1992).
12. a). Wu, C.J., Yang, L.H., Fried, L.E., Quenneville, J., Martinez, T.J., Phys. Rev. B 67, Art. No. 235101 (2003). b). Ch.W. Bauschlicher, J.W. Lawson, A. Ricca, Y.Xue, M.A. Ratner, Chem Phys. Lett. 388, 427 (2004).
13. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseira, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G. Jr. Montgomery, J.A., Stratmann, R.E., Burant, J.C., Dapprich, S., Millam, J.M., Daniels, A.D., Kudin, K.N., Strain, M.C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Menucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G.A., Ayala, P.Y., Morokuma, K., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Cioslowski, J., Ortiz, J.V., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Gomperts, R., Martin, L.R., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Gonzalez, C., Challacombe, M., Gill, P.M.W., Johnson, B.G., Chen, W., Wong, M.W., Andres, J.L., Head-Gordon, M., Replogle, E.S., Pople, J.A., Gaussian98, Gaussian Inc., Pittsburgh, PA (1998).
14. a) Krygowski, T.M., J. Chem. Inf. Comput. Sci. 33, 70 (1993). b) J. Kruszewski, T.M. Krygowski, Tetrahedron Lett. 1972, 3839 (1972). c). T.M. Krygowski, R. Anulewicz, Kruszewski, J. Acta Cryst. B 39, 732 (1983). d) T.M. Krygowski, M.K. Cyranskinski, Chem. Rev. 101, 1385 (2001).
15. Chalk, A.J., Tetrahedron 30, 1387 (1974).
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Keywords

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed