Oak and pine samples housed at the Institute of Botany, University of Hohenheim, are the backbone of the early Holocene part of the radiocarbon calibration curve, published in 1993 (Becker 1993; Kromer and Becker 1993; Stuiver and Becker 1993; Vogel et al. 1993). Since then the chronologies have been revised. The revisions include 1) the discovery of 41 missing years in the oak chronology and 2) a shift of 54 yr for the oldest part back into the past. The oak chronology was also extended with new samples as far back as 10,429 BP (8480 BC). In addition, the formerly tentatively dated pine chronology (Becker 1993) has been rebuilt and shifted to an earlier date. It is now positioned by 14C matching at 11,871-9900 BP (9922–7951 BC) with an uncertainty of ±20 yr (Kromer and Spurk 1998). With these new chronologies the 14C calibration curve can now be corrected, eliminating the discrepancy in the dating of the Younger Dryas/Preboreal transition between the proxy data of the GRIP and GISP ice cores (Johnsen et al. 1992; Taylor et al. 1993), the varve chronology of Lake Gościąż (Goslar et al. 1995) and the pine chronology (Becker, Kromer and Trimborn 1991).

We have developed a technique using a single apparatus to recover the inorganic and organic carbon from a small (few milligrams) aliquot of dried marine material for radiocarbon analysis. The main advantages of using a single apparatus are: 1) less sample is required, 2) decreased handling reduces contamination, and 3) less time and materials are used. Blank values of ∼5 μg and 19–44 μg are obtained for the inorganic and organic carbon extractions, respectively. δ14C results from sinking particulate organic and inorganic carbon are presented for samples collected in deep-sea sediment traps deployed for 10–30 day periods at 650 and 100 m above bottom (mab) in the northeast Pacific Ocean.

Since 1977, the German Institute of Archaeology in Cairo has been reexamining the archaic Royal necropolis Umm el-Qaab at Abydos (ca. 500 km south of Cairo). The necropolis consists of the tomb complexes of six kings and one queen of Dynasty I as well as two kings of Dynasty II in the southern part, the cemetery with royal tombs from Dynasty 0 and early Dynasty I in the middle and the predynastic cemetery in the northern part. Although partly destroyed and deprived of most of their contents, the tombs and the remaining artifacts are a major source for the early dynastic period and are of utmost importance for the understanding of predynastic development during Naqada I–III and the chronology of the formation of Egyptian culture. Sixteen newly 14C-dated samples were mainly taken from remains of wooden roofs and coffins, or in the case of the earliest tombs from mattings. The dating results in general are in good accordance with the relative archaeological dating of the tombs, but 100–150 yr earlier than the so far established historical chronology.

We report radiocarbon calibration data based on the revised German oak and pine series. The age range of the absolutely dated German oak series has been extended to 10,430 cal bp. The German pine series is tentatively linked to the oak series by 14C, and now reaches back to 11,871 cal bp (±20 yr). The revisions of the tree-ring time scale of the German oak chronology solved long-standing apparent discrepancies in the mid-Holocene 14C calibration data sets. The calibration data set based on the floating German pine is now in close agreement with the Preboreal part of 14C calibration series obtained from most varve chronologies and corals.

Chemical and isotopic analyses have been made of pigment samples from two separate rock art sites in Argentina. The purpose of the study has been to establish the feasibility of extracting carbonaceous material from the samples which will permit reliable radiocarbon dates for the time of painting. The two sites, Catamarca and Rio Negro, present quite different problems. Most of the paper is concerned with Catamarca, and here we have shown that the paint pigments contain very little or no organic binder; but they do contain calcium oxalate derived from local cacti, and calcium carbonate derived probably from local plant ash. We describe a method to purify carbon extracted from the calcium oxalate, and present the dates obtained on both components. We show that, though rare, natural deposits containing both calcium oxalate and calcite do occur, but that they are very distinct in both 13C and 14C compositions; and we argue that they are very unlikely to contaminate the pigments to such an extent that the 14C dates are altered. For the Rio Negro site we show that the ground for the paint pigments contains carbon derived from fires burnt inside the cave, and discuss how analytical methods provide information to develop a strategy for extracting material, from both ground and pigment, for more reliable dating.

Single-year and decadal radiocarbon tree-ring ages are tabulated and discussed in terms of 14C age calibration. The single-year data form the basis of a detailed 14C age calibration curve for the cal ad 1510–1954 interval (“cal” denotes calibrated). The Seattle decadal data set (back to 11,617 cal BP, with 0 BP = ad 1950) is a component of the integrated decadal INTCAL98 14C age curve (Stuiver et al. 1998). Atmospheric 14C ages can be transformed into 14C ages of the global ocean using a carbon reservoir model. INTCAL98 14C ages, used for these calculations, yield global ocean 14C ages differing slightly from previously published ones (Stuiver and Braziunas 1993b). We include discussions of offsets, error multipliers, regional 14C age differences and marine 14C age response to oceanic and atmospheric forcing.

We discuss the radiocarbon chronology of the loess deposited during the Upper Pleniglacial (Isotope Stage II) for the key site of Cosautsi (Republic of Moldova), which presents some major problems in 14C dating. Special care was paid to accurate microstratigraphic positioning of samples, collection of top-quality material (mainly conifer charcoal), and selection of uncontaminated pieces for dating and crossdating with bones by accelerator mass spectrometry (AMS) and/or conventional 14C dating. The results provide reliable and precise information on the sedimentation processes, the succession of short climatic events and the cycle of recurrent human settlements on the site between ∼20,000 and 16,000 bp. Two sets of climatic improvements can be ascribed to interstadial oscillations named, successively, Cosautsi VI (19,500–19,000 bp) and Cosautsi V (18–17,500 bp).

In a separate study, we conducted a series of high-precision radiocarbon measurements using wood from Britain and New Zealand to investigate interhemispheric offsets and possible temporal variations. To minimize variability associated with different species, the pretreatment of the oak (Quercus patraea) and cedar (Librocedrus bidwilli) was to α-cellulose for both. This study investigates the thoroughness of a range of pretreatment processes by the stable isotope analysis of the products.

The chief objective of this paper is to improve our understanding of the Neolithic in eastern Hungary using absolute chronological data. To accomplish this we calibrated new measurements as well as previously published dates. The up-to-date, standardized evaluation of 147 calibrated measurements showed temporal overlaps between archaeological cultures defined on the basis of ceramic styles. The average timespan of tell settlements of 285 yr was obtained using radiocarbon dates from four major settlements in eastern Hungary: Berettyóújfalu-Herpály, Hódmezővásáhely-Gorzsa-Cukortanya, Öcsöd-Kováshalom and Polgár-Csőszhalom.

The Queen's University of Belfast, Northern Ireland and University of Waikato, Hamilton, New Zealand radiocarbon laboratories have undertaken a series of high-precision measurements on decadal samples of dendrochronologically dated oak (Quercus patrea) and cedar (Libocedrus bidwillii) from Great Britain and New Zealand, respectively. The results show a real atmospheric offset of 3.4 ± 0.6% (27.2 ± 4.7 14C yr) between the two locations for the interval ad 1725 to ad 1885, with the Southern Hemisphere being depleted in l4C. This result is less than the value currently used to correct Southern Hemisphere calibrations, possibly indicating a gradient in Δ14C within the Southern Hemisphere.

Pretreatment of organic samples can be achieved by removal of contaminants, or, alternatively, by isolation of sample-specific components. We discuss the molecular aspects of these two pretreatment types, together with an assessment of their effectiveness in relation to sample type. The main division in sample type is the one between carbohydrates and proteins, leading to opposite chemical strategies for the two sample categories. Recommendations for routine 14C chemistry of organic samples also include the standardization of quality screening procedures using chemical, stable isotope and elemental data that can be collected routinely during the pretreatment of each sample.

Samples collected at the Chornoliska culture site near the village of Subotiv, Cherkasy region during the 1994–1995 Ukrainian-German expedition were radiocarbon dated in Kiev. The foundation of the Subotiv settlement dates to 1300–1200 cal BC. A skeleton found in one of the buildings at this site is dated at the end of the early period (between 1120 and 1040 cal BC). In the youngest part (a small town) of the Subotiv settlement, we found the remains of a “building sacrifice"—the skeleton of a teenager. The average calibrated date for this skeleton is 834–807 cal BC, whereas the timber from the rampart dates between 902–810 cal BC. Thus, the rampart was apparently built between 834–807 cal BC. Among the objects found on the site were Arzhan-type bone arrowheads. Such arrowheads, when found in Eastern Europe, are believed to indicate the military expansion of Proto-Scythian nomads. The Sargary settlement in western Kazakhstan dates to 960–820 cal BC, the Arzhan arrow in Siberia to 960–850 cal BC. We assume that the Chornogorivka complexes in eastern Eurasia date to the earlier time period (960–820) than those in western Eurasia (834–807). The time of the Chornogorivka expansion on the territory of Ukraine is therefore within the range 834 to 820 BC.

One explanation for the radiocarbon dates on the Shroud of Turin being younger than the time of Christ is that the heat from a fire, which scorched a portion of the Shroud, may have affected the 14C content (dates) on the shroud by affecting molecular exchange between the fabric and atmospheric carbon. This report describes a laboratory test on the susceptibility of cellulose, in the form of cotton, to incorporate carbon from CO2 while it is heated in a closed tube with carbon dioxide until the cotton considerably darkened. To maximize the effect of this hypothetical process, we simulated the shroud material with cotton that had a 14C level of 0.55 modern (55 pMC, equivalent to 4800 yr), and the atmosphere with pure CO2, which had a 14C level of 1.3 modern (130 pMC). No measurable 14C transferred from the gas phase to the solid phase. The implication of this test is that scorching is an unlikely mechanism to affect the apparent age of cellulose-like material.

Ca. 150 unequivocal 14C dates from the prehistoric cultures in the Russian Far East can be used to elucidate chrono-cultural boundaries in that region. Microblade technology started as early as ca. 20,000 bp, and continued to exist in the middle Amur River basin until ca. 10,500 bp, and in Primorye until ca. 7800 bp. The emergence of pottery-making in the lower Amur River basin goes back to ca. 13,300 bp. The transition from Upper Paleolithic to Neolithic took place during the time interval 13,300–7800 bp and pottery was widely spread in the Russian Far East by ca. 6700–8400 bp. The first evidence of shellfish collection is estimated to ca. 6400 bp at Peter the Great Gulf coast, Sea of Japan. The beginning of agriculture in Primorye, based on finding of both millet seeds (Setaria italica L.) and pollen of cultivated cereals (Cerealia), is 14C-dated to ca. 4200–3700 bp (ca. 1980–2900 cal BC). The Neolithic/Early Iron Age boundary was estimated at ca. 3100–3300 bp (1400–1600 cal BC) in the mainland Russian Far East, and to ca. 1800–2300 bp (400 cal BC–200 cal ad) on the Sakhalin and southern Kuril Islands.

To test the hypothesis that cellulose in linen can be carboxylated at high temperatures in the presence of CO2, water and silver, we heated two aliquots of cellulose extracted from old wood in glass ampoules, adding Ag powder to one to test its potential action as a catalyst for the carboxylation reaction. AMS measurement of the heated aliquots showed no statistically significant difference in 14C content from the “uncarboxylated” cellulose. We conclude that carboxylation is not a systematic source of error in the dating of cellulose-containing materials such as the linen in the Shroud of Turin.

In the framework of the interdisciplinary project “Settlement History of the Eastern Sahara” at the Universität zu Köln, a large number of sites were excavated during the 1980s in northern Sudan, where the Laqiya-region with the Wadi Shaw and Wadi Sahal was one of the main research areas. About 150 sites have been surveyed and partly excavated. One of these sites, Wadi Shaw 82/52, yielded sherds of a Maidum bowl, which is dateable to the Egyptian IVth and Vth Dynasty. This site was dated by four radiocarbon dates. The dates are compared with the historical chronology of Egypt for the IVth and Vth Dynasty, and are shown to be in good agreement.