Skip to main content Accessibility help
×
Hostname: page-component-848d4c4894-p2v8j Total loading time: 0.001 Render date: 2024-05-30T17:38:41.376Z Has data issue: false hasContentIssue false

Part I - Reaction-Diffusion Systems and Models of Catalysis

Published online by Cambridge University Press:  18 December 2009

Vladimir Privman
Affiliation:
Clarkson University, New York
Get access

Summary

Editor's note

The first three chapters of the book cover topics in reactions and catalysis. Chemical reactions comprise a vast field of study. The recent interest in models in low dimension has been due to the importance of two-dimensional surface geometry, appropriate, for instance, in heterogeneous catalysis. In addition, several experimental systems realize 1D reactions (Part VII).

The classical theory of chemical reactions, based on rate equations and, for nonuniform densities, diffusion-like differential equations, frequently breaks down in low dimension. Recent advances have included the elucidation of this effect in terms of fluctuation-dominated dynamics. Numerous models have been developed and modern methods in the theory of critical phenomena applied. The techniques employed range from exact solutions to renormalization-group, numerical, and scaling methods.

Models of reactions in 1D are also interrelated with many other 1D systems ranging from kinetic Ising models (Part II) and deposition (Part IV) to nucleation (Part III). Chapter 1 reviews the scaling theory of basic reactions and summarizes numerous results. One of the methods of obtaining exact solutions in 1D, the interparticle-distribution approach, is reviewed in Ch. 2. Other methods for deriving exact results in 1D are not considered in this Part. Instead, closely related systems and solution techniques based on kinetic Ising models and cellular automata are presented in Chs. 4, 6, 8. Coagulation models in Ch. 9 employ methods that have also been applied to reactions.

More complicated models of catalysis, directed percolation, and kinetic phase transitions, are treated in Ch. 3.

Type
Chapter
Information
Publisher: Cambridge University Press
Print publication year: 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×