Book contents
- Frontmatter
- Contents
- Preface
- Acknowledgments
- Introduction
- Part One Classical chaos and quantum localization
- Part Two Atoms in strong fields
- Localization of classically chaotic diffusion for hydrogen atoms in microwave fields
- Inhibition of quantum transport due to “scars” of unstable periodic orbits
- Rubidium Rydberg atoms in strong fields
- Diamagnetic Rydberg atom: confrontation of calculated and observed spectra
- Semiclassical approximation for the quantum states of a hydrogen atom in a magnetic field near the ionization limit
- The semiclassical helium atom
- Stretched helium: a model for quantum chaos in two-electron atoms
- Part Three Semiclassical approximations
- Part Four Level statistics and random matrix theory
- Index
Diamagnetic Rydberg atom: confrontation of calculated and observed spectra
Published online by Cambridge University Press: 07 May 2010
- Frontmatter
- Contents
- Preface
- Acknowledgments
- Introduction
- Part One Classical chaos and quantum localization
- Part Two Atoms in strong fields
- Localization of classically chaotic diffusion for hydrogen atoms in microwave fields
- Inhibition of quantum transport due to “scars” of unstable periodic orbits
- Rubidium Rydberg atoms in strong fields
- Diamagnetic Rydberg atom: confrontation of calculated and observed spectra
- Semiclassical approximation for the quantum states of a hydrogen atom in a magnetic field near the ionization limit
- The semiclassical helium atom
- Stretched helium: a model for quantum chaos in two-electron atoms
- Part Three Semiclassical approximations
- Part Four Level statistics and random matrix theory
- Index
Summary
We present a detailed comparison of the observed and computed negative- and positive-energy spectrum of a Rydberg atom in a strong magnetic field. The study extends from −30 to +30cm−1 at a field of 6 T.
The experimental resolution is sufficiently high to provide well-resolved spectra over the entire range. The spectrum calculated for hydrogen is in remarkable agreement with the spectrum observed in lithium.
As described in the preceding Letter, hereafter referred to as DBG, the hydrogen atom in a magnetic field has attracted unusual interest because it is among the simplest nonseparable systems that are physically realizable, because it is one of the small number of systems whose classical motion displays chaotic behavior in regimes where accurate quantum-mechanical calculations are possible, and because it can be studied experimentally with high precision. The simplicity of this problem is deceiving, however, for carrying forward theory and experiment have both proven to be formidable undertakings. DBG describes a breakthrough in the problem of calculating the positive-energy spectrum at laboratorysized magnetic fields. We report here the results of a comparison of calculated spectra with spectra observed experimentally by the MIT group who are the co-authors of this joint paper.
The most successful previous study of this kind was a comparison of the observed and computed spectrum for deuterium by Holle et al. for energy in the range of −190 to −20 cm−1. However, the experimental resolution was too low to achieve fully resolved spectra at the highest energies, and the computational method was limited to the negative-energy region. The work described here overcomes these limitations.
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- Quantum ChaosBetween Order and Disorder, pp. 269 - 272Publisher: Cambridge University PressPrint publication year: 1995