Skip to main content Accessibility help
×
Hostname: page-component-848d4c4894-r5zm4 Total loading time: 0 Render date: 2024-06-19T15:13:35.536Z Has data issue: false hasContentIssue false

1 - Polymerization: an overview

Published online by Cambridge University Press:  29 October 2009

Richard H. Boyd
Affiliation:
University of Utah
Paul J. Phillips
Affiliation:
University of Tennessee, Knoxville
Get access

Summary

Polymers are large molecules made up of many atoms linked together by covalent bonds. They usually contain carbon and often other atoms such as hydrogen, oxygen, nitrogen, halogens and so forth. Thus they are typically molecules considered to be in the province of organic chemistry. Implicit in the definition of a polymer is the presumption that it was synthesized by linking together in some systematic way groups of simpler building block molecules or monomers. Although the final molecular topology need not be entirely linear, it is usually the case that the linking process results in linear segments or imparts a chain-like character to the polymer molecule.

Most of the synthetic methods for linking together the building block molecules can be placed into one of two general classifications. The first of these results when the starting monomers react in such a way that groups of them that have already joined can react with other already joined groups. The linked groups have almost the same reactivity towards further reaction and linking together as the original monomers. This general class of reactions is called step polymerization. In the other general method, an especially reactive center is created and that center can react only with the original monomer molecules. Upon reaction and incorporating a monomer, the reactive center is maintained and can keep reacting with monomers, linking them together, until some other process interferes.

Type
Chapter
Information
Publisher: Cambridge University Press
Print publication year: 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×