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3 - Probability

Published online by Cambridge University Press:  04 December 2009

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Summary

As is already clear from the preceding historical sketch of the development of foundational problems in statistical mechanics, the concept of probability is invoked repeatedly in the important discussions of foundational issues. It is used informally in the dialectic designed to reconcile the time-asymmetry of statistical mechanics with the time-reversibility of the underlying dynamics, although, as we have seen, its introduction cannot by itself resolve that dilemma. Again, informally, it is used to account for the existence of equilibrium as the macro-state corresponding to the “overwhelmingly most probable” micro-states, and to account for the approach to equilibrium as the evolution of microstates from the less to the more probable. More formally, the attempts at finding an acceptable derivation of Boltzmann-like kinetic equations all rest ultimately on attempts to derive, in some sense, a dynamical evolution of a “probability distribution” over the micro-states compatible with the initial macro-constraints on the system. The picturesque notion of the ensemble, invoked in the later work of Maxwell and Boltzmann and made the core of the Gibbs presentation of statistical mechanics, really amounts to the positing of a probability distribution over the micro-states of a system compatible with its macro-constitution, and a study of the changes of such a distribution over time as determined by the underlying dynamics.

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Physics and Chance
Philosophical Issues in the Foundations of Statistical Mechanics
, pp. 90 - 127
Publisher: Cambridge University Press
Print publication year: 1993

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  • Probability
  • Lawrence Sklar
  • Book: Physics and Chance
  • Online publication: 04 December 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511624933.004
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  • Probability
  • Lawrence Sklar
  • Book: Physics and Chance
  • Online publication: 04 December 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511624933.004
Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Probability
  • Lawrence Sklar
  • Book: Physics and Chance
  • Online publication: 04 December 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511624933.004
Available formats
×