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Aqueous and solid-phase speciation of arsenic in Cornish soils
- C. Hutton, D. W. Bryce, W. Russeau, H. J. Glass, L. E. T. Jenkin, W. T. Corns, P. B. Stockwell
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- Journal:
- Mineralogical Magazine / Volume 69 / Issue 5 / October 2005
- Published online by Cambridge University Press:
- 05 July 2018, pp. 577-589
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Cornwall (UK) has suffered extensive arsenic contamination due to the historic mining and processing of mineral ores. Standard procedures for contaminated land risk assessment (DEFRA and Environment Agency, 2002a) are probably unworkable in Cornwall, with a very large number of sites classified as contaminated by arsenic. Methods of measuring the speciation and mobility of arsenic are essential for effective and rapid risk assessments of arsenic contamination.
Three clusters of lysimeters were installed in three different areas of an arsenic-contaminated Cornish site. A novel phosphoric acid microwave extraction technique was applied to the soils removed from the lysimeter holes; HPLC-HG-AFS analysis showed the majority of solid-phase arsenic to be arsenate (AsV). Pore waters obtained from the lysimeters showed variable, relatively low levels of arsenite (AsIII) and arsenate (AsV) to be present (<1–129 μg l–1). Less toxic arsenate predominated in most pore waters, with the presence of minor amounts of arsenite suggesting heterogeneous redox conditions. Pore-water arsenic concentrations were strongly positively related to solid-phase arsenate concentrations.
The use of techniques that assess the speciation of arsenic both in the solid and aqueous phases of a soil provides important information about the mobility of arsenic. The methodology presented in this paper may offer a novel basis for risk assessments of other contaminated sites.
Contributors
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- By Mitchell Aboulafia, Frederick Adams, Marilyn McCord Adams, Robert M. Adams, Laird Addis, James W. Allard, David Allison, William P. Alston, Karl Ameriks, C. Anthony Anderson, David Leech Anderson, Lanier Anderson, Roger Ariew, David Armstrong, Denis G. Arnold, E. J. Ashworth, Margaret Atherton, Robin Attfield, Bruce Aune, Edward Wilson Averill, Jody Azzouni, Kent Bach, Andrew Bailey, Lynne Rudder Baker, Thomas R. Baldwin, Jon Barwise, George Bealer, William Bechtel, Lawrence C. Becker, Mark A. Bedau, Ernst Behler, José A. Benardete, Ermanno Bencivenga, Jan Berg, Michael Bergmann, Robert L. Bernasconi, Sven Bernecker, Bernard Berofsky, Rod Bertolet, Charles J. Beyer, Christian Beyer, Joseph Bien, Joseph Bien, Peg Birmingham, Ivan Boh, James Bohman, Daniel Bonevac, Laurence BonJour, William J. Bouwsma, Raymond D. Bradley, Myles Brand, Richard B. Brandt, Michael E. Bratman, Stephen E. Braude, Daniel Breazeale, Angela Breitenbach, Jason Bridges, David O. Brink, Gordon G. Brittan, Justin Broackes, Dan W. Brock, Aaron Bronfman, Jeffrey E. Brower, Bartosz Brozek, Anthony Brueckner, Jeffrey Bub, Lara Buchak, Otavio Bueno, Ann E. Bumpus, Robert W. Burch, John Burgess, Arthur W. Burks, Panayot Butchvarov, Robert E. Butts, Marina Bykova, Patrick Byrne, David Carr, Noël Carroll, Edward S. Casey, Victor Caston, Victor Caston, Albert Casullo, Robert L. Causey, Alan K. L. Chan, Ruth Chang, Deen K. Chatterjee, Andrew Chignell, Roderick M. Chisholm, Kelly J. Clark, E. J. Coffman, Robin Collins, Brian P. Copenhaver, John Corcoran, John Cottingham, Roger Crisp, Frederick J. Crosson, Antonio S. Cua, Phillip D. Cummins, Martin Curd, Adam Cureton, Andrew Cutrofello, Stephen Darwall, Paul Sheldon Davies, Wayne A. Davis, Timothy Joseph Day, Claudio de Almeida, Mario De Caro, Mario De Caro, John Deigh, C. F. Delaney, Daniel C. Dennett, Michael R. DePaul, Michael Detlefsen, Daniel Trent Devereux, Philip E. Devine, John M. Dillon, Martin C. Dillon, Robert DiSalle, Mary Domski, Alan Donagan, Paul Draper, Fred Dretske, Mircea Dumitru, Wilhelm Dupré, Gerald Dworkin, John Earman, Ellery Eells, Catherine Z. Elgin, Berent Enç, Ronald P. Endicott, Edward Erwin, John Etchemendy, C. Stephen Evans, Susan L. Feagin, Solomon Feferman, Richard Feldman, Arthur Fine, Maurice A. Finocchiaro, William FitzPatrick, Richard E. Flathman, Gvozden Flego, Richard Foley, Graeme Forbes, Rainer Forst, Malcolm R. Forster, Daniel Fouke, Patrick Francken, Samuel Freeman, Elizabeth Fricker, Miranda Fricker, Michael Friedman, Michael Fuerstein, Richard A. Fumerton, Alan Gabbey, Pieranna Garavaso, Daniel Garber, Jorge L. A. Garcia, Robert K. Garcia, Don Garrett, Philip Gasper, Gerald Gaus, Berys Gaut, Bernard Gert, Roger F. Gibson, Cody Gilmore, Carl Ginet, Alan H. Goldman, Alvin I. Goldman, Alfonso Gömez-Lobo, Lenn E. Goodman, Robert M. Gordon, Stefan Gosepath, Jorge J. E. Gracia, Daniel W. Graham, George A. Graham, Peter J. Graham, Richard E. Grandy, I. Grattan-Guinness, John Greco, Philip T. Grier, Nicholas Griffin, Nicholas Griffin, David A. Griffiths, Paul J. Griffiths, Stephen R. Grimm, Charles L. Griswold, Charles B. Guignon, Pete A. Y. Gunter, Dimitri Gutas, Gary Gutting, Paul Guyer, Kwame Gyekye, Oscar A. Haac, Raul Hakli, Raul Hakli, Michael Hallett, Edward C. Halper, Jean Hampton, R. James Hankinson, K. R. Hanley, Russell Hardin, Robert M. Harnish, William Harper, David Harrah, Kevin Hart, Ali Hasan, William Hasker, John Haugeland, Roger Hausheer, William Heald, Peter Heath, Richard Heck, John F. Heil, Vincent F. Hendricks, Stephen Hetherington, Francis Heylighen, Kathleen Marie Higgins, Risto Hilpinen, Harold T. Hodes, Joshua Hoffman, Alan Holland, Robert L. Holmes, Richard Holton, Brad W. Hooker, Terence E. Horgan, Tamara Horowitz, Paul Horwich, Vittorio Hösle, Paul Hoβfeld, Daniel Howard-Snyder, Frances Howard-Snyder, Anne Hudson, Deal W. Hudson, Carl A. Huffman, David L. Hull, Patricia Huntington, Thomas Hurka, Paul Hurley, Rosalind Hursthouse, Guillermo Hurtado, Ronald E. Hustwit, Sarah Hutton, Jonathan Jenkins Ichikawa, Harry A. Ide, David Ingram, Philip J. Ivanhoe, Alfred L. Ivry, Frank Jackson, Dale Jacquette, Joseph Jedwab, Richard Jeffrey, David Alan Johnson, Edward Johnson, Mark D. Jordan, Richard Joyce, Hwa Yol Jung, Robert Hillary Kane, Tomis Kapitan, Jacquelyn Ann K. Kegley, James A. Keller, Ralph Kennedy, Sergei Khoruzhii, Jaegwon Kim, Yersu Kim, Nathan L. King, Patricia Kitcher, Peter D. Klein, E. D. Klemke, Virginia Klenk, George L. Kline, Christian Klotz, Simo Knuuttila, Joseph J. Kockelmans, Konstantin Kolenda, Sebastian Tomasz Kołodziejczyk, Isaac Kramnick, Richard Kraut, Fred Kroon, Manfred Kuehn, Steven T. Kuhn, Henry E. Kyburg, John Lachs, Jennifer Lackey, Stephen E. Lahey, Andrea Lavazza, Thomas H. Leahey, Joo Heung Lee, Keith Lehrer, Dorothy Leland, Noah M. Lemos, Ernest LePore, Sarah-Jane Leslie, Isaac Levi, Andrew Levine, Alan E. Lewis, Daniel E. Little, Shu-hsien Liu, Shu-hsien Liu, Alan K. L. Chan, Brian Loar, Lawrence B. Lombard, John Longeway, Dominic McIver Lopes, Michael J. Loux, E. J. Lowe, Steven Luper, Eugene C. Luschei, William G. Lycan, David Lyons, David Macarthur, Danielle Macbeth, Scott MacDonald, Jacob L. Mackey, Louis H. Mackey, Penelope Mackie, Edward H. Madden, Penelope Maddy, G. B. Madison, Bernd Magnus, Pekka Mäkelä, Rudolf A. Makkreel, David Manley, William E. Mann (W.E.M.), Vladimir Marchenkov, Peter Markie, Jean-Pierre Marquis, Ausonio Marras, Mike W. Martin, A. P. Martinich, William L. McBride, David McCabe, Storrs McCall, Hugh J. McCann, Robert N. McCauley, John J. McDermott, Sarah McGrath, Ralph McInerny, Daniel J. McKaughan, Thomas McKay, Michael McKinsey, Brian P. McLaughlin, Ernan McMullin, Anthonie Meijers, Jack W. Meiland, William Jason Melanson, Alfred R. Mele, Joseph R. Mendola, Christopher Menzel, Michael J. Meyer, Christian B. Miller, David W. Miller, Peter Millican, Robert N. Minor, Phillip Mitsis, James A. Montmarquet, Michael S. Moore, Tim Moore, Benjamin Morison, Donald R. Morrison, Stephen J. Morse, Paul K. Moser, Alexander P. D. Mourelatos, Ian Mueller, James Bernard Murphy, Mark C. Murphy, Steven Nadler, Jan Narveson, Alan Nelson, Jerome Neu, Samuel Newlands, Kai Nielsen, Ilkka Niiniluoto, Carlos G. Noreña, Calvin G. Normore, David Fate Norton, Nikolaj Nottelmann, Donald Nute, David S. Oderberg, Steve Odin, Michael O’Rourke, Willard G. Oxtoby, Heinz Paetzold, George S. Pappas, Anthony J. Parel, Lydia Patton, R. P. Peerenboom, Francis Jeffry Pelletier, Adriaan T. Peperzak, Derk Pereboom, Jaroslav Peregrin, Glen Pettigrove, Philip Pettit, Edmund L. Pincoffs, Andrew Pinsent, Robert B. Pippin, Alvin Plantinga, Louis P. Pojman, Richard H. Popkin, John F. Post, Carl J. Posy, William J. Prior, Richard Purtill, Michael Quante, Philip L. Quinn, Philip L. Quinn, Elizabeth S. Radcliffe, Diana Raffman, Gerard Raulet, Stephen L. Read, Andrews Reath, Andrew Reisner, Nicholas Rescher, Henry S. Richardson, Robert C. Richardson, Thomas Ricketts, Wayne D. Riggs, Mark Roberts, Robert C. Roberts, Luke Robinson, Alexander Rosenberg, Gary Rosenkranz, Bernice Glatzer Rosenthal, Adina L. Roskies, William L. Rowe, T. M. Rudavsky, Michael Ruse, Bruce Russell, Lilly-Marlene Russow, Dan Ryder, R. M. Sainsbury, Joseph Salerno, Nathan Salmon, Wesley C. Salmon, Constantine Sandis, David H. Sanford, Marco Santambrogio, David Sapire, Ruth A. Saunders, Geoffrey Sayre-McCord, Charles Sayward, James P. Scanlan, Richard Schacht, Tamar Schapiro, Frederick F. Schmitt, Jerome B. Schneewind, Calvin O. Schrag, Alan D. Schrift, George F. Schumm, Jean-Loup Seban, David N. Sedley, Kenneth Seeskin, Krister Segerberg, Charlene Haddock Seigfried, Dennis M. Senchuk, James F. Sennett, William Lad Sessions, Stewart Shapiro, Tommie Shelby, Donald W. Sherburne, Christopher Shields, Roger A. Shiner, Sydney Shoemaker, Robert K. Shope, Kwong-loi Shun, Wilfried Sieg, A. John Simmons, Robert L. Simon, Marcus G. Singer, Georgette Sinkler, Walter Sinnott-Armstrong, Matti T. Sintonen, Lawrence Sklar, Brian Skyrms, Robert C. Sleigh, Michael Anthony Slote, Hans Sluga, Barry Smith, Michael Smith, Robin Smith, Robert Sokolowski, Robert C. Solomon, Marta Soniewicka, Philip Soper, Ernest Sosa, Nicholas Southwood, Paul Vincent Spade, T. L. S. Sprigge, Eric O. Springsted, George J. Stack, Rebecca Stangl, Jason Stanley, Florian Steinberger, Sören Stenlund, Christopher Stephens, James P. Sterba, Josef Stern, Matthias Steup, M. A. Stewart, Leopold Stubenberg, Edith Dudley Sulla, Frederick Suppe, Jere Paul Surber, David George Sussman, Sigrún Svavarsdóttir, Zeno G. Swijtink, Richard Swinburne, Charles C. Taliaferro, Robert B. Talisse, John Tasioulas, Paul Teller, Larry S. Temkin, Mark Textor, H. S. Thayer, Peter Thielke, Alan Thomas, Amie L. Thomasson, Katherine Thomson-Jones, Joshua C. Thurow, Vzalerie Tiberius, Terrence N. Tice, Paul Tidman, Mark C. Timmons, William Tolhurst, James E. Tomberlin, Rosemarie Tong, Lawrence Torcello, Kelly Trogdon, J. D. Trout, Robert E. Tully, Raimo Tuomela, John Turri, Martin M. Tweedale, Thomas Uebel, Jennifer Uleman, James Van Cleve, Harry van der Linden, Peter van Inwagen, Bryan W. Van Norden, René van Woudenberg, Donald Phillip Verene, Samantha Vice, Thomas Vinci, Donald Wayne Viney, Barbara Von Eckardt, Peter B. M. Vranas, Steven J. Wagner, William J. Wainwright, Paul E. Walker, Robert E. Wall, Craig Walton, Douglas Walton, Eric Watkins, Richard A. Watson, Michael V. Wedin, Rudolph H. Weingartner, Paul Weirich, Paul J. Weithman, Carl Wellman, Howard Wettstein, Samuel C. Wheeler, Stephen A. White, Jennifer Whiting, Edward R. Wierenga, Michael Williams, Fred Wilson, W. Kent Wilson, Kenneth P. Winkler, John F. Wippel, Jan Woleński, Allan B. Wolter, Nicholas P. Wolterstorff, Rega Wood, W. Jay Wood, Paul Woodruff, Alison Wylie, Gideon Yaffe, Takashi Yagisawa, Yutaka Yamamoto, Keith E. Yandell, Xiaomei Yang, Dean Zimmerman, Günter Zoller, Catherine Zuckert, Michael Zuckert, Jack A. Zupko (J.A.Z.)
- Edited by Robert Audi, University of Notre Dame, Indiana
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- The Cambridge Dictionary of Philosophy
- Published online:
- 05 August 2015
- Print publication:
- 27 April 2015, pp ix-xxx
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Major southeast-directed Caledonian thrusting and folding in the Dalradian rocks of mid-Ulster: implications for Caledonian tectonics and mid-crustal shear zones
- G. I. Alsop, D. H. W. Hutton
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- Journal:
- Geological Magazine / Volume 130 / Issue 2 / March 1993
- Published online by Cambridge University Press:
- 01 May 2009, pp. 233-244
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The dominant structure controlling the disposition of Dalradian stratigraphy in mid-Ulster has hitherto been regarded as a southeast-facing gently inclined F1 anticline, a gross geometry modelled on, and thought to be a possible correlative of, the Tay Nappe in Scotland. Remapping of the supposedly inverted southern limb of this major fold reveals that much of it is in fact the correct way up. However, a stratigraphie repetition coupled with a reversal in younging does occur in the Sperrin Mountains, much further south than previously realized. This hitherto unrecognized upward southeast-facing isoclinal Sperrin Nappe is, however, a D2 structure, traceable for at least 40 km along strike and responsible for a regional stratigraphie inversion over an area of 300 km2. Following D2, a major 10 km thick D3 ductile shear zone resulted in translation towards the east-southeast. In the south, this deformation carried the Dalradian over Ordovician volcanics of the Tyrone Igneous Complex along the Omagh Thrust. Penecontemporaneity of magmatism with deformation clearly demonstrates that D3 is Caledonian (Arenig-Llanvirn). This deformation correlates with similar southeast-directed Caledonian thrusting in southern Donegal and Connemara. The apparent absence of Dalradian deformation of this age in southwestern Scotland may imply that Caledonian collision of outboard terranes with the miogeoclinal margin was initiated in Ireland and/or subsequent strike-slip has removed the evidence for deformation of this age from southwestern Scotland. The D3 shear zone in the Sperrin Mountains affects a very large volume of psammitic rocks. Within this shear zone the strain is not markedly higher than surrounding areas; however, its existence is demonstrated by the reorientation of mineral lineations over a large area. Such broad zones of only moderate strain may, we believe, be typical of translatory tectonics in areas of the mid-crust where there is little lithological diversity.
Discussion on major southeast-directed Caledonian thrusting and folding in the Dalradian rocks of mid-Ulster: implications for Caledonian tectonics and mid-crustal shear zones
- J. W. Arthurs, R. A. Smith, T. P. Johnson, G. I. Alsop, D. H. W. Hutton
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- Journal:
- Geological Magazine / Volume 131 / Issue 3 / May 1994
- Published online by Cambridge University Press:
- 01 May 2009, pp. 417-421
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The nodular granite of Castanheira, north central Portugal: origin of the nodules and evidence for diapiric mobilization of granite
- R. J. Reavy, D. H. W. Hutton, A. A. Finch
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- Journal:
- Geological Magazine / Volume 130 / Issue 2 / March 1993
- Published online by Cambridge University Press:
- 01 May 2009, pp. 145-153
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The Castanheira pluton in north-central Portugal is a small (1000 m × 600 m) granite body of Hercynian age which contains a remarkable abundance of granite-cored, biotite-rimmed nodules. The nodules are interpreted as representing original bubbles in the uppermost volatile-rich zone of a granitic pluton. Strong depletion in K and Rb in the host granite around the nodules suggests that the biotite is magmatic in origin. The nodules may have formed by reaction between chloroferrate(II) complexes in the vapour phase and silicate melt, possibly followed by condensation of the vapour phase to a small granitic core. Motion of the vapour bubble stabilized a gradient in chemical potential with respect to the host granite, giving rise to the nodules. Chemical, petrological and structural data suggest that the pluton was part of a larger granite body, which was forcefully emplaced during synchronous transcurrent shearing. The inferred presence of volatiles, in addition to the pervasive tourmalinization of the roof zone, suggest that the magma was halogen-rich; this may imply that the magma had low viscosity.
The Antrim–Galway Line: a resolution of the Highland Border Fault enigma of the Caledonides of Britain and Ireland
- P. D. Ryan, N. J. Soper, D. B. Snyder, R. W. England, D. H. W. Hutton
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- Journal:
- Geological Magazine / Volume 132 / Issue 2 / March 1995
- Published online by Cambridge University Press:
- 01 May 2009, pp. 171-184
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The westward continuation of the Highland Border fault of Scotland (HBFZ) into Ireland is problematic. It is widely thought to follow a pronounced magnetic and gravity lineament, the Fair Head-Clew Bay Line (FCL). The advantage of this interpretation is that it places all the Ordovician ophiolitic complexes and associated sedimentary basins to the south of the FCL, which would represent the contact between Laurentia and the outboard terranes. Its main shortcomings are that both the deep structure and timing of strike-slip are different on the HBFZ and FCL. In Ireland the FCL is a north-dipping feature that can be traced to the Moho on BIRPS profiles, while the HBFZ has no such signature. Terrane amalgamation in western Ireland was completed by the late Ordovician, while in Scotland the Midland Valley terrane did not finally dock until the early Devonian. These considerations suggest that in western Ireland a branch of the HBFZ exists, which was active in post-Ordovician time and must lie south of Connemara. An examination of Irish geological, geophysical and image-processed magnetic data shows that a profound lineament can be traced from Antrim to Galway Bay (the Antrim–Galway Line). Stitching plutons date movement on it as pre-405 Ma. We propose that the Antrim–Galway Line represents the continuation of the Scottish HBFZ, while the FCL is a preserved Ordovician splay of the HBFZ system whose northdipping geometry is a product of Ordovician collapse of the orogen in western Ireland.
Tectonic and kinematic evolution within mid-crustal orogenic root zones: a case study from the Caledonides of northwestern Ireland
- G. I. ALSOP, R. BRYSON, D. H. W. HUTTON
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- Journal:
- Geological Magazine / Volume 138 / Issue 2 / March 2001
- Published online by Cambridge University Press:
- 16 May 2001, pp. 193-211
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The Slieve League Peninsula of northwest Ireland lies on the western limb of a major orogenic strike-swing in which regional foliation trends have deviated from the northeast–southwest trends typical of much of Scotland, to west–east orientations. Across-strike coastal exposures on the western tip of the peninsula through Neoproterozoic Dalradian metasediments enable a detailed examination and analysis of the structural evolution of a Caledonian orogenic root zone which has been previously correlated with the Loch Awe Syncline of southwest Scotland. Minor structural development may be evaluated in terms of regional strain profiles and overprinting relationships. Over much of the area, a composite, steep northeast–southwest-trending S2–S3 foliation containing a gently southwest-plunging quartz mineral elongation lineation is the dominant fabric at outcrop, and is associated with MP2 almandine–amphibolite facies metamorphism. F2 folds are isoclinal with curvilinear hinges and similar geometry. They typically plunge steeply towards the southwest and display variable (dextral) or north-directed vergence, whilst minor F3 fold hinges plunge moderately towards the southwest and typically verge (sinistrally) towards the south. Major, composite D1–D3 tectonic slides are developed in the Argyll Group. Structural and stratigraphic relationships indicate that D1 induced large-scale reversals in younging across tectonic slides, resulting in reversals in subsequent F2 and F3 facing patterns. Tectonic sliding is associated with an intensification of strain demonstrated by increasingly intrafolial and curvilinear folding, together with extensional crenulations, sheared quartz pods and metre-scale asymmetric boudinage of metadolerites, all of which indicate dextral (D2) and sinistral (D3) shear. After unfolding subsequent folds (F4), this corresponds to top-to-the-north (D2) and top-to-the-south (D3) translations. D4 results in regionally northwest-verging structures, with minor crenulations and the S4 cleavage transecting fold hinges in an anticlockwise sense, suggesting a dextral component of deformation. The detailed kinematic data indicate that the overall geometry of this western, deep-level arm of the root zone is not a product of the classic mushrooming fountain of nappes model, but rather major interference between consistent northerly directed D2 thrusting and a later phase of southeast-directed (D3) retrocharriage (‘back-folding’) which intensifies towards the south.
Ductile transpression and localization of deformation along tectonic boundaries in the Caledonides of northwestern Ireland
- G. I. ALSOP, R. BRYSON, D. H. W. HUTTON
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- Journal:
- Geological Magazine / Volume 135 / Issue 5 / September 1998
- Published online by Cambridge University Press:
- 01 September 1998, pp. 699-718
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Orogenesis is increasingly interpreted in terms of strain focusing, localization and partitioning processes. Such heterogeneous deformation is considered a consequence of the tectonic framework, with pre-existing structural and stratigraphic variability providing inherent zones of crustal weakness. Detailed structural investigation of Neoproterozoic Dalradian metasediments in the Glencolumbkille region, northwest Ireland, enables patterns of reworking and strain localization to be assessed in terms of four overprinting ductile deformation episodes. A well-defined and intricate Dalradian stratigraphy provides readily distinguishable markers which not only focus deformation along marked rheological boundaries, but also aid in the definition and identification of resultant geometries. Overall structural and stratigraphic relationships show that whilst D1 was not associated with major structures, D2 is related to north–northeast directed folding and ductile thrusting resulting in a major phase of crustal thickening and almandine-amphibolite facies metamorphism. Structures generated during D2 deformation subsequently became the locus of intense D3 strain and were reactivated in an oblique sense associated with south or southwest directed translations. Local overprinting relationships clearly demonstrate S2 fabrics being transposed by S3 resulting in a composite foliation over large areas. Similarly, the L2 mineral lineation is abruptly transposed by L3 over relatively small distances indicating high D3 strain gradients and the susceptibility of lineations to reworking. The final stage of ductile deformation (D4) which was increasingly localized and focused into earlier (D2−D3) high strain zones, is marked by a pronounced phase of sinistral transpression associated with clockwise cleavage and minor fold transection of northwest verging upright folds. Sinistral shear is strongly partitioned in to the steep limbs of mesoscopic F4 folds. The detailed investigation of structures generated within such multiply deformed and reworked zones provides evidence of both the kinematic and tectonic evolution of regional deformation systems.
The rapakivi granites of S Greenland—crustal melting in response to extensional tectonics and magmatic underplating
- P. E. Brown, T. J. Dempster, T. N. Harrison, D. H. W. Hutton
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- Journal:
- Transactions of the Royal Society of Edinburgh: Earth Sciences / Volume 83 / Issue 1-2 / 1992
- Published online by Cambridge University Press:
- 03 November 2011, pp. 173-178
- Print publication:
- 1992
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Early Proterozoic rapakivi intrusions in S Greenland occur as thick sheets which have ramp–flat geometry and were intruded along the median planes of active ductile extensional shear zones. These shear zones and their intrusions were linked via transfer zones in a major three-dimensional framework. At high structural levels (c. 6 km) the rapakivi intrusions developed thermal aureoles which overprint the regional assemblages, whereas at deeper levels in the regional structure they are contemporaneous with regional metamorphism. Thermobarometry on the regional and contact assemblages indicates low pressure granulite facies conditions (200–400 MPa, 650°-800°C) suggesting very high thermal gradients. The rapakivi suite and associated norites have low initial 87Sr/86Sr together with positive εNd values, indicating the involvement of predominantly young crust and/or mantle component in the generation of the igneous suite. It is considered that the voluminous norites are closely related to the mafic melts which underplated the juvenile crust to trigger the generation of the monzonitic rapakivi suite. Taken together, the data are consistent with a model of Proterozoic lithospheric extension, thinning of relatively juvenile continental crust and compression of mantle isotherms, resulting in high crustal heat flow, mafic underplating, and crustal melting with emplacement of magmas along a linked network of extensional shear zones.