Zirconolite-rich ceramics were produced by the cold crucible meltingtechnique in an air atmosphere, at 1550±50 °C and 1 atm. Four samples withoverall composition (in wt.%): 4.9–14.3 CaO; 19.0–41.3 ZrO2;24.1–42.6 TiO2; 1.3–11.3 Al2O3; 6.8–30.0 Gd2O3, and 1.1–8.5 SiO2 have beenstudied. Total phases in the ceramics consist of major zirconolite and minorrutile, perovskite, zirconia, aluminium titanate, and glass. The Gd2O3 content in zirconolite reaches up to 31.4wt.% corresponding to the formula: (Cao4,Gd0.7)Zri.0(Tii4,Alo 5)070. Thedata on the phase composition agree well with coupled Gd incorporation intothe mineral structure. Ca(H) + Ti(IV) = Gd(III) + Al(III), and 2Gd(III) -Ca(II) + Zr(IV). The highest Gd contents observed in the other phases are25.4 % for zirconia, 12.6 % in glass, 8.8 % in perovskite, and 1.4 % forrutile. The rest of the elements' distribution in the samples areanalyzed.