The reactions between alkoxides and/or alkoxides and anhydrous acetates have
been investigated for access to advanced multicomponent niobates or
titanates and with the aim to get insight into relationships between the
nature of the initial precursors ‐ single or mixed‐metal derivatives,
ligands (OAc or OR, R = Et, iPr),…‐ and the properties of the final
material. Data are based on a variety of techniques: FT‐IR, multinuclear NMR
(1H, 13C, 207Pb, 113Cd),
X‐ray investigations on single crystals. Powders have been analyzed by TGA,
SEM‐EDX, light scattering and XRD.