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Frontmatter
- P. C. Deshmukh, Indian Institute of Technology, Tirupati, India
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5 - The Non-relativistic Hydrogen Atom
- P. C. Deshmukh, Indian Institute of Technology, Tirupati, India
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Summary
One must always do what one really cannot.
—Niels BohrA groundbreaking event in the development of the quantum theory of atomic structure is the remarkable discovery by Johann Jacob Balmer in 1884. He figured out that Anders Jonas Angstrom's measurements of the wavelengths = 4101.2, 4340.1, 4860.74, and 6562.10 Å of the four prominent lines in the spectrum of the hydrogen atom fit the formula, where b = 3645.6 Å, and n = 3, 4, 5, 6. This is an outstanding illustration of the arithmetic genius that Balmer was, being an arithmetic teacher in a girls’ school. Balmer's formula was independently rediscovered by Johannes Robert Rydberg six years later, and rationalized in the planetary model of the old quantum theory proposed by Niels Bohr in 1913. Orbits, however, are intangible, position and momentum measurements not being compatible. Solution to the Schrödinger equation with appropriate boundary conditions satisfactorily account for the Balmer–Rydberg–Bohr formula, explaining the discrete eigenenergies of the hydrogen atom. In Section 5.1, we discuss the bound-state solutions of the Schrödinger equation for the hydrogen atom. However, the Schrödinger equation does not fully account for the degeneracy of the energy levels of (even the nonrelativistic) hydrogen atom. This bemusing condition is addressed in the Sections 5.2 and 5.3 of this chapter, and the continuum eigenfunctions are discussed in Section 5.4.
5.1 Eigenvalues and Eigenfunctions of the Hydrogen Atom
As the very first atom in the periodic table, the hydrogen atom is the simplest one. It is the prototype of one-electron central field atomic systems (including ions) for which exact analytical solution to the Schrödinger equation can be obtained. The electron–proton two-particles Schrödinger equation for the hydrogen atom is
where and are respectively the notional position vectors in a laboratory frame of reference of the electron and the proton, and me and mp their respective masses. The gradient operators and seek space derivatives with respect to the electron and the proton coordinates respectively, and the interaction potential energy operator depends on the relative distance between the two particles. The center of mass of the two particles is located at
and the reduced mass
which is located at the position vector with respect to the center of mass.
Appendix A - Symmetry of the Hamiltonian
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Summary
A symmetry transformation can be represented on the Hilbert space of physical states by an operator that is either linear and unitary, or anti-linear and anti-unitary.
—Eugene P. WignerA.1 Continuous, Dynamical, and Discrete Symmetries
The role of symmetry in natural laws has been underscored by many, notably by Eugene P. Wigner [1]. Symmetry plays a huge role in our understanding of the laws of nature. Plato (427–327 BCE) recognized that the only regular solids, whose faces are polygons having identical faces meeting at identical solid angles, are the (i) tetrahedron, (ii) cube, (iii) octahedron, (iv) dodecahedron, and (v) icosahedron. Their symmetry properties are celebrated in Euler's theorem
where V is the number of vertices, E the number of edges, and F the number of faces. In 1905, Einstein recognized the symmetry in Maxwell's laws of electrodynamics and formulated the special theory of relativity. This symmetry resulted from the mind-boggling invariance of the speed of light in all inertial frames of reference. It required for its account a non-Euclidean four-dimensional (flat) space–time continuum [Chapter 13 of Reference 2]. Maxwell's theory of electrodynamics engendered an unimaginable constancy of the speed of light in all inertial frames of reference, regardless of their mutual motion. Einstein harbored length-contraction and time-dilation to account for the invariance of the speed of light, which is a fundamental symmetry principle. About ten years later, Einstein interpreted gravity in terms of an equivalence principle, inspired yet again by symmetry. A few years later, in 1918, Emmy Noether established that each conservation law is in essence an equivalent expression of an underlying symmetry. Rudimentary introduction to some of these ideas is now found even in undergraduate texts, such as Reference [2]. In this chapter, we discuss the role of symmetry in atomic structure and dynamics.
The hallmark of quantum theory is the recognition of employing operators to represent dynamical variables of classical mechanics. The simplest symmetry operation is translation through an infinitesimal displacement in homogeneous space.
8 - Quantum Mechanics of Spectral Transitions
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Summary
The GMRT (Giant Metrewave Radio Telescope) is an array of thirty fully steerable parabolic radio telescopes having a diameter of 45 meters for radio astronomical research at meter wavelengths. It is an extremely advanced facility set up by the National Centre for Radio Astrophysics at Khodad (near Pune, India).
Theories of the formation of structure in the Big-Bang Universe predict the presence of proto galaxies or proto clusters of galaxies made up of clouds of neutral hydrogen gas before their gravitational condensation into galaxies. It should in principle be possible to detect these through the well-known radio line emitted by neutral hydrogen at a frequency of 1420 MHz. (see Fig. 7.4 in Chapter 7). The line is, however, expected to be very weak and red-shifted to meter wavelengths because of the expansion of the universe between emission, billions of years ago, and detection at the present epoch. Visit: http://www.ncra.tifr.res.in/ncra/gmrt/ about-gmrt/goals-of-gmrt (courtesy: NCRA , TIFR, India). (downloaded on 26 March 2023).
In the previous seven chapters, we have introduced the barebones of quantum mechanics. The methodology we reviewed equips us to study the physical universe we live in. Spectroscopy is a powerful experimental technique used to investigate matter. Basically, spectroscopy investigates a target system through its interaction with a probe, which can be electromagnetic radiation, or elementary or composite particles, or their combination. Our prototype of the target system is an atom. Atomic spectroscopy, or more generally atomic physics and quantum physics developed synchronously. These disciplines continue to interpenetrate each other to jointly push the frontiers of science, engineering, and technology.
8.1 Spectroscopic Oscillator Strengths
Spectroscopy literature is embellished by terminology from classical, semi-classical, and quantum-mechanical models. An all too pervasive term employed in the description of spectral transitions is the oscillator strength [1, 2]. It has its origins in the earliest explanatory models that used classical mechanics. The phenomenology pertaining to the spectroscopic oscillator strength is now comprehensively integrated into the fully quantum mechanical scheme. It is insightful to track the metamorphosis of the term oscillator strength from its earliest avatar in semi-classical physics to its current usage within the quantum models.
Let us consider a spectral transition in an atom which results from the absorption of electromagnetic energy. It is natural to inquire how much power is pumped by the electric field into the atomic system.
1 - Description of a Physical System
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Summary
The measure of greatness in a scientific idea is the extent to which it stimulates thought and opens up new lines of research.
—P. A. M. DiracFrom our day-to-day experience, we develop our notion of reality. However, our perception of physical properties, such as position and momentum, needs refinement to describe natural phenomena correctly. In this chapter we introduce fundamental principles of the quantum theory that does so with enduring cogency. The laws of nature that govern the functioning of the physical universe cannot be accounted for using classical physics of Newton, Lagrange, and Hamilton. Foundational principles and mathematical structure of quantum theory are introduced in this chapter.
1.1 Quantum versus Classical Physics Theories
In classical physics, the mechanical state of a system is represented by a point in the position– velocity phase space, or equivalently in the position–momentum phase space. The entire theoretical formalism of Newtonian–Lagrangian–Hamiltonian mechanics is based on this Galilean conjecture. The classical hypothesis seems appropriate in a large number of physical situations that concern our day-to-day experiences. With this ansatz, the temporal evolution of a system is described by the trajectory of the point in the phase space. The trajectory is obtained from the equation of motion that governs the time dependence of position and velocity, represented respectively by q and (or alternatively the time dependence of position and momentum, represented respectively by q and p). The alternative equations of motion – Newton’s, Lagrange’s, and Hamilton's – are equivalent. Their applicability must be reconciled with the upper limit on accuracy with which conjugate physical properties of an object, viz. position and momentum, are simultaneously measured. There is, however, an inverse relation between the accuracy of simultaneous measurement of these two properties. The more accurately you measure either, the less accurately can you measure the other. The act of measuring either of the conjugate properties requires an observation. Observations resulting in accurate measurements of conjugate variables are, however, not compatible with each other. Heisenberg's principle of uncertainty is the quantitative expression of this law of nature. It is expressed as a rigorous mathematical inequality that is neatly written in a compact form. Nonetheless, we refrain from advancing its mathematical expression too soon. It has no classical analogue. It cannot be written in any terms of what we are familiar with from classical mechanics.
Preface
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Summary
A graduate course on quantum mechanics is a daunting task – for both students and teachers. Students come for such a course with a fair amount of background in classical physics, classical in the sense that it is time-tested. They are familiar with the works of Newton, Lagrange, Hamilton, Euler, etc. In this scheme, an object's physical state is described by its position q and momentum p, and temporal evolution by Hamilton's equations of motion for the time rates and. Their experience with classical physics entrenches their faith in it and builds their intuition, but they must now be taught that a physical theory that requires simultaneous knowledge of position and momentum is fundamentally untenable. Students must now settle with the fact that classical mechanics ‘works’ only when it is a very good approximation to a more appropriate theory of Nature, which is quantum mechanics. The foundational principles of quantum mechanics conflict with those of classical physics, causing confusion and doubt. Overcoming the resulting befuddlement involves learning what seems like an abstract formalism, which nonetheless turned out to be an unassailable theory of practical value. It changed our lives in the last century with quantum devices, and is now all set to take another leap into the second quantum revolution. It ushers in mind-blowing technology driven by entanglement and quantum computing.
The route to diligent applications of quantum mechanics begins with a shock. Students must grapple with formidable challenges on the path to comprehending consequential principles in a mystified territory. They have to develop proficiency in new methodologies involving abstract mathematics before they can see for themselves that quantum theory simply works; nothing succeeds like success. They can then use the theory to propel the frontiers of sciences, engineering, and technology. Amid this bewilderment, a graduate course in quantum mechanics is as romantic as it is challenging. One must learn to see beyond the corners of your vision, acquire rigorous capabilities in mathematics, enjoy luminous discourses between brilliant minds, cultivate an inventiveness to develop new technology that impacts human life, and understand the cosmos. Quantum mechanics: formalism, methodologies, and applications is a vast subject, very young compared to classical physics, but a very rich field to which some of the most outstanding intellectuals have made dazzling contributions during the past hundred odd years.
9 - The Many-Electron Atom
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Summary
It may well be that the high-speed digital computer will have as great an influence on civilization as the advent of nuclear power.
—Douglas R. HartreeStatistics is intrinsic to quantum theory. Description of nature requires it. In classical physics, we take recourse to statistical analysis either when we are not interested in a detailed solution, or when we are unable to cope up with a large amount of data. Statistical methods enable us to extract important and useful information about the system to understand its physical properties. For example, rather than keeping track of kinetic energies of individual molecules, we determine their average, and benefit from the notion of temperature. The great debate between Albert Einstein and Niels Bohr in the late 1920s and in the 1930s eventually established (especially after the work of John Bell in 1964, discussed in Chapter 11) that the role of statistics in describing nature is far deeper than was suspected earlier. Statistics must be invoked to describe physical properties of nature even when we are dealing with a single particle, or for that matter even vacuum. In this chapter, we study another important manifestation of the role of statistics in quantum theory; this comes from the identity of particles in nature.
9.1 Symmetry Properties of Wavefunctions for Bosons and Fermions
If we have ten electrons, classical physics would regard the particles as distinguishable; the ten electrons could be numbered from one through ten, and one could, at least in principle, follow the dynamics of a particular, say the seventh, electron. Electrons are fundamental particles in nature. They are not amenable to their description by classical statistics. They must be described by quantum theory. In an N-electron system, it is impossible to tag any of these electrons by a number, such as the seventh. This impacts how the electrons occupy energy levels available to them.
The smallest many-particles system is a pair of identical particles. If we subject the pair of particles to an interchange, effected by the operator, and then interchange them yet again, we must get the original state. We expect the double interchange to be the identity operator. We therefore write
where the two-particle state is represented by, with representing the coordinates of the two particles. These coordinates would include not only the three space coordinates but also the spin coordinate.
6 - Approximation Methods
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Summary
One of the basic rules of the universe is that nothing is perfect. Perfection simply doesn't exist…..Without imperfection, neither you nor I would exist
—Stephen Hawking (1942–2018)Approximations are made in mathematics, physics, engineering, and life sciences for a variety of reasons such as (a) obtaining an exact solution is not possible and (b) an exact solution is not necessary, subject to a given context. Both of these factors are important in the development of approximations. We have already seen in Chapter 2 that out of the infinite alternative paths accessible to a system due to their entanglement/superposition, the classical path that makes action stationary results from the condition that action is much larger than the PEB constant. When this condition is satisfied, laws of classical physics provide an excellent approximation to quantum mechanics. In Chapter 2, we observed that the interpretation of the wavefunction as probability amplitude became the basis of the path integral formulation of quantum mechanics, in which the propagator's phase is the action. Considering this relationship, it is appropriate to wonder if the Schrödinger equation could have been predicted from classical mechanics, if only the wavefunction (Eq. 6.22, below) was introduced, even just as a definition. In Section 6.1, we demonstrate, in hindsight, how this could have been possible. Of course, historical development of quantum mechanics took place on a different course. We also demonstrate the inverse of this process, viz., how the classical equation of motion is obtainable as an approximation from quantum mechanics in the limit h→0. An approximation scheme often implemented to solve the Schrödinger equation, called the Wentzel–Kramers–Brilloiun–Jeffrey (WKBJ) method, is based on the connections between classical and quantum mechanics. It is introduced in Section 6.1. In Section 6.2, we discuss perturbation methods to obtain approximate solutions to unsolvable problems. Time-independent perturbation methods are discussed in Section 6.2, and time-dependent perturbation methods in Section 6.3. Major non-perturbative approaches to attack complex problems include the adiabatic approximation, the sudden approximation, and the method of variation. These are introduced in Section 6.4.
6.1 Classical Limit of the Schrödinger Equation and the WKBJ Approximation
Readers who are well conversant with the Hamilton–Jacobi (HJ) theory in classical mechanics [1] will be able to skip a significant part of the discussion in this section. It is, however, included here, even if only briefly, for the sake of completeness.
2 - Path Integral Formulation ofQuantum Mechanics
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Summary
We choose to examine a phenomenon which is impossible, absolutely impossible, to explain in any classical way, and which has in it the heart of quantum mechanics. In reality, it contains the only mystery.
—Richard P. FeynmanIn this chapter we show that a reformulation of quantum mechanics, namely Feynman's path integral approach, is equivalent to the earlier ones, due to Schrödinger and Heisenberg. We shall introduce and apply it in this chapter to interpret the Aharonov–Bohm effect, which is considered to be a “quantum wonder.” It underscores the importance of electromagnetic potentials. We shall find that in addition to the dynamical phase introduced in Chapter 1, another angle, namely the geometric phase (Pancharatnam–Berry phase), is an important physical property of the wavefunction whose consequences are measurable.
2.1 Propagator: Propagation of a Quantum of Knowledge
Notwithstanding the equivalence of wave mechanics and matrix mechanics, Schrödinger and Heisenberg did not appreciate each other's methodologies [1]. In 1926, Schrödinger said: “I knew of [Heisenberg’s] theory, of course, but I felt discouraged, not to say repelled, by the methods of transcendental algebra, which appeared difficult to me, and by the lack of visualizability.” Heisenberg's dislike for Schrödinger's wave mechanics was equally intense. In the same year, in a letter to Pauli, he wrote “The more I think about the physical portion of Schrödinger's theory, the more repulsive I find it…. What Schrödinger writes about the visualizability of his theory ‘is probably not quite right,’ in other words it's crap.” In the mean time, Paul A. M. Dirac, who had made path-breaking contributions [2] in that eventful year (1926) to the formulation of quantum mechanics, had drawn a penetrating analogy [3] between classical and quantum mechanics. Dirac's remark drew the attention of Richard P. Feynman, who used it to build the path integral approach to quantum mechanics based on the variational principle.
Feynman was introduced to the principle of extremum action [4] rather early, while in high school. He reveals in his book [5] that “my Physics teacher … Mr. Bader … told me something … absolutely fascinating…. Every time the subject comes up, I work on it … the principle of least (rather, ‘extremum’) action.”
Dedication
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List of Figures
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Contents
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Appendix D - Occupation Number Formalism Second Quantization
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Summary
We might say that the three operators a†, a and n = a†a correspond respectively to the Creator (Brahma), the Destroyer (Shiva), and the Preserver (Vishnu) in Hindu mythology.
—J. J. Sakurai in Advance Quantum MechanicsThe aforementioned remark by Sakurai may be taken in a lighter vein. When we consider matter energy conversion, it does become essential to introduce operators for particle creation and annihilation. We will, however, introduce them in this appendix with a limited objective, to indicate their efficacy in going beyond the Hartree–Fock (HF) self-consistent field (SCF) method (Chapter 9). It would prepare the readers to tackle problems involving a many-electron system going beyond the single-particle approximation, also referred to as the Independent Particle Approximation (IPA). The mathematical machinery we employ to achieve this is the occupation number formalism. Also, it will familiarize the reader with basic tools introduced in Appendix E to solve the quantum mechanical many-electron problem on a quantum computer (Chapter 11). Much of the occupation number formalism was developed by Jordan and Wigner [1, 2].
D.1 Creation and Annihilation Operators
In Chapter 1, we introduced “quantization” as a mathematical framework to describe the laws of nature in a consistent and successful manner. Essentially, it encompassed dispensing with the classical description of a system in terms of the dynamical variables q and p, and replacing them by operators qop and pop. These operate on wavefunctions, which are coordinate representations of state vectors in a Hilbert space. The resulting mathematical contraption initially seemed abstract, but unlike the classical description, it provides a suitable and beneficial description of nature. Quantization leads to discrete energy eigen-spectra when boundary conditions on the differential (Schrödinger) equation are appropriate for bound-states of the physical system under study, as well as to an energy continuum in the case of unbound states. When a bound state and a continuum state are degenerate, and both are accessible to the system, one has meta-stable states (resonances) which may decay (autoionization) into separate fragments of the system. Such a process can also be described as annihilation of a particle in a discrete level and creation of the same in a continuum eigenstate. In particular, the description of atomic photoionization (Section 6.3, Chapter 6) as well as that of an autoionization resonance benefits from a reformulation in terms of annihilation and creation operators.
Index
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Foreword
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Summary
Since its formulation during the first part of the twentieth century, quantum mechanics has fascinated everybody who has tried to grasp it. Classical physics regarded the world to be deterministic; it claimed that if we just knew everything with enough precision, we should be able to predict what will happen tomorrow. Laws of nature, however, can be best explained by quantum mechanics, which is very different from classical physics: only the probability of a certain outcome of an experiment can be predicted. There is also a fundamental limit to how precisely certain pairs of physical quantities can be measured: when we improve the precision of measurement of one quantity, we lose it on another! Even more mind-boggling is the concept of entanglement. Two entangled particles can travel far from each other and still have a connection so that measurements on one of them immediately forces the other into a specific quantum state, regardless of the distance between them. Through the history of quantum mechanics, accomplished scholars and students alike have found this hard to accept, and argued that the theory must not be complete, that we are still waiting for its final version. Nevertheless, quantum mechanics has been proven to be a very successful theory. As far as we know, its predictions are all correct and technologies based on quantum mechanics are nowadays used everywhere: the smart electronic devices in our pockets, the energy efficient LED lamps, and the solar panels that harvest sunlight – deep inside they function because of the laws of nature explained by quantum mechanics.
It is often said that it is not possible to really understand quantum mechanics. This might be true, but with enough effort it is certainly possible to learn to master its machinery and use it to explain physical phenomena and develop new technology. Professor Pranawa Deshmukh writes in this book: “Quantum theory may shock and confuse us, but it is a successful theory of the physical world. It is cast in a mathematical framework which must be learned with patience and rigour.”
As a university teacher I know that the first course in quantum mechanics brings something special to many students. While classical physics seems to be completely settled and just for new generations to learn, quantum mechanics comes with surprises, riddles, and philosophical discussions.
Appendix E - Electron Structure Studies with Qubits
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Summary
Accurate prediction of chemical and material properties from first principles quantum chemistry is a challenging task on traditional computers. Recent developments in quantum computation offer a route toward highly accurate solutions with polynomial cost.
—Jarrod R. McClean, Ryan Babbush, Peter J. Love, and Alán Aspuru-Guzik, J. Phys. Chem. Lett. , 24:4368– 4380 (2014), https://pubs.acs.org/ doi/10.1021/jz501649m.Information processing employing mathematical modeling using qubits has enormous potential in drug development for clinical trials against dreadful diseases. There are many different ways in which a molecule can be folded to optimize a chemical reaction. Designing smart materials for emerging technologies also requires mathematical simulations, most efficiently implemented on a quantum computer. In this appendix, we provide a cursory introduction to the young and expanding field of electron structure studies with qubits.
The original meaning of the term quantum supremacy proposed by John Preskill in 2012 was intended to describe the point where quantum computers can do things that classical computers cannot. It is often interpreted as the demonstrated and quantified ability to process any problem faster on a quantum computer than on a classic computer. The term quantum advantage is also much in vogue; it is used to describe attainment of a quantum computational algorithm in solving a real-world problem faster than on a classical computer. Platforms for the development of quantum computing architecture include (a) quantum gate–based (Chapter 11) and (b) quantum annealing–based approach (which employs optimization techniques akin to those in operations research). Industry giants such as Google, Honeywell, IBM, and Intel use the quantum gate–based platform, while D-wave systems employs quantum annealing.
The quantum phase estimation (QPE) was the first algorithm that was proposed to solve the Schrödinger equation on a quantum computer. It is a fully quantum algorithm to obtain eigenvalues of a Hamiltonian, but it requires rather sophisticated hardware and employs the inverse quantum Fourier transform (IQFT) method. It is a multipurpose program that is a part of other quantum algorithms, including Shor's algorithm. A full configuration-interaction computation that provides variationally the best wavefunction has been carried out using the QPE algorithm [1]. However, QPE requires a very large number of qubits.
An alternative approach employs the variational quantum eigensolver (VQE), which utilizes quantum and classical resources to solve quantum eigenvalue problems [2]. Of specific interest is the study of many-electron correlations.
Appendix C - Spherical Harmonics
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We know from Chapter 4 that the orbital angular momentum operators and commute with each other and can therefore be simultaneously diagonalized in their common eigenbasis. From Eqs. 4.57a,b, these operators are given by
The representation of the simultaneous eigenvectors of and in the coordinate space in various equivalent notations is
where denotes the unit vector along the position vector of an arbitrary point P in space whose polar and azimuthal angles respectively are and, shown in Fig. C.1.
The functions are called as spherical harmonics. They satisfy the following equations:
Writing the eigenvalue equation for as
we find that the differential equation to be solved for the spherical harmonics is
From Chapter 4, we already know that the eigenvalue of the operator is. Hence, we shall set hereafter. The polar angle _ and the azimuthal angle _ are independent degrees of freedom. Hence, we seek a solution to the above differential equation using the method of separation of variables and factorize the spherical harmonics into a function of only the polar angle, and another of the azimuthal angle alone:
Insertion of Eq. C.8 in C.7 provides a neat separation of the partial differential equation C.7,
where the left-hand side depends only on the azimuthal angle and the right-hand side only on the polar angle. We may therefore set each side to be a constant, and choose this constant to be m2 wherein m is to be determined. It would soon be seen that this choice turns out to be a particularly convenient one. The two independent ordinary differential equations to be now solved are
The boundary condition determines the solution of Eq. C.10 to be
where is an arbitrary constant and, i.e., zero, or a positive or negative integer, thus ratifying the choice of the constant of separation we had made to be a convenient one.
It is now expedient to solve the polar equation by introducing an auxiliary variable
Correspondingly
The differential equation corresponding to Eq. C.11 satisfied by is
For, the equation reduces to
Equations C.15a,b are known as the Legendre's differential equation, and Eqs. C.14a,b as the associated Legendre differential equation, after the French mathematician Adrien-Marie Legendre (1752–1833). Equation C.15 remains invariant as, and correspondingly, so the functions are symmetric or anti-symmetric with respect to the XY-plane.
10 - Quantum Collisions
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Summary
How wonderful that we have met with a paradox. Now we have some hope of making progress
—Niels BohrProbing an elementary or composite particle, an atom, an ion, a molecule, a cluster, or, for that matter any quantum system, involves studying how the target responds to a query – an investigation that is made using a probe that could be electromagnetic radiation (a photon or a beam of light that is incident on the target), or impinging the target with some particles, such as electrons, positrons, neutrons, α-particles, or composites of the same such as atoms, ions, and molecules. Typically, the investigation is called “spectroscopy” when the probe is electromagnetic radiation that is absorbed, scattered or reemitted by the target, which is the object of investigation. When the probe is some other particle, it is usually called “collisions.” The quantum mechanics of spectroscopy and collisions is, however, very closely and seamlessly related, as we shall uncover in this chapter. Niels Bohr's remark quoted above in the frame of a diagram depicting collisions signposts the fact that studies of quantum collisions have resulted in many landmark developments in physics.
10.1 Partial Wave Analysis, Faxen–Holstmark Equation for Potential Scattering
Very commonly, quantum collisions are analyzed using what is called as partial wave analysis, which is a mathematical framework developed by Hilding Faxen and Johan Holtsmark in 1927 [1–4]. The Faxen–Holtsmark theory aims at investigating a target T using a monoenergetic incident beam of projectile particles P. Figures 10.1a–d schematically illustrate the scattering process. A monoenergetic beam of incident particles represented by a wavepacket in Fig. 10.1a enters an apparatus containing the target atoms. The polar axis of this coordinate frame is the Z-axis of a Cartesian coordinate system that is chosen to be along the direction of incidence of the probe particles – also referred to as projectiles. Information about the target is obtained from the interaction between the projectiles and the target. The probability of encounter between the incident and the target particles is of primary interest in the scattering formalism. A measure of the encounter probability is provided by the ratio
The flux of the incident particles is
where NP is the number of probing particles reaching the target per unit time, and S is the effective cross-sectional area of the incident beam that enters the apparatus through the collimator.
Appendix B - Schrödinger, Heisenberg, and Dirac “Pictures” of Quantum Dynamics
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- 04 January 2024, pp 582-586
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Summary
A consistent description of the physical state of a system is provided by its wavefunction whose time-evolution is described by the Schrödinger equation
The wavefunction, is the coordinate representation of the state vector in the Hilbert space that describes the system. Unitary transformations of an orthonormal basis set that spans the Hilbert space amount to rotation of the basis set. An example of this is the unitary transformation from basis to using the Clebsch– Gordan coefficients that we discussed in Chapter 4. Such unitary transformations preserve the norm of the state vectors, and alternative basis sets connected by them provide mathematically equivalent descriptions of quantum mechanics. Preference of using one basis over another is dictated by algebraic elegance.
Alternative descriptions of the temporal evolution of a physical system are possible using generalized rotations that leave the physics invariant, but alter the description of the temporal evolution of the system. Whereas the Schrödinger picture describes temporal evolution of a physical system using methodologies in which the operators are independent of time, and all the time-dependence appears in the wavefunctions, in the Heisenberg picture all the time-dependence is contained in the operators, while the wavefunctions are considered independent of time. In the Dirac picture (also called as the Interaction picture), both the wavefunctions and the operators are considered to be time-dependent. The three pictures are essentially equivalent, and transformations from any one of them to any other are effected using generalized rotations brought about by unitary transformations described below.
The time-evolution operator in the Schrödinger picture is given by Eq. 1.86b (Chapter 1). If the reference time t0 is considered to be zero, the time evolution of a physical state is described by
where the exponential operator is
which gives the dynamical phase (Eq. 1.114b in Chapter 1) of a stationary state:
Operators like q, p, H are independent of time in the Schrödinger picture.
11 - Introduction to Quantum Information and Quantum Computing
- P. C. Deshmukh, Indian Institute of Technology, Tirupati, India
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- Quantum Mechanics
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- 14 September 2023
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- 04 January 2024, pp 507-563
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When Einstein died, his greatest rival, Bohr, found for him words of moving admiration. When a few years later Bohr in turn died, someone took a photograph of the blackboard in his study. There's a drawing on it. A drawing of the ‘light-filled box’ in Einstein's thought experiment. To the very last, the desire to challenge oneself and understand more. And to the very last: doubt.
—Carlo RovelliIn this chapter we shall study how quantum entanglement is tested in a laboratory experiment, and how it empowers us to boost computing powers to unprecedented levels. We develop our notion of reality from our day-to-day experiences. Quantum theory is largely counterintuitive because it conflicts with our naïve and untutored perceptions of position and momentum. It accounts for physical events in the universe with enduring cogency; but it demands reconciliation with the principle of uncertainty and a consequent statistical description of nature. Quantum theory has impacted science, technology, and also human lifestyle, notwithstanding the fact that relations such as Eq. 1.105 (Chapter 1) and Eq. 3.3 (Chapter 3) characterize quantum theory as essentially probabilistic. Einstein's famous quote “God does not play dice” grossly undervalues his unease, and also his insight, in quantum physics. Bohr's proverbial response “it is not your job to tell God what to do,” on the other hand, underscores not just his confidence in quantum theory but also his extraordinary insight in an exhaustive discernment of the laws of nature. The previous ten chapters are inspired by the triumph of quantum mechanics. In the present chapter, we revisit a few elements of the Bohr–Einstein deliberations and also the works of John Bell three decades later, which provided a methodology, based on which experiments could be performed to obtain clarity on the probability conundrum in quantum theory. In the meantime, intellectual churning over half a century since the Bohr–Einstein debates led to a deeper understanding of the principle of superposition and entanglement. The Bohr–Einstein debates immortalized the fifth Solvay conference held in 1927 [1], but continued through subsequent years, with two major publications in 1935 – one by Einstein, Podolsky, and Rosen [2], and the other by Bohr [3] – providing major landmarks. In-depth analysis of the works triggered by Einstein and Bohr, and later by John Bell [4], has now emerged as a robust cornerstone of quantum information science and quantum computing, heralding the second quantum revolution.