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Morphological and structural evolutions of nonequilibrium titanium-nitride alloy powders produced by reactive ball milling

Published online by Cambridge University Press:  31 January 2011

M. Sherif El-Eskandarany ,
K. Sumiyama ,
K. Aoki  and
K. Suzuki
M. Sherif El-Eskandarany
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
K. Sumiyama
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
K. Aoki
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
K. Suzuki
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
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Abstract

Nonequilibrium titanium-nitride alloy powders have been fabricated by a high energetic ball mill under nitrogen gas flow at room temperature and characterized by means of x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and differential scanning calorimetry. Initial hcp titanium is completely transformed to nonequilibrium-fcc Ti–N after 720 ks of the milling time. The fcc Ti–N phase is stable at relatively low temperature and transforms at 855 K to Ti2N and δ phases. At the final stage of milling, the particle- and grain-sizes of alloy powders are 1 mm and 5 nm, respectively, and the lattice parameter is 0.419 nm.

Type
Articles
Information
Journal of Materials Research , Volume 7 , Issue 4 , April 1992 , pp. 888 - 893
Copyright
Copyright © Materials Research Society 1992

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References

1.Koch, C. C., Cavin, O. B., McKamey, C. G., and Scarbrough, J. D., Appl. Phys. Lett. 43, 1017 (1983).Google Scholar
2.El-Eskandarany, M. Sherif, Aoki, K., and Suzuki, K., J. Less-Common Met. 167, 113 (1990).Google Scholar
3.El-Eskandarany, M. Sherif, Itoh, F., Aoki, K., and Suzuki, K., Non-Cryst, J.. Solids 117/118, 729 (1990).Google Scholar
4.El-Eskandarany, M. Sherif, Aoki, K., Itoh, H., and Suzuki, K., J. Less-Common Met. 169, 235 (1991).Google Scholar
5.El-Eskandarany, M. Sherif, Aoki, K., and Suzuki, K., Scripta Metall. 25, 1695 (1991).CrossRefGoogle Scholar
6.El-Eskandarany, M. Sherif, Aoki, K., and Suzuki, K., in Proc. of 5th Int. Conf. on the Structure of Non-Crystalline Materials (NCM 5), Akiu-Sendai, Japan, September 2–6, 1991, edited by Suzuki, K. (in press).Google Scholar
7.El-Eskandarany, M. Sherif, Aoki, K., and Suzuki, K., Alloys, J. and Compounds (J. Less-Common Met.) (1991, in press).Google Scholar
8.Batalla, E. and Zwartz, E.G., J. Mater. Res. 5, 1802 (1990).Google Scholar
9.El-Eskandarany, M. Sherif, Aoki, K., and Suzuki, K., J. Appl. Phys. (1991, in press).Google Scholar
10.El-Eskandarany, M. Sherif, Sumiyama, K., Aoki, K., and Suzuki, K., in Proc. of Int. Syrnp. on Mechanical Alloying (ISMA), Kyoto, Japan, May 7–10, 1991, edited by P.H. Shingu (in press).Google Scholar
11.Calka, A., Appl. Phys. Lett. 59, 1568 (1991).CrossRefGoogle Scholar
12.Jack, K. H., Acta Cryst. 3, 392 (1950).Google Scholar
13.Munir, Z. A., Ceram. Bull. 67, 342 (1988).Google Scholar
14.Nakamura, K., Inagawa, K., Tsuruoka, K., and Komiya, S., Thin Solid Films 40, 155 (1977).CrossRefGoogle Scholar
15.Deevi, S. and Munir, Z. A., J. Mater. Res. 5, 2177 (1990).Google Scholar
16.Tsunekawa, Y., Hirai, H., Okumiya, M., and Niimi, I., J. of Thermal Spraying Soc. Jpn. 26, 1150 (1989).Google Scholar
17.Wriedt, H. A. and Murray, J. L., Bulletin of Alloy Phase Diagrams 4, 412 (1987).Google Scholar
18.Guinier, A., X-ray Diffraction (Freeman, San Francisco, CA, 1963), p. 124.Google Scholar
19.Beattie, J. H. and Versnyder, F., Trans. Am. Soc. Met. 45, 397 (1953).Google Scholar