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Ultrathin NiO nanoflakes perpendicularly oriented on carbon nanotubes as lithium ion battery anode

Published online by Cambridge University Press:  20 August 2013

Jialiang Zhong ,
Oh B. Chae ,
Wei Shi ,
Jianzhang Fan ,
Hongyu Mi  and
Seung Mo Oh
Jialiang Zhong
Affiliation:
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, People’s Republic of China
Oh B. Chae
Affiliation:
Department of Chemical and Biological Engineering and World Class University (WCU) program of Chemical Convergence for Energy & Environment (C2E2), Seoul National University, Seoul 151-744, Korea
Wei Shi
Affiliation:
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, People’s Republic of China
Jianzhang Fan
Affiliation:
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, People’s Republic of China
Hongyu Mi*
Affiliation:
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, People’s Republic of China
Seung Mo Oh*
Affiliation:
Department of Chemical and Biological Engineering and World Class University (WCU) program of Chemical Convergence for Energy & Environment (C2E2), Seoul National University, Seoul 151-744, Korea
*
a)Address all correspondence to these authors. e-mail: mmihongyu@163.com
b)e-mail: seungoh@plaza.snu.ac.kr
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Abstract

Core–shell nickel oxide/carbon nanotube (CNT) microwires, with interconnected nickel oxide nanoflakes (∼10 nm in thickness) vertically oriented on polymer-based CNTs, were synthesized by using low-cost starting materials and a scalable growth route. As revealed by morphological characterization, sheet–sheet and wire–wire interwoven of the composite constructed a porous structure. The composite as lithium ion battery anode exhibited high reversible capacity of 752 mAh/g at a current density of 100 mA/g over 30 cycles with 82% capacity retention. Even at high rate (1000 mA/g), the composite still delivered a high charge capacity (304 mAh/g) over 25 cycles. When the rate was reset to its initial value, 87.7% of the initial charge capacity was recovered. The composite showed remarkably enhanced performance compared to pure NiO, which was presumably due to the advantages of porous structure, oriented attachment, and attractive synergetic effect.

Keywords

compositeenergy storagemicrostructure
Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 18 , 28 September 2013 , pp. 2577 - 2583
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Etacheri, V., Marom, R., Elazari, R., Salitra, G., and Aurbach, D.: Challenges in the development of advanced Li-ion batteries: A review. Energy Environ. Sci. 4, 3243 (2011).CrossRefGoogle Scholar
Cabana, J., Monconduit, L., Larcher, D., and Palacin, M.R.: Beyond intercalation-based Li-ion batteries: The state of the art and challenges of electrode materials reacting through conversion reactions. Adv. Mater. 22, E170 (2010).CrossRefGoogle Scholar
Thackeray, M.M., Wolverton, C., and Isaacs, E.D.: Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ Sci. 5, 7854 (2012).CrossRefGoogle Scholar
Aravindan, V., Gnanaraj, J., Lee, Y.S., and Madhavi, S.: LiMnPO4-a next generation cathode material for lithium-ion batteries. J. Mater. Chem. 2013, 1, 3518.CrossRefGoogle Scholar
Choi, N.S., Chen, Z.H., Freunberger, S.A., Ji, X.L., Sun, Y.K., Amine, K., Yushin, G., Nazar, L.F., Cho, J., and Bruce, P.G.: Challenges facing lithium batteries and electrical double-layer capacitors. Angew. Chem. Int. Ed. 51, 9994 (2012).CrossRefGoogle ScholarPubMed
Ge, M.Y., Rong, J.P., Fang, X., and Zhou, C.W.: Porous doped silicon nanowires for lithium ion battery anode with long cycle life. Nano Lett. 12, 2318 (2012).CrossRefGoogle ScholarPubMed
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., and Tarascon, J.M.: Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407, 496 (2000).CrossRefGoogle ScholarPubMed
Wang, B., Cheng, J.L., Wu, Y.P., Wang, D., and He, D.N.: Porous NiO fibers prepared by electrospinning as high performance anode materials for lithium ion batteries. Electrochem. Commun. 23, 5 (2012).CrossRefGoogle Scholar
Aravindan, V., Kumar, P.S., Sundaramurthy, J., Ling, W.C., Ramakrishna, S., and Madhavi, S.: Electrospun NiO nanofibers as high performance anode material for Li-ion batteries. J. Power Sources 227, 284 (2013).CrossRefGoogle Scholar
Nuli, Y.N., Zhang, P., Guo, Z.P., Liu, H.K., Yang, J., and Wang, J.L.: Nickel-cobalt oxides/carbon nanoflakes as anode materials for lithium-ion batteries. Mater. Res. Bull. 44, 140 (2009).CrossRefGoogle Scholar
Pan, Q.M., Qin, L.M., Liu, J., and Wang, H.B.: Flower-like ZnO–NiO–C films with high reversible capacity and rate capability for lithium-ion batteries. Electrochim. Acta 55, 5780 (2010).CrossRefGoogle Scholar
Xia, Y., Zhang, W.K., Xiao, Z., Huang, H., Zeng, H.J., Chen, X.R., Chen, F., Gan, Y.P., and Tao, X.Y.: Biotemplated fabrication of hierarchically porous NiO/C composite from lotus pollen grains for lithium-ion batteries. J. Mater. Chem. 22, 9209 (2012).CrossRefGoogle Scholar
Cheng, M.Y. and Hwang, B.J.: Mesoporous carbon-encapasulated NiO nanocomposite negative electrode materials for high-rate Li-ion battery. J. Power Sources 195, 4977 (2010).CrossRefGoogle Scholar
Li, T., Ni, S.B., Lv, X.H., Yang, X.L., and Duan, S.: Preparation of NiO-Ni/natural graphite composite anode for lithium ion batteries. J. Alloys Compd. 553, 167 (2013).CrossRefGoogle Scholar
Rahman, M.M., Chou, S.L., Zhong, C., Wang, J.Z., Wexler, D., and Liu, H.K.: Spray pyrolyzed NiO–C nanocomposite as an anode material for the lithium-ion battery with enhanced capacity retention. Solid State Ionics 180, 1646 (2010).CrossRefGoogle Scholar
Lu, H.W., Li, D., Sun, K., Li, Y.S., and Fu, Z.W.: Carbon nanotube reinforced NiO fibers for rechargeable lithium batteries. Solid State Sci. 11, 982 (2009).CrossRefGoogle Scholar
Kottegoda, I.R.M., Idris, N.H., Lu, L., Wang, J.Z., and Liu, H.K.: Synthesis and characterization of graphene-nickle oxide nanostructures for fast charge-discharge application. Electrochim. Acta 56, 5815 (2011).CrossRefGoogle Scholar
Mai, Y.J., Shi, S.J., Zhang, D., Lu, Y., Gu, C.D., and Tu, J.P.: NiO-graphene hybrid as an anode material for lithium ion batteries. J. Power Sources 204, 155 (2012).CrossRefGoogle Scholar
Zhu, X.J., Hu, J., Dai, H.L., and Jiang, L.: Reduced graphene oxide and nanosheet-based nickel oxide microsphere composite as an anode material for lithium ion batteries. Electrochim. Acta 64, 23 (2012).CrossRefGoogle Scholar
Xu, C.H., Sun, J., and Gao, L.: large scale synthesis of nickel oxide/multiwalled carbon nanotube composites by direct thermal decomposition and their lithium storage properties. J. Power Sources 196, 5138 (2011).CrossRefGoogle Scholar
Hwang, S.G., Kim, G.O., Yun, S.R., and Ryu, K.S.: NiO nanoparticles with plate structure growth on graphene as fast charge-discharge anode materials for lithium ion batteries. Electrochim. Acta 78, 406 (2012).CrossRefGoogle Scholar
Zhou, G.M., Wang, D.W., Yin, L.C., Li, N., Li, F., and Cheng, H.M.: Oxygen bridges between NiO nanosheets and graphene for improvement of lithium storage. ACS Nano 6, 3214 (2012).CrossRefGoogle ScholarPubMed
Fan, J.Z., Mi, H.Y., Xu, Y.L., and Gao, B.: In situ fabrication of Ni(OH)2 nanofibers on polypyrrole-based carbon nanotubes for high-capacitance supercapacitors. Mater. Res. Bull. 48, 1342 (2013).CrossRefGoogle Scholar
Palanisamy, P. and Raichur, A.M.: Synthesis of spherical NiO nanoparticles through a novel biosurfactant mediated emulsion technique. Mater. Sci. Eng., C 29, 199 (2009).CrossRefGoogle Scholar
Li, Q.Y., Wang, R.N., Nie, Z.R., Wang, Z.H., and Wei, Q.: Preparation and characterization of nanostructured Ni(OH)2 and NiO thin films by a simple solution growth process. J. Colloid Interface Sci. 320, 254 (2008).CrossRefGoogle ScholarPubMed
Shi, C.S., Wang, G.Q., Zhao, N.Q., Du, X.W., and Li, J.J.: NiO nanotubes assembled in pores of porous anodic alumina and their optical absorption properties. Chem. Phys. Lett. 454, 75 (2008).CrossRefGoogle Scholar
Song, M.K., Par, S.J., Alamgir, F.M., Cho, J., and Liu, M.L.: Nanostructured electrodes for lithium-ion and lithium-air batteries. The latest developments, challenges, and perspectives. Mater. Sci. Eng., R 72, 203 (2011).CrossRefGoogle Scholar
Kalam, A., Al-Shihri, A.S., Al-Sehemi, A.G., Awwad, N.S., Du, G.H., and Ahmad, T.: Effect of pH on solvothermal synthesis of β-Ni(OH)2 and NiO nano-architectures: Surface area studies, optical properties and adsorption studies. Superlattice Microstruct. 55, 83 (2013).CrossRefGoogle Scholar
Yang, C.M., Weidenthaler, C., Spliethoff, B., Mayanna, M., and Schuth, F.: Facile template synthesis of ordered mesoporous carbon with polypyrrole as carbon precursor. Chem. Mater. 17, 355 (2005).CrossRefGoogle Scholar
Chen, X., Zhang, N.Q., and Sun, K.N.: Facile ammonia-induced fabrication of nanoporous NiO films with enhanced lithium-storage properties. Electrochem. Commun. 20, 137 (2012).CrossRefGoogle Scholar
Wu, H., Xu, M., Wu, H.Y., Xu, J.J., Wang, Y.L., Peng, Z., and Zheng, G.F.: Aligned NiO nanoflake arrays grown on copper as high capacity lithium-ion battery anodes. J. Mater. Chem. 22, 19821 (2012).CrossRefGoogle Scholar
Xie, D., Yuan, W.W., Dong, Z.M., Su, Q.M., Zhang, J., and Du, G.H.: Facile synthesis of porous NiO hollow microspheres and its electrochemical lithium-storage performance. Electrochim. Acta 92, 87 (2013).CrossRefGoogle Scholar
Débart, A., Dupont, L., Poizot, P., Lerichen, J.B., and Tarascon, J.M.: A transmission electron microscopy study of the reactivity mechanism of tailor-made CuO particles toward lithium. J. Eletrochem. Soc. 148, A1266 (2001).CrossRefGoogle Scholar
Varghese, B., Reddy, M.V., Zhu, Y., Lit, C.S., Hoong, T.C., Subba Rao, G.V., Chowdari, B.V.R., Wee, A.T.S., Lim, C.T., and Sow, C.H.: Fabrication of NiO nanowall electrodes for high performance lithium ion battery. Chem. Mater. 20, 3360 (2008).CrossRefGoogle Scholar
Huang, X.H., Tu, J.P., Zhang, B., Xhang, C.Q., Li, Y., Yuan, Y.F., and Wu, H.M.: Electrochemical properties of NiO–Ni nanocomposite as anode material for lithium ion batteries. J. Power Sources 161, 541 (2006).CrossRefGoogle Scholar
Liu, X.G., Or, S.W., Jin, C.G., Lv, Y.H., Feng, C., and Sun, Y.P.: NiO/C nanocapsules with onion-like carbon shell as anode material for lithium ion batteries. Carbon 60, 215 (2013).CrossRefGoogle Scholar
Zou, Y.Q. and Wang, Y.: NiO nanosheets grown on graphene nanosheets as superior anode materials for Li-ion batteries. Nanoscale 3, 2615 (2011).CrossRefGoogle ScholarPubMed
Ci, S.Q., Zou, J.P., Zeng, G.S., Sheng, Q., Luo, S.L., and Wen, Z.H.: Improved electrochemical properties of single crystalline NiO nanoflakes fro lithium storage and oxygen electroreduction. RSC Adv. 2, 5185 (2012).CrossRefGoogle Scholar