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Classification and consequences of complex lead perovskite ferroelectrics with regard to B-site cation order

  • C. A. Randall (a1), A. S. Bhalla (a1), T. R. Shrout (a1) and L. E. Cross (a1)
  • DOI:
  • Published online: 01 January 2011

From a number of studies on ferroelectric and related materials based on complex lead perovskites [Pb(Bx′B1−x″)O3], it is apparent that the B-site cation order influences the crystallography, phase transitions, and other physical properties. A classification of complex lead perovskites is presented based on the relative scale of long-range cation order. In particular, we discuss the implications of cation order in relation to relaxor and normal ferroelectric behavior.

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