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Direct synthesis of tin oxide nanotubes on microhotplates using carbon nanotubes as templates

  • Prahalad Parthangal (a1), Richard E. Cavicchi (a2), Douglas C. Meier (a2), Andrew Herzing (a2) and Michael R. Zachariah (a3)...

Tin oxide (SnO2) nanotubes have been synthesized using carbon nanotubes (CNTs) as removable templates. The entire synthesis takes place on the microscale on a micromachined hotplate, without the use of photolithography, taking advantage of the device’s built-in heater. Well-aligned multiwalled CNT forests were grown directly on microhotplates at 600 °C using a bimetallic iron/alumina composite catalyst and acetylene as precursor. Thin films of anhydrous SnO2 were then deposited onto the CNT forests through chemical vapor deposition of tin nitrate at 375 °C. The CNTs were then removed through a simple anneal process in air at temperatures above 450 °C, resulting in SnO2 nanotubes. Gas sensing measurements indicated a substantial improvement in sensitivity to trace concentrations of methanol from the SnO2 nanotubes in comparison with a SnO2 thin film. The synthesis technique is generic and may be used to create any metal oxide nanotube structure directly on microscale substrates.

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28. D.P. Woodruff and T.A. Delchar : Modern Techniques of Surface Science, 2nd ed. (Cambridge University Press, Cambridge, UK, 1994), p. 108.

37. J. Tiffany , R.E. Cavicchi , and S. Semancik : Microarray study of temperature dependent sensitivity and selectivity of metal/oxide sensing interfaces, in Advanced Environmental and Chemical Sensing Technology, Vol. 4205, edited by T. VoDinh and S. Buttgenbach (SPIE-International Society for Optical Engineering, Bellingham, WA, 2001), p. 240.

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Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
  • URL: /core/journals/journal-of-materials-research
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