Skip to main content
×
Home
    • Aa
    • Aa
  • Get access
    Check if you have access via personal or institutional login
  • Cited by 11
  • Cited by
    This article has been cited by the following publications. This list is generated based on data provided by CrossRef.

    Kowalczyk, G. Kordan, V. Stetskiv, A. and Pavlyuk, V. 2016. Lithiation and magnesiation of R5Sn3 (R = Y and Gd) alloys. Intermetallics, Vol. 70, p. 53.


    Balińska, Agnieszka Kordan, Vasyl Misztal, Renata and Pavlyuk, Volodymyr 2015. Electrochemical and thermal insertion of lithium and magnesium into Zr5Sn3. Journal of Solid State Electrochemistry, Vol. 19, Issue. 8, p. 2481.


    Pavlyuk, Volodymyr Milashys, Viktoriya Dmytriv, Grygoriy and Ehrenberg, Helmut 2015. A new tetragonal structure type for Li2B2C. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue. 1, p. 39.


    Pavlyuk, Volodymyr Sozanskyi, Martyn Dmytriv, Grygoriy Indris, Sylvio and Ehrenberg, Helmut 2015. Amendment of the Li-Bi Phase Diagram Crystal and Electronic Structure of Li2Bi. Journal of Phase Equilibria and Diffusion, Vol. 36, Issue. 6, p. 544.


    Chumak, Ihor Hinterstein, Manuel and Ehrenberg, Helmut 2014. Lix(Al0.8Zn0.2) alloys as anode materials for rechargeable Li-ion batteries. Progress in Solid State Chemistry, Vol. 42, Issue. 4, p. 149.


    Chumak, Ihor Pavlyuk, Volodymyr and Ehrenberg, Helmut 2014. Binary Lithium Indides Li22-xIn8+x(x= 0.1), Li11-xIn4+x(x= 1.05), and Li10-xIn2+x(x= 1.59) with Clusters. European Journal of Inorganic Chemistry, Vol. 2014, Issue. 12, p. 2053.


    Pavlyuk, Volodymyr Chumak, Ihor Akselrud, Lev Lidin, Sven and Ehrenberg, Helmut 2014. LiZn4 − x(x= 0.825) as a (3 + 1)-dimensional modulated derivative of hexagonal close packing. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 70, Issue. 2, p. 212.


    Chumak, Ihor Pavlyuk, Volodymyr Dmytriv, Grygoriy Pauly, Hermann and Ehrenberg, Helmut 2013. The crystal and electronic structures of the Li2−xAg1+xIn3 (x=0.05) indide. Journal of Solid State Chemistry, Vol. 197, p. 248.


    Pavlyuk, V. Stetskiv, A. and Rożdżyńska-Kiełbik, B. 2013. The isothermal section of the phase diagram of Li–La–Ge ternary system at 400 °C. Intermetallics, Vol. 43, p. 29.


    Pavlyuk, Volodymyr Chumak, Ihor and Ehrenberg, Helmut 2012. Polymorphism of Li2Zn3. Acta Crystallographica Section B Structural Science, Vol. 68, Issue. 1, p. 34.


    Thoss, Franziska Giebeler, Lars Oswald, Steffen Ehrenberg, Helmut and Eckert, Jürgen 2012. Study on the reversible Li-insertion of amorphous and partially crystalline Al86Ni8La6 and Al86Ni8Y6 alloys as anode materials for Li-ion batteries. Electrochimica Acta, Vol. 60, p. 85.


    ×

Li(Al1–zZnz) alloys as anode materials for rechargeable Li-ion batteries

  • I. Chumak (a1), G. Dmytriv, V. Pavlyuk (a2), S. Oswald, J. Eckert (a1), H. Trill, H. Eckert (a3), H. Pauly (a4) and H. Ehrenberg (a1)
  • DOI: http://dx.doi.org/10.1557/JMR.2010.0191
  • Published online: 01 January 2011
Abstract

The cycling behavior of anode materials based on alloys from the Li(Al1–zZnz) continuous solid solution has been studied. The performance of the most promising composition Li(Al0.8Zn0.2) was tested in half-cells against metallic Li with three different electrolytes and in full Li-ion cells against a V2O5 cathode. The underlying structure evolution during cycling and the most relevant fatigue mechanisms are elucidated by x-ray diffraction, nuclear magnetic resonance, and x-ray photoelectron spectroscopy, and reveal a loss of mobile Li due to the ongoing formation of solid electrolyte interfaces. An enhanced stability for Li(Al1–zZnz) electrodes with z˜0.2 results from a peculiar microstructure due to the decomposition of Al and Zn in the Li-poor state and their intermixing in the Li-rich state.

Copyright
Corresponding author
a)Address all correspondence to this author. e-mail: i.chumak@ifw-dresden.de
b)This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/jmr_policy
Linked references
Hide All

This list contains references from the content that can be linked to their source. For a full set of references and notes please see the PDF or HTML where available.

1.M. Winter , J.O. Besenhard , M.E. Spahr , P. Novák Insertion electrode materials for rechargeable lithium batteries. Adv. Mater. 10, 725(1998)

2.M. Winter , J.O. Besenhard Electrochemical lithiation of tin and tin-based intermetallics and composites. Electrochim. Acta 45, 31(1999)

3.J. Yang , M. Wachtler , M. Winter , J.O. Besenhard Sub-microcrystalline Sn and Sn–SnSb powders as lithium storage materials for lithium-ion batteries. Electrochem. Solid-State Lett. 2, 161(1999)

9.D. Massiot , F. Fayon , M. Capron , I. King , S. Le Calvé , B. Alonso , J.O. Durand , B. Bujoli , Z. Gan , G. Hoatson Modelling one- and two-dimensional solid-state NMR spectra. Magn. Reson. Chem. 40, 70(2002)

10.L. Vegard Die Konstitution der Mischkristalle und die Raumfüllung der Atome. Z. Phys. 5, 17(1921)

11.A.R. Denton , N.W. Ashcroft Vegard's law. Phys. Rev. A 43, 3161(1991)

13.K. Brandt Historical development of secondary lithium batteries. Solid State Ionics 69, 173(1994)

14.R.A. Farrar , H.W. King Axial ratios and solubility limits of H.C.P. η phases in the systems Cd–Au, Cd–Li, and Zn–Li. Metallography 1, 79(1968)

16.M. Wachtler , J.O. Besenhard , M. Winter Tin and tin-based intermetallics as new anode materials for lithium-ion cells. J. Power Sources 94, 189(2001)

17.M. Winter , W.K. Appel , B. Evers , T. Hodal , K-C. Möller , I. Schneider , M. Wachtler , M.R. Wagner , G.H. Wrodnigg , J.O. Besenhard Studies on the anode/electrolyte interface in lithium ion batteries. Monatsh. Chem. 132, 473(2001)

Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
  • URL: /core/journals/journal-of-materials-research
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Keywords: