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Synthesis of titanium boride (TiB)2 nanocrystallites by solution-phase processing

  • Susan E. Bates (a1), William E. Buhro (a1), Claire A. Frey (a2), Shankar M.L. Sastry (a2) and K.F. Kelton (a3)
  • DOI: http://dx.doi.org/10.1557/JMR.1995.2599
  • Published online: 01 March 2011
Abstract

Nanocrystalline TiB2 is prepared by reaction of NaBH4 and TiCl4. The initial solution-phase reaction affords an amorphous precursor powder from which 5-100 nm TiB2 crystallites are obtained upon annealing at 900-1100 °C. Crystallite sizes depend on the annealing temperature and other processing parameters. Crystallite morphology is size dependent; crystallites smaller than 12-15 nm are cuboidal, whereas crystallites larger than 12-15 nm are hexagonal platelets. The procedure affords gram quantities of the smallest available TiB2 nanocrystallites.

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