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Recent developments in ductile bulk metallic glass composites

  • M. Ferry (a1), K.J. Laws (a1), C. White (a1), D.M. Miskovic (a1), K.F. Shamlaye (a1), W. Xu (a1) and O. Biletska (a1)
  • DOI:
  • Published online: 08 January 2013

Offering a unique suite of mechanical, physical, and chemical properties, bulk metallic glasses (BMGs) show significant promise as engineering materials. Unfortunately, most BMGs exhibit low tensile ductility at ambient temperature that limits their use as structural (load-bearing) materials. To overcome this problem, BMG composites (BMGCs) containing a second phase are being developed for improving ductility by controlling the mechanics of shear band nucleation and growth in the glassy matrix, which is the primary mode of failure in these materials. This review describes some recent developments in BMGCs and discusses the influence of the type of second phase on mechanical behavior.

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1.M.M. Trexler and N.N. Thadhani: Mechanical properties of bulk metallic glasses. Prog. Mater. Sci. 55, 759 (2010).

2.A. Inoue and A. Takeuchi: Recent development and application products of bulk glassy alloys. Acta Mater. 59, 2243 (2011).

3.W.H. Wang, C. Dong, and C.H. Shek: Bulk metallic glasses. Mater. Sci. Eng. R 44, 45 (2004).

4.M.F. Ashby and A.L. Greer: Metallic glasses as structural materials. Scripta Mater. 54, 321 (2006).

5.A.L. Greer: Metallic glasses…on the threshold. Mater. Today 12, 14 (2009).

7.J.J. Lewandowski, W.H. Wang, and A.L. Greer: Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 85, 77 (2005).

8.J. Schroers and W.L. Johnson: Ductile bulk metallic glass. Phys. Rev. Lett. 93, 255506 (2004).

9.M.D. Demetriou, M.E. Launey, G. Garrett, J.P. Schramm, D.C. Hofmann, W.L. Johnson, and R.O. Ritchie: A damage-tolerant glass. Nature Mater. 10, 123 (2011).

10.Z. Bian, H. Kato, C.L. Qin, W. Zhang, and A. Inoue: Cu-Hf-Ti-Ag-Ta bulk metallic glass composites and their properties. Acta Mater. 53, 2037 (2005).

11.M.L. Lee, Y. Li, and C.A. Schuh: Effect of a controlled volume fraction of dendritic phases on tensile and compressive ductility in La-based metallic glass matrix composites. Acta Mater. 52, 4121 (2004).

12.L.Q. Xing, J. Eckert, W. Loser, and L. Schultz: High-strength materials produced by precipitation of icosahedral quasicrystals in bulk Zr-Ti-Cu-Ni-Al amorphous alloys. Appl. Phys. Lett. 74, 664 (1999).

13.D.C. Hofmann, J.-Y.S.A. Wiest, , G. Duan, M-L. Lind, M.D. Demetriou, and W.L. Johnson: Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085 (2008).

14.H. Choi-Yim, R.D. Conner, F. Szuecs, and W.L. Johnson: Processing, microstructure and properties of ductile metal particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 50, 2737 (2002).

15.K. Hajlaoui, A.R. Yavari, A. LeMoulec, W.J. Botta, F.G. Vaughan, A.L.G.J. Das, and A. Kvick: Plasticity induced by nanoparticle dispersions in bulk metallic glasses. J. Non-Crystal. Solids 353, 327 (2007).

16.A. Inoue, W. Zhang, T. Tsurui, A.R. Yavari, and A.L. Greer: Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass. Philos. Mag. Lett. 85, 221 (2005).

17.C.C. Hays, C.P. Kim, and W.L. Johnson: Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901 (2000).

18.R.D. Conner, R.B. Dandliker, and W.L. Johnson: Mechanical properties of tungsten and steel fiber reinforced Zr41.25Ti13.75Cu12.5Ni10Be22.5 metallic glass matrix composites. Acta Mater. 46, 6089 (1998).

19.H. Choi-Yim, S.-Y. Lee, and R.D. Conner: Mechanical behavior of Mo and Ta wire-reinforced bulk metallic glass composites. Scripta Mater. 58, 763 (2008).

20.F. Szuecs, C.P. Kim, and W.L. Johnson: Mechanical properties of Zr56.2Ti13.8Nb5.0Cu 6.9Ni5.6Be12.5 ductile phase reinforced bulk metallic glass composite. Acta Mater. 49, 1507 (2001).

21.K.M. Flores, W.L. Johnson, and R.H. Dauskardt: Fracture and fatigue behavior of a Zr-Ti-Nb ductile phase reinforced bulk metallic glass matrix composite. Scripta Mater. 49, 1181 (2003).

23.A. Inoue: Mechanical properties of Zr-based bulk glassy alloys containing nanoscale compound particles. Intermetallics 8, 455 (2000).

24.A. Inoue, B.L. Shen, H. Koshiba, H. Kato, and A.R. Yavari: Ultra-high strength above 5000 MPa and soft magnetic properties of Co-Fe-Ta-B bulk glassy alloys. Acta Mater. 52, 1631 (2004).

25.R.D. Conner, W.L. Johnson, N.E. Paton, and W.D. Nix: Shear bands and cracking of metallic glass plates in bending. J. Appl. Phys. 94, 904 (2003).

26.L.H. Dai and Y.L. Bai: Basic mechanical behaviors and mechanics of shear banding in BMGs. Int. J. Impact Eng. 35, 704 (2008).

28.J. Eckert, J. Das, S. Pauly, and C. Duhamel: Processing routes, microstructure and mechanical properties of metallic glasses and their composites. Adv. Eng. Mater. 9, 443 (2007).

31.M. Kinaka, H. Kato, M. Hasegawa, and A. Inoue: High specific strength Mg-based bulk metallic glass matrix composite highly ductilized by Ti dispersoid. Mater. Sci. Eng A 494, 299 (2008).

32.Z. Zhu, H. Zhang, Z. Hu, W. Zhang, and A. Inoue: Ta-particulate reinforced Zr-based bulk metallic glass matrix composite with tensile plasticity. Scripta Mater. 62, 278 (2010).

33.J. Eckert, M. Seidel, A. Kubler, U. Klement, and L. Schultz: Oxide dispersion strengthened mechanically alloyed amorphous Zr-Al-Cu-Ni composites. Scripta Mater. 38, 595 (1998).

34.H.M. Fu, H.F. Zhang, H. Wang, Q.S. Zhang, and Z.Q. Hu: Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in situ TiC particles. Scripta Mater. 52, 669 (2005).

35.H.K. Lim, E.S. Park, J.S. Park, W.T. Kim, and D.H. Kim: Shear band formation and mechanical properties of cold-rolled bulk metallic glass and metallic glass matrix composite. J. Mater. Sci. 40, 6127 (2005).

38.M.E. Siegrist and J.F. Löffler: Bulk metallic glass-graphite composites. Scripta Mater. 56, 1079 (2007).

39.H. Choi-Yim, R. Busch, U. Köster, and W.L. Johnson: Synthesis and characterization of particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 47, 2455 (1999).

40.J. Schroers, T. Nguyen, and G.A. Croopnick: A novel metallic glass composite synthesis method. Scripta Mater. 56, 177 (2007).

41.J.T. Fan, Z.F. Zhang, S.X. Mao, B.L. Shen, and A. Inoue: Deformation and fracture behaviors of Co-based metallic glass and its composite with dendrites. Intermetallics 17, 445 (2009).

42.J. Das, W. Loser, U. Kuhn, J. Eckert, S.K. Roy, and L. Schultz: High-strength Zr-Nb-(Cu,Ni,Al) composites with enhanced plasticity. Apply. Phys. Lett. 82, 4690 (2003).

43.H. Choi-Yim, R.D. Conner, and W.L. Johnson: In situ composite formation in the Ni-(Cu)-Ti-Zr-Si system. Scripta Mater. 53, 1467 (2005).

44.W. Xu, R. Zheng, K.J. Laws, S.P. Ringer, and M. Ferry: In situ formation of crystalline flakes in Mg-based metallic glass composites by controlled inoculation. Acta Mater. 59, 7776 (2011).

45.L. Robin, K.J. Laws, W. Xu, G. Kurniawan, K. Privat, and M. Ferry: The three-dimensional structure of Mg-rich plates in as-cast mg-based bulk metallic glass composites. Metall. Mater. Trans A 41, 1691 (2010).

46.C.L.C. Fan, D.V. Louzguine, and A. Inoue: Nanocrystalline composites with high strength obtained in Zr-Ti-Ni-Cu-Al bulk amorphous alloys. Appl. Phys. Lett. 75, 340 (1999).

47.X. Hui, W. Dong, G.L. Chen, and K.F. Yao: Formation, microstructure and properties of long-period order structure reinforced Mg-based bulk metallic glass composites. Acta Mater. 55, 907 (2007).

48.H. Tan, Y. Zhang, and Y. Li: Synthesis of La-based in situ bulk metallic glass matrix composite. Intermetallics 10, 1203 (2002).

50.R. Doglione, S. Spriano, and L. Battezzati: Static mechanical characterization of a bulk amorphous and nanocrystalline Zr40Ti14Ni11Cu10Be25 alloy. Nanostruct. Mater. 8, 447 (1997).

51.C.J. Gilbert, R.O. Ritchie, and W.L. Johnson: Fracture toughness and fatigue-crack propagation in a Zr-Ti-Ni-Cu-Be bulk metallic glass. Appl. Phys. Lett. 71, 476 (1997).

52.W. Xu, L. Robin, R. Zheng, K.J. Laws, and M. Ferry: Phase redistribution in an in situ Mg-based bulk metallic glass composite during deformation in the supercooled liquid region. Scripta Mater. 63, 556 (2010).

53.J.R. Strife and K.M. Prewo: Mechanical behaviour of an amorphous metal ribbon reinforced resin-matrix composite. J. Mater. Sci. 17, 359 (1982).

54.C. Fan, C.F. Li, A. Inoue, and V. Haas: Deformation behavior of Zr-based bulk nanocrystalline amorphous alloys. Phys. Rev. B 61, R3761 (2000).

55.X.L. Fu, Y. Li, and C.A. Schuh: Mechanical properties of metallic glass matrix composites: effects of reinforcement character and connectivity. Scripta Mater. 56, 617 (2007).

56.Z.G. Li, X. Hui, C.M. Zhang, and G.L. Chen: Formation of Mg–Cu–Zn–Y bulk metallic glasses with compressive strength over gigapascal. J. Alloys Compds. 454, 168 (2008).

57.J.Z. Liang and R.K.Y. Li: Rubber toughening in polypropylene – a review. J. Appl. Polym. Sci. 77, 409 (2000).

58.D.C. Hofmann: Shape memory bulk metallic glass composites. Science 329, 1294 (2010).

59.S. Pauly, S. Gorantla, G. Wang, U. Kühn, and J. Eckert: Transformation-mediated ductility in CuZr-based bulk metallic glasses. Nature Mater. 9, 473 (2010).

60.S. Pauly, G. Liu, G. Wang, J. Das, K.B. Kim, U. Kühn, and J. Eckert: Modeling deformation behavior of Cu-Zr-Al bulk metallic glass matrix composites. Appl. Phys. Lett. 95, 101906 (2009).

61.P. Gargarella, S. Pauly, K.K. Song, J. Hu, N.S. Barekar, M. Samadi Khoshkhoo, A. Teresiak, H. Wendrock, U. Kühn, C. Ruffing, E. Kerscher, and J. Eckert: Ti-Cu-Ni shape memory bulk metallic glass composites. Acta Mater. 61, 151 (2013).

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