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ART. 275 - On the Law of the Pressure of Gases between 75 and 150 millimetres of Mercury

Published online by Cambridge University Press:  05 December 2011

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Summary

In a recently published paper I have examined, with the aid of a new manometer, the behaviour of gases at very low pressures, rising to 1·5 millims. of mercury, with the result that Boyle's law was verified to a high degree of precision. There is, however, a great gap between the highest pressure there dealt with and that of the atmosphere—a gap which it appeared desirable in some way to bridge over. The sloping manometer, described in the paper referred to, does not lend itself well to the use of much greater pressures, at least if we desire to secure the higher proportional accuracy that should accompany the rise of pressure. The present communication gives the results of observations, by another method, of the law of pressure in gases between 75 millims. and 150 millims. of mercury. It will be seen that for air and hydrogen Boyle's law is verified to the utmost. In the case of oxygen, the agreement is rather less satisfactory, and the accordance of separate observations is less close. But even here the departure from Boyle's law amounts only to one part in 4000, and may perhaps be referred to some reaction between the gas and the mercury. In the case of argon too the deviation, though very small, seems to lie beyond the limits of experimental errors.

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Scientific Papers , pp. 27 - 40
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1912

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