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We perform direct numerical simulations of soluble bubbles dissolving in a Taylor–Couette (TC) flow reactor with a radius ratio of $\eta =0.5$ and Reynolds number in the range $0 \leq Re \leq 5000$, which covers the main regimes of this flow configuration, up to fully turbulent Taylor vortex flow. The numerical method is based on a geometric volume-of-fluid framework for incompressible flows coupled with a phase-change solver that ensures mass conservation of the soluble species, whilst boundary conditions on solid walls are enforced through an embedded boundary approach. The numerical framework is validated extensively against single-phase TC flows and competing mass transfer in multicomponent mixtures for an idealised infinite cylinder and for a bubble rising in a quiescent liquid. Our results show that when bubbles in a TC flow are mainly driven by buoyancy, theoretical formulae derived for spherical interfaces on a vertical trajectory still provide the right fundamental relationship between the bubble Reynolds and Sherwood numbers, which reduces to $Sh \propto \sqrt {Pe}$ for large Péclet values. For bubbles mainly transported by TC flows, the dissolution of bubbles depend on the TC Reynolds number and, for the turbulent configurations, we show that the smallest characteristic turbulent scales control mass transfer, in agreement with the small-eddy model of Lamont & Scott (AIChE J., vol. 16, 1970, pp. 513–519). Finally, the interaction between two aligned bubbles is investigated and we show that a significant increase in mass transfer can be obtained when the rotor of the apparatus is operated at larger speeds.
A heuristic greedy algorithm is developed for efficiently tiling spatially dense redshift surveys. In its first application to the Galaxy and MassAssembly (GAMA) redshift survey we find it rapidly improves the spatial uniformity of our data, and naturally corrects for any spatial bias introduced by the 2dF multi-object spectrograph. We make conservative predictions for the final state of the GAMA redshift survey after our final allocation of time, and can be confident that even if worse than typical weather affects our observations, all of our main survey requirements will be met.
This case illustrates the surgical use of wire localization, a well tried technique from a different field of surgery, in the removal of an ultrasound-detected, impalpable deep lower cervical lymph node in a high-risk patient. A localization needle with an echogenic tip was placed freehand
under ultrasound guidance, immediately before surgery. The imaging and marking of the impalpable cervical lymph node resulted in a precise surgical dissection and a reduction in operating time whilst minimizing risks to the patient and staff.
The spectra of the Sloan Digital Sky Survey (SDSS) are being used to construct a catalogue of QSO absorption lines, for use in studies of abundances, relevant radiation fields, number counts as a function of redshift, and other matters, including the evolution of these parameters. The catalogue includes intervening, associated, and BAL absorbers, in order to allow a clearer definition of the relationships between these three classes. We describe the motivation for and the data products of the project to build the SDSS QSO absorption line catalogue.
We positionally match sources observed by the Sloan Digital Sky Survey (SDSS), the Two Micron All Sky Survey (2MASS), and the Faint Images of the Radio Sky at Twenty-cm (FIRST) survey. Practically all 2MASS sources are matched to an SDSS source within 2 arcsec; ~11% of them are optically resolved galaxies and the rest are dominated by stars. About 1/3 of FIRST sources are matched to an SDSS source within 2 arcsec; ~80% of these are galaxies and the rest are dominated by quasars. Based on these results, we project that by the completion of these surveys the matched samples will include about 107 stars and 106 galaxies observed by both SDSS and 2MASS, and about 250,000 galaxies and 50,000 quasars observed by both SDSS and FIRST. Here we present a preliminary analysis of the optical, infrared and radio properties for the extragalactic sources from the matched samples. In particular, we find that the fraction of quasars with stellar colors missed by the SDSS spectroscopic survey is probably not larger than ~10%, and that the optical colors of radio-loud quasars are ~0.05 mag. redder (with 4σ significance) than the colors of radio-quiet quasars.
Observations of order–disorder phenomena at high pressure in hydrous phases are reinterpreted with the results of Rietveld analysis and neutron-diffraction data. The reported partial amorphization of the hydrogen sublattice in β-Co(OD)2 at 11.2 GPa was not confirmed in powder-diffraction data collected with the Paris-Edinburgh cell to 15.5 GPa. The diffraction data, and perhaps the spectroscopic data on which the observations of amorphization are based, are consistent with an increase in the H…H repulsion with pressure. The structural consequences of competition between H…H repulsion and H-bond (O—H…O) formation is observed in the M(OH)2 compounds in general. It is also observed in the dense high-pressure phases recovered from high-pressure synthetic experiments.
Introduction
The hydrogen bond (X—H… Y) is one of the most studied bond geometries in the mineralogical, biological, and solid-state organic chemical communities [1, 2]. For nonmineral and mineral structures alike, the published literature, consisting mainly of crystal-structure determinations at ambient pressure, provides a means to study the bond as donor (X) and acceptor (Y) vary over a variety of structures and chemistries [3, 4]. The secondary environment, however, is important in considering the effects of structure on H-bond geometry [5]; in many cases gross changes in this environment from one structure type to the next make it difficult to separate the effects of the relatively weak H bonding from the steric effects because of the framework making up the remainder of the structure [5].
A disturbed calcium homeostasis characterizes diabetic pregnancy. This study documents changes in bone mineral composition in diabetic pregnant rats and examines the effect of insulin replacement. Control pregnant (CP), diabetic pregnant (DP) and insulin-treated DP (DPi) rats were assessed for femoral calcium and magnesium content, bone mineral density (BMD) and the ratio of hypertrophic to maturing and proliferative cells in the femoral growth plate. DP rats showed a significantly (P < 0·01) lower body weight, femoral weight and length than CP rats. Femoral calcium and magnesium content was also significantly (P < 0·05) lower in DP rats, as was ash weight. When calcium and magnesium were normalized for ash weight no signficant differences were apparent. A significantly (P < 0·05) lower total BMD at the distal femur was seen in DP rats. This comprised a significantly (P < 0·01) lower trabecular BMD with no significant change in cortical BMD. A significantly (P < 0·05) higher ratio of hypertrophic to maturing and proliferative cells of the femoral growth plate was evident in DP animals. DPi rats showed normal blood glucose concentrations and femoral growth plate histology. DPi rats also showed normal femoral weight and length but only partially restored femoral ash weight and mineral content. Insulin failed to normalize total or trabecular BMD. Diabetes mellitus clearly has a marked effect on bone growth and mineral content in pregnancy which may be relevant to overall calcium homeostasis. The lower bone growth, bone calcium content and trabecular BMD may be unfortunate consequences of the marked hypercalciuria reported elsewhere in diabetes and may serve to maintain normocalcaemia in the disease.
Wide-field surveys of galaxies and clusters are an indispensable tool for studying large scale structure in the universe. The Abell catalogue (Abell 1958), Zwicky catalogue (Zwicky et. al. 1961-1968), and the Lick survey (Shane and Wirtanen 1967, Seldner et. al. 1977) have provided many statistical results of key importance to our understanding of galaxy formation and clustering (see e.g. Peebles 1980). However, these surveys were constructed more than 20 years ago. Since then, there have been major technological developments in photographic emulsions, automatic scanning machines and computers. It is therefore possible to improve significantly on earlier surveys by generating deep galaxy catalogues with high photometric precision and uniformity over wide areas of sky. Over the last four years, we have taken advantage of these developments to construct a new survey of several million galaxies.
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