Meta-sedimentary rocks recovered beneath Palaeogene basalts near the base of Ocean Drilling Program (ODP) Leg 152-917A offshore South-East Greenland were thought to be of Late Cretaceous age. This interpretation, however, has several inconsistencies as it requires a tectono-metamorphic event during the Cretaceous not recognized in the North Atlantic region, and the presence of a wide Mesozoic sedimentary basin that extended from SE-Greenland to the Rockall Plateau, for which there is currently no evidence. Here, we report a Neoproterozoic U/Pb apatite age of 905 ± 21 Ma and a younger 40Ar/39Ar isochron whole-rock age of 820 ± 40 Ma for an altered tuff layer that occurs in the upper part of the meta-volcaniclastic sequence recovered from hole 917A. The 40Ar/39Ar step-heating ages on biotite and whole-rock mini-cores from deeper in hole 917A yielded Palaeoproterozic dates that cluster around 1950 to 1850 Ma, pointing toward a Palaeoproterozoic source. The U/Pb apatite date is interpreted as the eruption age of the tuff layer, whereas the younger whole-rock 40Ar/39Ar age is consistent with low-temperature greenschist alteration of volcanic glass and secondary mineral growth during sedimentary burial in an extensional regime. The c. 905 Ma age for the tuff provides the first evidence for Neoproterozoic rocks offshore South-East Greenland and suggests a correlation between this sequence and the Torridon Group in the Hebridean Foreland of the Scottish Caledonides. The calc-alkaline nature of the volcaniclastic rocks and the age of the tuff layer point toward a source area with arc-magmatism related to the Renlandian event of the Valhalla Orogeny.

Extensive magmatism in NE China, eastern Central Asian Orogenic Belt, has produced multi-stage granitic plutons and accompanying W mineralization. The Narenwula complex in the southwestern Great Xing’an Range provides important insights into the petrogenesis, geodynamic processes and relationship with W mineralization. The complex comprises granodiorites, monzogranites and granite porphyry. Mafic microgranular enclaves are common in the granodiorites, and have similar zircon U–Pb ages as their host rocks (258.5–253.9 Ma), whereas the W-bearing granitoids yield emplacement ages of 149.8–148.1 Ma. Permian granodiorites are I-type granites that are enriched in large-ion lithophile elements and light rare earth elements, and depleted in high field strength elements and heavy rare earth elements. Both the mafic microgranular enclaves and granodiorites have nearly identical zircon Hf isotopic compositions. The results suggest that the mafic microgranular enclaves and granodiorites formed by the mixing of mafic and felsic magmas. W-bearing granitoids are highly fractionated A-type granites, enriched in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti and Eu. They have higher W concentrations and Rb/Sr ratios, and lower Nb/Ta, Zr/Hf and K/Rb ratios than the W-barren granodiorites. These data and negative ϵHf(t) values (–6.0 to –2.1) suggest that they were derived from the partial melting of ancient lower crust and subsequently underwent extreme fractional crystallization. Based on the regional geology, we propose that the granodiorites were generated in a volcanic arc setting related to the subduction of the Palaeo-Asian Ocean, whereas the W-bearing granitoids and associated deposits formed in a post-orogenic extensional setting controlled by the Mongol–Okhotsk Ocean and Palaeo-Pacific Ocean tectonic regimes.

Marble in the supracrustal rocks of the Lewisian Complex, Tiree, includes chlorine-bearing amphiboles, chlorine-rich apatite, sulphur-rich scapolite, albite and phlogopite, all of which are regarded as evidence for evaporites in other metamorphosed sequences. Titanite yields U–Pb ages of ∼1.6 Ga, i.e. late Laxfordian, which excludes a younger imprint of sodium metasomatism. Traces of anhydrite, and isotopically heavy pyrite, also indicate deposition from seawater. Elsewhere in the Hebrides, tourmaline in Lewisian Complex marbles may represent seafloor exhalative deposits. Combined, the evidence suggests Lewisian Complex supracrustal marbles formed in an evaporative environment, like other Palaeoproterozoic successions across the North Atlantic region.

Various genetic models have been proposed for the supergiant Proterozoic Broken Hill Pb–Zn–Ag deposit largely based on geological and geochronological evidence. Here we present Zn, Cd and S isotope compositions as well as Zn/Cd ratios of sphalerite from Broken Hill and minor Broken Hill-type deposits (Australia) to help constrain these models but focus on syngenetic and magmatic–hydrothermal processes, since epigenetic models can be rejected because the orebodies were deformed and metamorphosed by the Olarian Orogeny. Values of δ34SVCDT, δ66ZnAA-ETH and δ114CdNIST SRM 3108 for sphalerite from Broken Hill range from +0.27 to +4.73 ‰, −1.15 to +0.46 ‰ and −0.48 to +0.01 ‰, respectively, while those for the smaller Broken Hill-type deposits range from −5.11 to +1.28 ‰, −0.97 to +0.10 ‰ and −1.02 to +2.59 ‰, respectively. By combining published S isotope data of sulfides from the Broken Hill district with those obtained here, the sources of sulfur via thermochemical sulfate reduction, bacterial sulfate reduction and a magmatic origin cannot be distinguished. However, when the S isotope compositions are considered along with the broad range of Cd and Zn isotope data for sphalerite, which are among the lightest and heaviest yet reported for a sulfide deposit, the isotopic datasets are consistent with low-temperature biogenic processes associated with syngenetic deposition of sulfides. Cadmium isotope compositions when coupled with Zn/Cd ratios of sphalerite have previously been used to classify Pb–Zn deposits, including low-temperature, high-temperature and exhalative ores. However, the Zn/Cd ratios of sphalerite from Broken Hill cannot be used for such classification purposes.

This study corroborates interpretations suggesting that the Makrotantalon Unit on Andros represents a tectonic slice with Pelagonian affinity in the nappe stack of the Cycladic Blueschist Unit. Previously reported Cretaceous 40Ar–39Ar dates of a garnet-glaucophane schist from the Makrotantalon Unit could not be reproduced by Rb–Sr geochronology, but this is not an indication of contamination with excess Ar. Instead, the newly dated samples record disturbance of the Rb–Sr isotope system by partial recrystallization. Subsets of these phengite populations, representing the smaller grain-size fractions, yielded low-precision dates ranging from c. 21 to c. 15 Ma that document deformation-related resetting and recrystallization of a presumably Cretaceous white mica population. Although these Miocene dates cannot be linked with blueschist-facies metamorphism, they provide time constraints on the formation of shear zones that overprinted the original thrust contact during exhumation. The geological relevance of a Cretaceous high-pressure event is confirmed by a Rb–Sr date of c. 121 Ma for an epidote-glaucophane schist collected further away from the tectonic contact. The occurrence of a second blueschist-facies event in the Eocene is verified by Rb–Sr dates of two epidote-glaucophane schists (c. 40 Ma and c. 44 Ma) that can unambiguously be assigned to the Makrotantalon Unit.

Remnants of some of the planet’s most ancient life forms, stromatolites in the late Mesoproterozoic sea of the Chattisgarh Basin, India, preserve a conspicuous sinuous pattern. They occur as successive biostromes, 10–30 cm thick, separated by 2–5-cm-thick marly layers and discrete bioherms up to several metres thick and 20 m across. Stromatolite columns in the Chandi Formation are 5–10 cm high, sinuous, inclined and straight, with both branched and non-branched types. These stromatolites are composed of calcite micrite and show well defined light and dark laminae with evidence of erosion between lamina sets. The column sinuosity probably originated as a response to changes in direction and strength of currents. Successive flat beds of stromatolite (biostromes), separated by marl/clay horizons, impart a rhythmic pattern to the succession. The Chandi sinuous stromatolite columns resemble those occurring in China, North America and Siberia, of a comparable age, suggesting that similar marine conditions of stromatolite formation might have been operating in the late Mesoproterozoic seas worldwide. However, the petrographic and sedimentological analyses of these stromatolites indicate their development through in situ production of carbonate with some trapping and binding of detrital sediment. As a result of the presence of terrigenous material within the stromatolites, whole-rock geochemical analyses for trace elements and rare earth elements cannot be used for interpretation of seawater chemistry and the redox conditions at the time.

Fractures that form when fluid pressure ruptures the rock are referred to as fluid-driven fractures or hydrofractures. These include most dykes, inclined sheets and sills, but also many mineral veins and joints, as well as human-made hydraulic fractures. While considerable field and theoretical work has focused on the geometry and arrest of hydrofractures, how they select their propagation paths, particularly in layered and faulted rocks, has received less attention. Here I propose that of all the possible paths that a given hydrofracture may follow, it selects the path of least (minimum) action as determined by Hamilton’s principle. This means that the selected path is that along which the energy transformed (released) multiplied by the time taken for the propagation is a minimum. Hydrofractures advance their tips/fronts in steps, with a time lag between the fracture front and the fluid front. In the present framework, each step is then controlled by Hamilton’s principle. The results suggest that when the hosting rock body is regarded as homogeneous, isotropic and non-fractured, hydrofracture paths are everywhere perpendicular to the trajectories of the minimum compressive (maximum tensile) principal stress σ3 and follow the trajectories of the maximum principal compressive stress σ1. When applied to layered and faulted rock body, the results indicate that hydrofracture paths may follow existing faults for a while, depending primarily on (1) the dip of the fault (steep faults are the most likely to be used by vertically propagating hydrofractures), and (2) the tensile strength across the fault compared with the tensile strength of the host rock along a path following the direction of σ 1. The results suggest that hydrofractures may use faults as parts of their paths primarily if the fault is steeply dipping and with close to zero tensile strength.

The Middle Miocene Climatic Optimum is known for abrupt events during the global cooling trend of the past 20 Ma. Its identification in the Tibetan Plateau can help explain the cause of the critical Middle Miocene climate transition in Central Asia. In this study, fine-grained mixed sediments widely distributed in the Miocene Qaidam Lake in the northern Tibetan Plateau were used as a sensitive indicator for palaeoclimate. Their geochemical characteristics were investigated, together with an analysis of 2600 m long successive gamma-ray logging data from the whole JS2 drillcore, to understand the mid-Miocene climate transition in the Tibetan Plateau. By comparing the gamma-ray curve of the mixed sediments with global temperature, the Middle Miocene Climatic Optimum event can be easily identified. Further, the detailed petrological features and geochemical data of lacustrine fine-grained mixed sediments from a 400 m drillcore show oxidizing, high-sedimentation rate and brackish-saline water conditions in a semi-arid climate during the Middle Miocene period, demonstrating a dryer climate in the Qaidam Basin than in the monsoon-sensitive regions in Central Asia. These fine-grained mixed sediments have recorded climate drying before 15.3 Ma that represents a climatic transition within the Middle Miocene Climatic Optimum; increasing carbonate-rich mixed sediments, decreasing algal limestone layers and decreasing lacustrine organic matter are indicators of this transition. Regional tectonic events include the retreat of the Paratethys from Central Asia at ∼15 Ma and the synchronous tectonic reorganization of the Altyn-Tagh fault system and the northeastern Tibetan Plateau. We find that global climate change is the primary factor affecting the overall characteristics and changes of the Neogene climate in the Qaidam Basin, including the occurrence of the Middle Miocene Climatic Optimum and the cooling and drying tendency, while the regional events are a secondary factor.

No basis for controversy exists in the naming of a global, strongly negative, uppermost Cambrian carbon isotope (δ13C) excursion. The HERB Event (HERB) has met the standards for chemostratigraphic units (i.e. consistent biostratigraphic brackets, content and concept) since 1992. By comparison, the TOCE excursion morphed through four temporally distinct δ13C events with spike-like nadirs that shifted temporally through the uppermost Cambrian until its synonymization with HERB (2006–12). In 2018, TOCE became a prolonged interval with very early onset and enveloped HERB – meaning five TOCE homonyms have been unambiguously defined and figured. HERB lies in the high-diversity ptychaspid biomere (trilobites) and below the ptychaspid extinction. But, data on it were used in TOCE’s 2006 proposal and in later iterations (2008, 2012) to show it (1) higher, both at and above the ptychaspid extinction; (2) at the level of HERB (2012, 2018); and (3) even extending well below HERB (2018). TOCE fails the recommendations for a formal chemostratigraphic unit. Its relationship to latest Cambrian biotic turnover includes equation with extinction and high-diversity intervals. One TOCE homonym is a synonym, albeit junior, of HERB.

Fragmentation and amalgamation of supercontinents play an important role in shaping our planet. The break-up of such a widely studied supercontinent, Rodinia, has been well documented from several parts of India, especially the northwestern and eastern sector. Interestingly, being located very close to the Proterozoic tectonic margin, northeastern India is expected to have had a significant role in Neoproterozoic geodynamics, but this aspect has still not been thoroughly studied. We therefore investigate a poorly studied NE–SW-trending Shillong Basin of Meghalaya from NE India, which preserves the stratigraphic record and structural evolution spanning the Neoproterozoic Era. The low-grade metasedimentary rocks of Shillong Basin unconformably overlie the high-grade Archean–Proterozoic basement and comprise a c. 4000-m-thick platform sedimentary rock succession. In this study, we divide this succession into three formations: lower Tarso, middle Ingsaw and upper Umlapher. A NW–SE-aligned compression event later caused the thrusting of these sedimentary rocks over the basement with a tectonic contact in the western margin, resulting in NE–SW-trending fold belts. The rift-controlled Shillong Basin shows a comparable Neoproterozoic evolution with the equivalent basins of peninsular India and eastern Gondwana. The recorded Neoproterozoic rift tectonics are likely associated with Rodinia’s break-up and continent dispersion, which finally ended with the oblique collision of India with Australia and the intrusion of Cambrian granitoids during the Pan-African Orogeny, contributing to the assembly of Gondwana. This contribution is the first to present a complete litho-structural evolution of the Shillong Basin in relation to regional and global geodynamic settings.

This article integrates field, powder X-ray diffraction and microstructural data to constrain deformation mechanisms in and the rheology of granite-derived fault rocks exposed along the SE side of the crustal-scale, strike-slip Kellyland fault zone. Deformation in this area of the Kellyland fault zone localized during cooling and is marked by (1) foliated granite, (2) a ∼50 m wide band of pulverized foliated granite, (3) a ∼2.8 m wide breccia zone hosting coeval shear zones, and (4) a >100 m wide ultramylonite zone. The earliest fabric in the foliated granite is defined by elongated quartz grains, and quartz dislocation creep was the rate-controlling deformation mechanism. Seismogenic deformation initiated when recorded flow stresses reached 96–104 MPa at temperatures of 400–450 °C and is marked by coeval pulverization and formation of breccia. Interseismic viscous creep at similar flow stresses is recorded by mutual cross-cutting relationships between breccia-hosted shear zones, brittle fractures and pseudotachylyte. Field and microstructural observations indicate that breccia-hosted shear zones are low-strain equivalents of the >100 m wide ultramylonite zone, and seismogenic deformation abated as the ultramylonite formed. The rheology of ultramylonites was governed by grain-size-sensitive creep at 112–124 MPa flow stresses. Hence, from the onset of seismogenesis, the Kellyland fault zone was likely a constant-stress system wherein the rate-controlling mechanism shifted from episodic seismogenic slip and interseismic viscous creep to steady state grain-size-sensitive creep in ultramylonites derived from brittle fault rocks. Flow stresses recorded by these rocks also imply that the whole zone was relatively weak if the brittle–viscous transition and uppermost viscous zone are the strongest part of the crust.

Mosonik, a 3.25 Ma extensively dissected stratovolcano located in the North Tanzanian Divergence of the East African Rift, consists predominantly of phonolite and three types of phonolitic nephelinite distinguished by the presence or absence of amphibole or garnet antecrysts and differing populations of complexly zoned antecrystal and phenocrystal pyroxenes. The antecryst–phenocryst assemblage is typical of hybrid lavas derived by magma mixing. Compositional data are given for all major minerals. Owing to the high modal proportions (30–60 vol. %) of antecrysts and phenocrysts of pyroxene and nepheline plus the hybrid character of the lavas, bulk-rock compositions do not represent those of the parental liquids. Thus, assimilation–fractional crystallization modelling of the bulk-rock major- and trace-element abundances is inappropriate and an unevolved parental magma cannot as yet be defined. Sr–Nd isotopic data for Mosonik and other Older Extrusive Series rocks suggest derivation by partial melting of ancient metasomatized lithospheric mantle with mixing of Sr and Nd from two sources coupled with minor lower crustal contamination, melting being induced by the plume currently impinging on the Tanzanian craton, and representing the initial interaction of the plume with the cratonic lithosphere. In contrast, the Younger Extrusives, as exemplified by Oldoinyo Lengai nephelinite–carbonatite volcanism, could be derived from this ancient metasomatized lithospheric mantle plus a recent plume-derived asthenospheric component and no contamination by crustal material. The isotopically and genetically distinct Natron–Engaruka melilitites are considered to represent direct adiabatic melting of the Tanzanian plume without lithospheric contributions. Carbonatites and melilite-bearing nephelinites also occur at Mosonik but are not considered in this study as they are only a very minor volumetric component of the volcano.

The sedimentary characteristics and preservation potential of lacustrine carbonates provide fundamental information on climate change. The lacustrine carbonate deposition in the Eocene Dongying Depression was investigated using a combination of mineralogical, petrological and geochemical analyses. Micritic calcite/dolomite, granular calcite, columnar calcite, calcareous shell fragments and reworked detrital calcite were identified. Varying patterns of carbonates (VPC) including lithofacies, geochemical indicators and carbonate distribution were revealed in the Dongying Depression: (i) carbonates hardly precipitate in the nearshore area (average 12 wt %); (ii) carbonate content is high (average 53 wt %) in the shallow lake and (iii) gradually decreases to reach a minimum (average 24 wt %) in the deeper part of the lake. Comparison of VPC in four Holocene lakes (the Qinghai Lake and Barkol Lake in China, Oro Lake in Canada and Montcortès Lake in Spain) with the Dongying Depression suggests that four distinct lake stages were developed, namely the terrigenous clastic/gypsum-rich, carbonate-rich, carbonate-decreasing and carbonate-poor stages. A depositional model of lacustrine carbonates influenced by detrital influx, climate, palaeoproductivity and salinity is developed. This study contributes to the understanding of the genetic mechanisms of lacustrine carbonate deposition to reconstruct environmental changes.

The recognition of fossiliferous horizons both below and above the classical Ediacara levels of the Flinders Ranges, South Australia, significantly expands the potential of this candidate World Heritage succession. Here we document a small window into the biology and taphonomy of the late Ediacaran seafloor within the new Nilpena Sandstone Member of the Rawnsley Quartzite in Bathtub Gorge, northern Heysen Range. A 1 m2 slab extracted from the gorge, now on permanent display at the South Australian Museum, has a death assemblage dominated by the erniettomorph Phyllozoon hanseni Jenkins and Gehling 1978 and a newly named macroscopic tubular body fossil – Aulozoon soliorum gen. et sp. nov. – on its fine sandstone bed sole. The orientations and juxtaposition of these taxa suggest overprinting of an in situ benthic Phyllozoon community by sand-filled tubes of Aulozoon carried in by a storm wave-base surge. Phyllozoon hanseni is a widespread species that is restricted to the Nilpena Sandstone Member of the Rawnsley Quartzite, whereas Dickinsonia costata ranges from the underlying Ediacara Sandstone Member into the Nilpena Sandstone Member. Fundamental differences in the ways these two vendobiont taxa are constructed and preserved may provide insights into their biology and phylogenetic affinities. In the Nilpena Sandstone Member, D. costata is joined by Dickinsonia rex Jenkins 1992, which appears to be confined to the member, and is here re-described to clarify its taxonomic status and stratigraphic distribution.

Traditionally, the strata of the Luonie Valley, Dechang County, SW Sichuan, China, are considered to contain a suite of felsic volcanic rocks (the Huili Group) that erupted after c. 1050 Ma. However, we report here new age constraints, elemental and Lu–Hf isotope geochemistry for a different suite of older basaltic agglomerate lava, basaltic tuff lava and basalt from the same area, which we name the Luonie Formation. New dating results show that the basaltic volcanic suite of the upper part of the Luonie Formation formed at 1126.1 ± 9.9 Ma, significantly earlier than deposition of the Huili Group, but comparable in age to the 1142 ± 16 Ma Laowushan Formation in central Yunnan Province. Granite intrusion into the Luonie Formation dated 1050.7 ± 12.7 Ma provides crucial supporting evidence for this earlier depositional age. We also report a maximum sedimentary age of c. 1158 Ma for the underlying arkose, implying stratigraphic conformity with the basaltic volcanic rock suite.

The ϵHf(t) values of the basaltic volcanic rocks are mainly positive, indicating that the rocks are mainly derived from the depleted mantle and slightly stained by crustal materials. The characteristics of P*, Nb* and Zr* anomalies also support this view. The distribution patterns of trace and rare earth elements indicate that the basaltic volcanic rocks formed in an extensional setting. The Zr/4–Y–2Nb and Th–Nb/16–Zr/117 discrimination diagrams also provide evidence for this understanding. Lithofacies analysis shows that basaltic volcanic wrocks with the characteristics of both continental and marine facies should be formed in a littoral–neritic environment. We propose here that the evidence is consistent with a phase of continental extension that preceded the convergence of the SW Yangtze Block to form part of Rodinia.

New palynological results from the Gafo Formation (southern sector of the Pulo do Lobo Domain, South Portuguese Zone) are integrated with recently studied sections and drillholes from the Portuguese and Spanish sectors. A total of 44 samples were studied, 27 of which were positive for palynomorph taxonomy. This research revealed well preserved palynological assemblages, including 73 spore species allocated to 28 genera, four acritarch genera, three prasinophyte algae genera plus common chitinozoan remains. Some additional forms were retained under open nomenclature. From this, the first complete age determination for the Gafo Formation in Portugal and Spain was achieved, indicating a middle Famennian (Grandispora gracilis–Grandispora famenensis, GF Biozone) to a late Famennian (Grandispora echinata, VH Biozone) age. A greywacke sample from the same Gafo Formation was dated by U–Pb zircon geochronology and a maximum depositional age of 369 ± 2.5 Ma was obtained. A correlation between these palynological and U–Pb zircon data and the palynoflora assemblages of previous authors was made, as well as with the ages of felsic volcanic rocks found intercalated in the Gafo Formation, confirming the complex stratigraphy of Pulo do Lobo Domain. The results are consistent with stratigraphic mapping and structural interpretations, allowing a middle–late Famennian age (GF and VH Biozone) to be assigned to the Gafo Formation sedimentary rocks. This work has also contributed to a reinterpretation of Gafo Formation depositional facies correlatives (e.g. the Santa Barbara Group in Spain) as being the same lithological unit.

We consider the implications of adding a cap to the yield surface for elastic–plastic and elastic–visco-plastic solids with coupling between deformation, fluid flow and mineral reactions. For a suitable combination of (low) permeability and strain rate, opening-mode veins can form in compression. Such behaviour is enhanced by dissolution and by simultaneous mineral reactions with negative ΔV. These are the opening-mode equivalents of compaction bands in rocks with high permeability. Stylolite parallel veins are considered as forming in this way; such veins are commonly the laminated or ribbon-quartz veins associated with intense gold mineralization. Axial plane veins and melt segregations are in this class also. The addition of a yield surface cap limits the permissible stress states portrayed by a failure-mode diagram and has implications for breccia formation. Failure discontinuities that form at the cap require a decrease in fluid pressure to form as opposed to extension joints and veins that require an increase in fluid pressure; discontinuities that form at the cap are in orientations that are commonly interpreted as reactivated early discontinuities. The switching between high fluid pressure and low fluid pressure, which we call mode-switching, arises from competition between mineral dissolution and deposition. This is an alternative to the fault-valve mechanism and does not require fault reactivation or failure at a ‘seal’ linked to seismicity or fault reactivation. The capped yield surface concept provides a unifying self-consistent approach for vein/breccia formation and for the kinematics of brittle and visco-plastic rocks.