Glycerol is a hygroscopic fluid that spontaneously absorbs water vapour from the atmosphere. For applications involving glycerol, care must be taken to avoid exposure to humidity, since its viscosity decreases quickly as water is absorbed. We report experimental measurements of the viscosity of glycerol in a parallel-plate rheometer where the outer interface is exposed to atmosphere. The measurements decrease with time as water is absorbed from the atmosphere and transported throughout the glycerol via diffusion and advection. Measured viscosities drop faster at higher relative humidities, confirming the role of hygroscopicity in the transient viscosities. The rate of viscosity decrease shows a non-monotonic relationship with the rheometer gap height. This behaviour is explained by considering the transition from diffusion-dominated transport in the narrow-gap regime to the large-gap regime where transport is dominated by inertia-driven secondary flows. Numerical simulations of the water absorption and transport confirm this non-monotonic behaviour. The experimental viscosity measurements show unexpectedly fast decreases at very small gap heights, violating the parallel-plate, axisymmetric model. We propose that this drop-off may be due to misalignment in the rheometer that becomes non-negligible for small gaps. Theoretical considerations show that secondary flows in a misaligned rheometer dominate the typical secondary inertial flows in parallel-plate rheometers at small gaps. Finally, simulations in a misaligned parallel-plate system demonstrate the same sharp drop-off in viscosity measurements at small gap heights. This modelling can be used to estimate the gap height where misalignment effects dominate the transient glycerol viscosity measurements.

Flows containing suspended colloidal particles and dissolved solutes are found in a multitude of natural and man-made systems including hydraulic fractures, water filtration systems and microfluidic devices, e.g. those designed for biological or medical applications. In these types of systems, unexpected particle dynamics such as rapid particle transport and focusing has been observed in the presence of local solute gradients due to the cooperating or competing effects of fluid advection and particle diffusiophoresis, the latter driven by local chemical gradients. We develop analytical expressions for the fluid, solute and particle dynamics in long, narrow channels due to the combined influence of pressure-driven channel flow with diffusiophoretic and diffusioosmotic effects. The results confirm a rapid particle focusing effect that can be controlled by manipulating the particle, solute and flow properties, as well as the channel’s geometry and surface chemistry. Thus, we propose a new approach for performing microfluidic zeta potentiometry, as well as techniques for sorting, concentrating and/or capturing particles based on their sizes or zeta potentials. Finally, we demonstrate that diffusioosmotic effects can be used to pump fluid against a pressure gradient.

Diffusiophoresis describes the motion of colloids in an electrolyte or non-electrolyte solution where there is a concentration gradient. While most of the studies of diffusiophoresis focus on the motion of solid particles, soft objects such as drops and bubbles are also known to experience diffusiophoresis. Here, we investigate the diffusiophoresis of charged drops in an electrolyte solution both analytically and experimentally. The drop is assumed to remain spherical. An analytical solution of the diffusiophoretic velocity of drops is obtained by perturbation methods. We find that the flow inside the drop is driven by the tangential electric stress at the interface and it directly influences the diffusiophoretic speed of the drop. Using charged oil droplets, we measure the drop speed under solute concentration gradients and find good agreement with the analytical solution. Our findings have potential applications for oil recovery and drug delivery.

Consider the dynamics of a healing film driven by surface tension, that is, the inward spreading process of a liquid film to fill a hole. The film is modelled using the lubrication (or thin-film) approximation, which results in a fourth-order nonlinear partial differential equation. We obtain a self-similar solution describing the early-time relaxation of an initial step-function condition and a family of self-similar solutions governing the finite-time healing. The similarity exponent of this family of solutions is not determined purely from scaling arguments; instead, the scaling exponent is a function of the finite thickness of the prewetting film, which we determine numerically. Thus, the solutions that govern the finite-time healing are self-similar solutions of the second kind. Laboratory experiments and time-dependent computations of the partial differential equation are also performed. We compare the self-similar profiles and exponents, obtained by matching the estimated prewetting film thickness, with both measurements in experiments and time-dependent computations near the healing time, and we observe good agreement in each case.

We study the propagation of viscous gravity currents along a thin permeable substrate where slow vertical drainage is allowed from the boundary. In particular, we report the effect of this vertical fluid drainage on the second-kind self-similar solutions for the shape of the fluid–fluid interface in three contexts: (i) viscous axisymmetric gravity currents converging towards the centre of a cylindrical container; (ii) viscous gravity currents moving towards the origin in a horizontal Hele-Shaw channel with a power-law varying gap thickness in the horizontal direction; and (iii) viscous gravity currents propagating towards the origin of a porous medium with horizontal permeability and porosity gradients in power-law forms. For each of these cases with vertical leakage, we identify a regime diagram that characterizes whether the front reaches the origin or not; in particular, when the front does not reach the origin, we calculate the final location of the front. We have also conducted laboratory experiments with a cylindrical lock gate to generate a converging viscous gravity current where vertical fluid drainage is allowed from various perforated horizontal substrates. The time-dependent position of the propagating front is captured from the experiments, and the front position is found to agree well with the theoretical and numerical predictions when surface tension effects can be neglected.