Proton Conductors: Solids, Membranes and Gels - Materials and Devices

doi:10.1017/CBO9780511524806

Protonic conduction in liquid electrolytes is commonplace but is relatively rare in solids. There is much interest worldwide in proton conducting solids, both from the scientific aspect, as materials with novel properties, but also for their possible applications in high-density solid-state batteries, sensors and other electrochemical devices. This book gives a comprehensive review of proton conductors, including theory, techniques, the materials themselves and applications.

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Contents

Frontmatter
pp i-vi
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Contents
pp vii-xvi
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List of contributors
pp xvii-xx
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Preface
pp xxi-xxvii
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Symbols
pp xxviii-xxxii
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I - HYDROGEN BOND AND PROTONIC SPECIES
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1 - The hydrogen bond and chemical parameters favouring proton mobility in solids
pp 1-17
- By Antoine Potier
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2 - Protonic species and their structures
pp 18-37
- By Deborah J. Jones, Jacques Roziere
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3 - Proton conductors: classification and conductivity
pp 38-60
- By Philippe Colomban, Alexandre Novak
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4 - Defects, non-stoichiometry and phase transitions
pp 61-78
- By Philippe Colomban, Alexandre Novak
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5 - Structural studies of proton conductors
pp 79-89
- By J. O. Thomas
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6 - Hydrogen in metals: structure, diffusion and tunnelling
pp 90-100
- By Ivar Svare
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II - MATERIALS: PREPARATION, STRUCTURES AND PROPERTIES
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7 - Structure and characterization of hydrogen insertion compounds of metal oxides
pp 101-121
- By P. G. Dickens, A. M. Chippindale
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8 - High temperature proton conductors based on perovskite-type oxides
pp 122-137
- By H. Iwahara
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9 - Highly ionic hydroxides: unexpected proton conductivity in Mg(OH)2 and homologues
pp 138-157
- By Friedemann Freund
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10 - Ice
pp 158-164
- By I. A. Ryzhkin
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11 - Anhydrous materials: oxonium perchlorate, acid phosphates, arsenates, sulphates and selenates
pp 165-182
- By Philippe Colomban, Alexandre Novak
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12 - Hydrogen behaviour in graphite–nitric acid intercalation compounds
pp 183-189
- By H. Fuzellier, J. Conard
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13 - Proton-containing β- and β″-alumina structure type compounds
pp 190-209
- By Hiroyuki Ikawa
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14 - Proton conduction in zeolites
pp 210-223
- By Erik Krogh Andersen, Inge G. Krogh Andersen, Erik Skou
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15 - Proton containing NASICON phases
pp 224-237
- By Abraham Clearfield
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16 - Phosphates and phosphonates of tetravalent metals as protonic conductors
pp 238-253
- By Giulio Alberti, Mario Casciola
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17 - Hydrogen uranyl phosphate, H3OUO4PO4. 3H2O (HUP), and related materials
pp 254-271
- By Philippe Colomban, Alexandre Novak
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18 - From crystalline to amorphous (particle) hydrates: inorganic polymers, glasses, clays, gels and porous media
pp 272-293
- By Philippe Colomban, Alexandre Novak
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19 - Perfluorinated membranes
pp 294-310
- By Gerald Pourcelly, Claude Gavach
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20 - Mixed inorganic-organic systems: the acid/polymer blends
pp 311-328
- By Jean-Claude Lassegues
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III - PROTON DYNAMICS AND CHARGE TRANSPORT
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21 - Incoherent neutron scattering studies of proton conductors: from the anhydrous solid state to aqueous solutions
pp 329-349
- By Jean-Claude Lassegues
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22 - NMR studies of local motions in fast protonic conductors
pp 350-366
- By S. V. Bhat
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Proton Conductors

Solids, Membranes and Gels - Materials and Devices

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