Hostname: page-component-7bb8b95d7b-495rp Total loading time: 0 Render date: 2024-09-23T10:25:42.081Z Has data issue: false hasContentIssue false

The Disorder-Order Transformation in Ni4Mo

Published online by Cambridge University Press:  06 March 2019

Fu-Wen Ling
Affiliation:
Georgia Institute of Technology Atlanta, Georgia 30332
E. A. Starke Jr.
Affiliation:
Georgia Institute of Technology Atlanta, Georgia 30332
Get access

Abstract

The progressive ordering of a single crystal of Ni4Mo by isothermal ageing at 650°C (transformation temperature = 868°C) has been studied by x-ray line broadening techniques using the Warren- Averbach method employing computer techniques. The long-range-order parameter, antiphase domain size, and internal strains were measured as a function of ordering time and compared with those previously obtained at 700°C. The activation energies for domain growth and ordering were found to be 91 kcal/mole and 44.5 kcal/mole respectively. The rms strain developed during ordering was found to be dependent on the degree of tetragonality of the structure.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1971

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Cohen, J. B., “A Brief Review of the Properties of Ordered Alloys,” J. Mater. Sci. 4:1012, 1969.Google Scholar
2. Ling, Fu-Wen and Starke, E. A. Jr., “The Development of Long- Range Order and the Resulting Strengthening Effects in Ni4.Mo,” Acta Met. (in press).Google Scholar
3. Warren, B. E., X-Ray Diffraction, Addison-Wesley Publ. Co., Reading, Mass., 1969.Google Scholar
4. Rachinger, W. A., “A Correction for the α1α2Doublet in the Measurement of Widths of X-Ray Diffraction Lines,” J. Sci. Inst. 25:254, 1948.Google Scholar
5. Stokes, A. R., “A Numerical Fourier-Analysis Method for the Correction of Widths and Shapes of Lines on X-Ray Powder Photographs,” Proceedings of the Physical Society 61:382, 1948.Google Scholar
6. Ling, Fu-Wen, “The Determination of Microstrains and Antiphase Domain Size Produced During Ordering of a Ni4Mo Single Crystal,” Ph.D. Thesis, Georgia Institute of Technology, Atlanta, Georgia, December, 1970.Google Scholar
7. Spruiell, J. E. and Stansbury, E. E., “X-Ray Study of Short-Range Order in Ni Alloy Containing 10.7 & 20.0 At.% Mo,” J. Phys. Chem. Solids 26:811, 1965.Google Scholar
8. Ruedl, E., Delavignette, P., and Amelinckx, S., “Electron Diffraction and Electron Microscopic Study of Long- and Short-Range Order in Ni4Mo and of Substructure Resulting from Ordering,” Phys. Stat. Solidi 28:305, 1968.Google Scholar
9. Okamoto, Paul R., “Initial Stages of Ordering in Ni4Mo,” Ph.D. Thesis, University of California, Berkeley, California, March, 1970.Google Scholar
10. Guthrie, P. V. and Stansbury, E. E., “X-Ray and Metallographic Study of the Nickel-Rish Alloys of the Nicke1-Molybdenum System II,” USAEC Report ORNL-3078, Oak Ridge National Laboratory, Tenn., July, 1961.Google Scholar
11. Ling, Fu-Wen and Starke, E. A. Jr., “The Kinetics of Disorder-Order Transformation,” to be published.Google Scholar
12. Adda, Y. and Philibert, J., “La Diffusion dens Res Solides,” Tome II, Presses Universitaires de France, Paris, 1966.Google Scholar
13. Gordon, Paul and El-Bassyouni, T. A., “The Effect of Purity on Grain Growth in Aluminum,” Trans, AIME 233:391, 1965.Google Scholar
14. Paquette, G. E. and Mikkola, D. E., “Antiphase Domain Growth in Cu3Au,” Trans. AIME 245:743, 1969.Google Scholar
15. Gordon, Paul and Vandermeer, R. A., “The Mechanism of Boundary Migration in Recrystallization,” Trans. AIME 224:917, 1962.Google Scholar