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Chemistry of illite-smectite inferred from TEM measurements of fundamental particles

Published online by Cambridge University Press:  09 July 2018

J. Środoń ,
F. Elsass ,
W. J. McHardy  and
D. J. Morgan
J. Środoń
Affiliation:
Centre de Géochimie de la Surface CNRS, 1, rue Blessig, 67084 Strasbourg
F. Elsass
Affiliation:
Station de Science du Sol INRA, Route de St-Cyr, 78000 Versailles, France
W. J. McHardy
Affiliation:
The Macaulay Land Use Research Institute, Craigiebuckler, Aberdeen AB9 2QJ
D. J. Morgan
Affiliation:
British Geological Survey, Keyworth NG12 5GG, UK
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Abstract

Mixed-layer illite-smectites (I-S) have a stable charge on the illite interlayer equal to 0·89/O10(OH)2, as shown by electron microscope measurements of mean fundamental particle thickness, using both Pt-shadowing and high-resolution techniques. This has been verified by independent measurements of total surface area and CEC. Typically, the smectite interlayer charge is close to 0·4/O10(OH)2 but clays evolving in K-deficient environments may exhibit higher values. In the course of illitization, the silicate layer composition becomes more restricted than the smectite composition, AlIV and AlVI increasing while Fe and Mg decrease. These substitutions lead to the composition of non-expandable illite differing distinctly from that of muscovite and phengite, close to FIX0·89Al1·85Fe0·05Mg0·10Si3·20Al0·80. HRTEM data show that XRD systematically underestimates %S layers in I-S due to the small size of coherent scattering domains. An experimental curve is proposed for correcting XRD data. The above results were obtained for I-S formed from volcanic materials in different diagenetic and hydrothermal environments. The illite interlayer charge value close to 0·9 reconciles well the available data on I-S produced by wetting and drying of K-smectites.

Type
Research Article
Information
Clay Minerals , Volume 27 , Issue 2 , June 1992 , pp. 137 - 158
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

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References

Refernces

Alexiades, C.A. & Jackson, M.L. (1966) Quantitative day mineralogical analysis of soils and sediments. Clays Clay Miner., 14, 34–42.Google Scholar
Altaner, S.P. & Bethke, C.M. (1988) Interlayer order in illite/smectite. Am. Miner., 73, 766–774.Google Scholar
Aronson, J.L. & Douthitt, C.B. (1986) K/Ar systematics of an acid-treated illite/smectite: implications for evaluating age and crystal structure. Clays Clay Miner., 34, 473–482.Google Scholar
Bremner, J.M. (1965) Inorganic forms of nitrogen. Pp. 1179-1237 in: Methods of Soil Analysis(Black, C.A., editor). Am. Soc. Agron., Madison, Wisconsin.Google Scholar
Brown, G. & Norrish, K. (1952) Hydrous micas. Mineral. Mag., 29, 929–932.Google Scholar
Brown, G. & Weir, A.H. (1963a) The identity of rectorite and allevardite. Proc. Int. Clay Conf. Stockholm I, 27–37.Google Scholar
Brown, G. & Weir, A.H. (1963) An addition to the paper "The identity of rectorite and allevardite".. Proc. Int. Clay Conf. Stockholm 2, 87–90.Google Scholar
Brusewitz, A.M. (1986) Chemical and physical properties of Paleozoic potassium bentonites from Kinnekulle, Sweden. Clays day Miner., 34, 442–454.Google Scholar
Carter, D.L., Heilman, M.D. & Gonzalez, C.L. (1965) Ethylene glycol monoethyl ether for determining surface area of silicate minerals. Soil Sci., 100, 356–360.CrossRefGoogle Scholar
Cooper, J.E. & Abedin, K.Z. (1981) The relationship between fixed ammonium-nitrogen and potassium in clays from a deep well on the Texas Gulf Coast. Texas J. Sci., 34, 103–111.Google Scholar
Daniels, E.J. & Altaner, S.P. (1990) Clay mineral authigenesis in coal and shale from Anthracite region, Pennsylvania. Am. Miner. IS,, 103–111.Google Scholar
Dval, R.S. & Hendricks, S.B. (1950) Total surface of clays in polar liquids as a characteristic index. Soil Sci., 69, 421–432 Google Scholar
Eberl, D.D. & Srodon, J. (1988) Ostwald ripening and interparticle-diffraction effects for illite crystals. Am. Miner., 73, 1335–1345.Google Scholar
Eberl, D.D., Środoń, J. & Northrop, H.R. (1986) Potassium fixation in smectite by wetting and drying. Pp. 296-326 in: Geochemical Processes at Mineral Surface (Davis, J .A. & Hayes, K.F., editors). Am. Chem. Soc. Sym. Series 323.Google Scholar
Eberl, D.D., Środoń, J., Lee, M., Nadeau, P.H. & Northrop, H.R. (1987) Sericite from the Silverton caldera, Colorado: Correlation among structure, composition, origin, and particle thickenss. Am. Miner., 72, 914–934.Google Scholar
Eslinger, E., Highsmith, P., Albers, D. & deMayo, B. (1979) Role of iron reduction in the conversion of smectite to illite in bentonites in the Disturbed Belt, Montana. Clays Clay Miner., 27, 327–338.Google Scholar
Garrels, R.M. & Mackenzie, F.T. (1971) Evolution of Sedimentary Rocks. W.W. Norton, New York.Google Scholar
Guven, N. (1972) Electron optical investigations of Marblehead illite. Clays Clay Miner., 20, 83–88.CrossRefGoogle Scholar
Hoffman, J. (1976) Regional metamorphism and K-Ar dating of clay minerals in Cretaceous sediments of the Disturbed Belt of Montana.PhD thesis, Case Western Reserve Univ., Cleveland, USA.Google Scholar
Howard, J.J. (1981) Lithium and potassium saturation of illite/smectite days from interlaminated shales and sandstones. Clays Clay Miner., 29, 136–142.Google Scholar
Howard, J.J. & Roy, D.M. (1985) Development of layer charge and kinetics of experimental smectite alteration. Clays Clay Miner., 33, 81–88.Google Scholar
Hower, J. & Mowatt, T.C. (1966) The mineralogy of illites and mixed-layer illite/montmorillonites. Am. Miner., 51, 825–854.Google Scholar
Huff, W.D. & Morgan, D.J. (1990) Stratigraphy, mineralogy and tectonic setting of Silurian K-bentonites in Southern England and Wales. Sciences Geol., 88, 33–42.Google Scholar
Inoue, A., Minato, H. & Utada, M. (1978) Mineralogical properties and occurrence of illite/montmorillonite mixed layer minerals formed from Miocene volcanic glass in Wago-Omono district. Clay Sci., 5, 123–136.Google Scholar
Jackson, M.L. (1975) Soil Chemical Analysis—Advanced Course. Published by the author, Madison, Wisconsin.Google Scholar
Jackson, M.L., Hseung, Y., Corey, R.B., Evans, E.J. & Vanden Heuvel, R.C. (1952) Weathering of clay size minerals in soils and sediments. II Chemical weathering of layer silicates. Soil Sci. Soc. Am. Proc., 16, 3–6.Google Scholar
Mackenzie, R.C. (1951) A micromethod for determination of cation exchange capacity of clay. J. Colloid Sci., 6, 219–222.Google Scholar
Meunier, A. & Velde, B. (1989) Solid solutions in I/S mixed-layer minerals and illite. Am. Miner., 74, 1106–1112.Google Scholar
Nadeau, P.H. (1985) The physical dimensions of fundamental clay particles. Clay Miner., 20, 499–514.Google Scholar
Nadeau, P.H. & Bain, D.C. (1986) Composition of some smectites and diagenetic illitic clays and implications for their origin. Clays Clay Miner., 34, 455–464.CrossRefGoogle Scholar
Nadeau, P.H., Wilson, M.J., McHardy, W.J. & Tait, J.M. (1984) Interstratified clays as fundamental particles. Science, 225, 923–925.Google Scholar
Norrish, K. & Pickering, J.G. (1983) Clay minerals. Pp. 281-308 in: Soils: an Australian Viewpoint. CSIRO, Melbourne/Academic Press, London.Google Scholar
Raman, K.V. & Jackson, M.L. (1966) Layer charge relations in clays minerals of micaceous soils and sediments. Clays Clay Miner., 14, 53–68.Google Scholar
Rundle, L.M. (1974) A combustion method for the determination of total sulphur in limestones. Analyst, 99, 163–165.Google Scholar
Środoń, J. (1976) Mixed-layer smectite/illites in the bentonites and tonsteins of the Upper Silesian Coal Basin. Prace Miner., 49, 84 pp.Google Scholar
Środoń, J. (1979) Correlation between coal and clay diagenesis in the Carboniferous of the Upper Silesian Coal Basin. Proc. lnt. Clay Conf. Oxford,, 251–260.Google Scholar
Środoń, J. (1980) Precise identification of illite/smectite interstratifications by X-ray powder diffraction. Clays Clay Miner., 28, 401–411.Google Scholar
Środoń, J. J. (1984) X-ray powder diffraction identification of illitic materials. Clays Clay Miner., 32, 337–349.Google Scholar
Środoń, J. (1990) Illite-smectite in the rock cycle. Lectures 6th Meet. European Clay Groups, Seville,, 137–151.Google Scholar
Środoń, J. & Eberl, D.D. (1984) Illite. Pp. 495–544 in: Micas (Bailey, S.W., editor). Reviews in Mineralogy 13, Mineralogical Society of America, Washington, DC.Google Scholar
Środoń, J., Andreoli, C., Elsass, F. & Robert, M. (1990) Direct high-resolution transmission electron microscopic measurement of expandability of mixed-layer illite/smectite in bentonite rock. Clays Clay Miner., 38, 373–379.Google Scholar
Środoń, J., Morgan, D.J., Eslinger, E.V., Eberl, D.D. & Karlinger, M.R. (1986) Chemistry of illite/smectite and end-member illite. Clays Clay Miner. 34, 368–378.Google Scholar
Velde, B. & Brusewitz, A.M. (1986) Compositional variation in component layers in natural illite/smectite. Clays Clay Miner., 34, 651–657.Google Scholar
Veblen, D.R., Guthrie, G.D., Livi, K.J.T. & Reynolds, R.C. Jr., (1990) High-resolution transmission electron microscopy and electron diffraction of mixed-layer illite/smectite: experimental results. Clays Clay Miner., 38, 1–13.Google Scholar