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Depth-Dependent Transformation of Kaolinite to Dickite In Sandstones of the Norwegian Continental Shelf

Published online by Cambridge University Press:  09 July 2018

S. N. Ehrenberg ,
P. Aagaard ,
M. J. Wilson ,
A. R. Fraser  and
D. M. L. Duthie
S. N. Ehrenberg
Affiliation:
Statoil, Geological Laboratory, postboks 300, N-4001 Stavanger, Norwa
P. Aagaard
Affiliation:
Geological Institute, University of Olso, postboks 1047, N-0316 Blindern, Norway, and
M. J. Wilson
Affiliation:
Macaulay Land Use Research Institute, Craigiebuckler, Aberdeen, AB9 2Q J, UK
A. R. Fraser
Affiliation:
Macaulay Land Use Research Institute, Craigiebuckler, Aberdeen, AB9 2Q J, UK
D. M. L. Duthie
Affiliation:
Macaulay Land Use Research Institute, Craigiebuckler, Aberdeen, AB9 2Q J, UK
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Abstract

Replacement of kaolinite by dickite has been observed to occur with increasing depth of burial in sandstones from three different basins on the Norwegian continental shelf. In the Garn Formation (Middle Jurassic) of Haltenbanken, samples from 1.4-2-7 km below the sea floor (110°C) contain kaolinite, whereas deeper than 3.2 km (130°C) mainly dickite is present. In the Statfjord Formation (Late Triassic-Early Jurassic) from Gullfaks and Gullfaks Sør Fields, transformation of kaolinite to dickite occurs at ~3.1 km below the sea floor (120°C) From the Stø and Nordmela Formations (Lower to Middle Jurassic) to the Troms Area, kaolin polytypes have been identified in only two shallow and two deep samples, but the results are consistent with the transformation depth determined in two other areas studied. These occurrences are significant because they allow the temperature of the kaolinite/dickite transformation to be established with greater confidence than had been possible previously. Also the observation of this transformation in all three areas so far examined indicates that it may be a general and predictable feature of kaolinbearing sandstones worldwide and therefore a potentially reliable paleogeothermometer. In most cases, the kaolinite occurs as relatively large vermicular crystals, whereas dickite forms more euhedral, blockier crystals. This morphological difference, together with the nature of the structural difference in octahedral occupancy between the kaolinite and dickite, suggests that the transformation occurs by dissolution and reprecipitation, rather then in the solid state.

Information

Type
Research Article
Information
Clay Minerals , Volume 28 , Issue 3 , September 1993 , pp. 325 - 352
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1993

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References

Anovitz, L.M., Perkins, D. & Essene, E.J. (1991) Metastability in near-surface rocks of minerals in the system Al2O3-SiO2-H20. Clays Clay Miner. 39, 225–233.CrossRefGoogle Scholar
Bailey, S.W. (1980a) Summary of recommendations of AIPEA nomenclature committee. Clay Miner. 15, 85–93.Google Scholar
Bailey, S.W. (1980b) Structures of layer silicates. Pp. 1-123 in: Crystal Structures of Clay Minerals and their X-ray Identification (G.W. Brindley & G. Brown, editors). Mineralogical Society, London.Google Scholar
Barnay, R. & Kelley, K.K. (1961) Heats and free energies of formation of gibbsite, kaolinite, halloysite, and dickite. US Bureau Mines Rept. Inv. 5825, 1–13.Google Scholar
Bates, R.L. & Jackson, J.A. (1987) Glossary of Geology, third edition. American Geological Institute, Alexandria, Virginia.Google Scholar
Bayliss, P., Loughnan, F.C. & Standard, J.C. (1965) Dickite in the Hawkesbury Sandstone of the Sydney basin, Australia. Am. Miner. 50, 418–426.Google Scholar
Berman, R.G. (1988) Internally consistent thermodynamic data set for minerals in the system Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2 . J. Petrol. 29, 445–522.Google Scholar
Bish, D.L. & Von Dreele, R. (1988) Reitveld refinement of the crystal structure of kaolinite. Abstract Ann. Mtg. Clay Miner. Soc. Google Scholar
Cassan, J.P. & Lucas, J. (1966) La diageneses des gres argileux d’Hassi-Messaoud (Sahara): silicification et dickitisation. Bull. Serv. Carte Geol. Alsace-Lorraine 19, 241–253.Google Scholar
Deer, W.A., Howie, R.A. & Zussman, J. (1966) An Introduction to the Rock-forming Minerals. Longman, London.Google Scholar
Dick, A.B. (1888) On kaolinite. Mineral. Mag. 8, 15–27.Google Scholar
Dick, A.B. (1908) Supplementary note on the mineral kaolinite. Mineral. Mag. 15, 124–128.Google Scholar
Drever, J.I. (1988) The Geochemistry of Natural Waters. 2nd edition, p. 79. Prentice-Hall, Englewood Cliffs, New Jersey.Google Scholar
Dunoyer de, Segonzac G. (1970) The transformation of clay minerals during diagenesis and low-grade metamorphism: a review. Sedimentology 15, 281–326.Google Scholar
Ehrenberg, S.N. (1980) Relationship between diagenesis and reservoir quality in sandstones of the Gam Formation, Haltenbanken, mid-Norwegian continental shelf. Am. Assoc. Petrol. Geol. Bull. 74, 1538–1558.Google Scholar
Ehrenberg, S.N. (1991) Kaolinized, potassium-leached zones at the contacts of the Gam Formation, Haltenbanken, mid-Norwegian continental shelf. Marine Petrol. Geol. 8, 250–269.Google Scholar
Ehrenberg, S.N. & Nadeau, P.H. (1989) Formation of diagenetic illite in sandstones of the Gam Formation, Haltenbanken, mid-Norwegian continental shelf. Clay Miner. 24, 233–253.CrossRefGoogle Scholar
Ferraro, J. & Kubler, B. (1964) Presence de dickite dans les gres Cambrienes d’Hassi Messaoud. Bull. Serv. Carte Geol. Alsace-Lorraine 17, 247–261.Google Scholar
Frey, M. (1987) Very low-grade metamorphism of clastic sedimentary rocks. Pp. 9-58 in: Low Temperature Metamorphism (M. Frey, editor). Blackie, Glasgow.Google Scholar
Giles, M.R., Stevenson, S., Martin, S.V., Cannon, S.J.C., Hamilton, P.J., Marshall, J.D. & Samways, G.M. (1992) The reservoir properties and diagenesis of the Brent Group: a regional perspective. Pp. 289-327 in: Geology of the Brent Group (A.C. Morton, R.S. Haszeldine, M.R. Giles & S. Brown, editors). Geol. Soc. Spec. Pub. 61.Google Scholar
Glassman, J.R., Lundegard, P.D., Clark, R.A., Penny, B.K. & Collins, I.D. (1989) Geochemical evidence for the history of diagenesis and fluid migration: Brent sandstone, Heather Field, North Sea. Clay Miner. 24,255-284Google Scholar
Haas, J.L., Jr., Robinson, G.R., Jr., & Hemingway, B.R. (1981) Thermodynamic tabulations for selected phases in the system at 101-325 kPa (1 atm) between 273-15 and 1800°K. J. Phys. Chem. Ref. Data 10, 575–669.Google Scholar
Haszeldine, R.S., Brint, J.F., Fallick, A.E., Hamilton, P.J. & Brown, S. (1992) Open and restricted hydrologies in Brent Group diagenesis: North Sea. Pp. 401-419 in: Geology of the Brent Group (A.C. Morton, R.S. Haszeldine, M.R. Giles & S. Brown, editors). Geol. Soc. Spec. Pub. 61.Google Scholar
Hemingway, J.E. & Brindley, G.W. (1948) The occurrence of dickite in some sedimentary rocks. Proc. 18th Int. Geol. Cong. Report 13, 308.Google Scholar
Hoffman, J. & Hower, J. (1979) Clay mineral assemblages as low grade metamorphic geothermometers: applications to the thrust faulted disturbed belt of Mantana, U.S.A. Pp. 55-79 in: Aspects of Diagenesis (P.A. Scholle & P.R. Schuger, editors). Soc. Econ. Paleont. Mineral. Spec. Pub. 26.Google Scholar
Hurst, A. & Irwin, H. (1982) Geological modelling of clay diagenesis in sandstones. Clay Miner. 17, 5–22.Google Scholar
Joswig, W. & Drits, V.A. (1986) The orientation of the hydroxyl groups in dickite by X-ray diffraction. N. Jb. Miner. Mh. 1, 19–22.Google Scholar
Kantorowicz, J. (1984) The nature, origin and distribution of authigenic clay minerals from Middle Jurassic Ravenscar and Brent Group sandstones. Clay Miner. 19, 359–375.CrossRefGoogle Scholar
King, E.G. & Weller, W.W. (1961) Low-temperature heat capacities and entropies at 298T5°K of diaspore, kaolinite, dickite, and halloysite. U.S. Bur. Mines Rept. Inv. 5810, 6p.Google Scholar
Kisch, H.J. (1983) Mineralogy and petrology of burial diagenesis (burial metamorphism) and incipient metamorphism in clastic rocks. Pp. 289-494 in: Diagenesis in Sediments and Sedimentary Rocks, 2 (G. Larsen & G.V. Chilingar, editors). Elsevier, Amsterdam.Google Scholar
Kossovskaya, A.G. & Shutov, V.D. (1963) Facies of regional epi- and metagenesis. Int. Geol. Rev. 7, 1157–1167.Google Scholar
Newham, R.E. (1956) Crystal structure of the mineral dickite. PhD thesis, Pennsylvania State Univ., USA.Google Scholar
Newham, R.E. (1961) A refinement of the dickite structure and some remarks on the polymorphism in kaolin minerals. Mineral. Mag. 32, 683–704.Google Scholar
Newham, R.E. & Brindley, G.W. (1956) The crystal structure of dickite. Acta Cryst. 9, 759–764.Google Scholar
Nyland, B., Jenšen, L.N., Skagen, J., Skarpnes, O. & Vorren, T. (1992) Tertiary uplift and erosion in the Barents Sea; magnitude, timing and consequences. Pp. 153-162 in: Structural and Tectonic Modelling and Its Application to Petroleum Geology (R.M. Larsen, H. Brekke, B.T. Larsen & E. Talleraas, editors). Elsevier, Amsterdam.Google Scholar
Olaussen, S., Dalland, A., Gloppen, T.G. & Johannessen, E. (1984) Depositional environment and diagenesis of Jurassic reservoir sandstone, in the eastern part of Troms I area. Pp. 61-79 in: Petroleum Geology of the North European Margin (A.M. Spencer et al. , editors). Norwegian Petrol. Soc., Graham & Trotman, London.Google Scholar
Olaussen, S., Beck, L., Falt, L.M., Graue, E., Jakobsen, K.G. Malm, O.A. & South, D. (1993) Gullfaks Field- Norway. Pp. 55-83 in: Treatise of Petroleum Geology—Atlas of Oil and Gas Fields, Structural Traps IV (J. Beaumont & N.H. Foster, editors). Am. Assoc. Petroleum Geologists, Tulsa. ‘Google Scholar
Paterson, E., Bunch, J.L. & Duthie, D.M.L. (1986) Preparation of randomly oriented samples for X-ray diffractometry. Clay Miner. 21, 101–106.Google Scholar
Petterson, O., Storu, A., Ljosland, E. & Massie, I. (1990) The Gullfaks Field: geology and reservoir development. Pp. 67-90 in: North Sea Oil and Gas Reservoirs-II (A.T. Buller, E. Berg, O. Hjelmeland, J. Kleppe, O. Torsaeter & J.O. Aasen, editors). Graham & Trotman, London.Google Scholar
Ramm, M. (1991) Porosity-depth trends in reservoir sandstones. (Paper 5: Diagenesis and porosity evolution of Lower and Middle Jurassic reservoir sandstones in the Troms I area, Barents Sea). PhD thesis, Univ. Oslo, Norway.Google Scholar
Riches, P., Traub-Sobott, L, Zimmerle, W. & Zinkernagel, U. (1986) Diagenetic peculiarities of potential Lower Jurassic reservoir sandstones, Troms 1 area, off northern Norway, and their tectonic significance. Clay Miner. 21, 565–584.Google Scholar
Ridley, J. & Thompson, A.B. (1986) The role of mineral kinetics in the development of metamorphic micro textures. Pp. 154-193 in: Fluid-Rock Interactions during Metamorphism (J.V. Walther & B.J. Wood, editors) Adv. Phys. Geochemistry 5.Google Scholar
Robie, R.A. & Waldbaum, D.R. (1968) Thermodynamic properties of minerals and related substances at 298T5 K and 1 bar (105 Pascals) pressure and at high temperatures. US Geol. Surv. Bull. 1259, 256p.Google Scholar
Robie, R.A., Hemingway, B.S. & Fisher, J.R. (1979) Thermodynamic properties of minerals and related substances at 298T5 K and 1 bar (105 Pascals) pressure and at high temperatures. US Geol. Surv. Bull. 1452, 456p.Google Scholar
Ross, C.S. & Kerr, P.F. (1931) The kaolin minerals. US Geol. Surv. Prof. Pap. 165E, 151–180.Google Scholar
Russell, J.D. (1987) Infrared methods. Pp. 133-173 in: A Handbook of Determinative Methods in Clay Mineralogy (M.J. Wilson, editor). Blackie, Glasgow.Google Scholar
Schroeder, R.J. & Hayes, J.B. (1968) Dickite and kaolinite in Pennsylvanian limestones of southeastern Kansas. Clays Clay Miner. 16, 41—49.Google Scholar
Shutov, V.D., Aleksandrova, A.V. & Losievskaya, S.A. (1970) Genetic interpretation of the polytypism of the kaolinite group in sedimentary rocks. Sedimentology 15, 69–82.Google Scholar
Smithson, F. (1954) The petrography of dickite sandstones in North Wales and northern England. Geol. Mag. 91, 177–188.Google Scholar
Smithson, F. (1957) Dickite in sandstones from northern England and North Wales. Mineral.Mag. 31, 381–391.Google Scholar
Thomas, M. (1986) Diagenetic sequences and K/Ar dataing in Jurassic sandstones, central Viking Graben: effects on reservoir properties. Clay Miner. 21, 695–710.CrossRefGoogle Scholar
Wilson, M.J. (1987) X-ray powder diffraction methods. Pp. 26-98 in: A Handbook of Determinative Methods in Clay Mineralogy (M.J. Wilson, editor). Blackie, Glasgow.Google Scholar