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Efficient removal of crystal violet from solution by montmorillonite modified with docosyl-trimethylammonium chloride and sodium dodecyl sulfate: modelling, kinetics and equilibrium studies

Published online by Cambridge University Press:  23 September 2022

Malihe Sarabadan ,
Hadis Bashiri Open the ORCID record for Hadis Bashiri [Opens in a new window]  and
Seyed Mahdi Mousavi
Malihe Sarabadan
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Hadis Bashiri*
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Seyed Mahdi Mousavi
Affiliation:
Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
*
*Email: hbashiri@kashanu.ac.ir
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Abstract

Two novel modified montmorillonite (Mnt) components were prepared using Mnt nanoparticles and two surfactants: docosyl-trimethylammonium chloride (BTAC) and sodium dodecyl sulfate (SDS). These modified Mnts were used to remove a carcinogenic and harmful dye, crystal violet (CV), from solution. Optimization and modelling studies of the adsorption of these two modified Mnts were performed using response surface methodology. Four influential variables (concentration of adsorbent, temperature, pH and CV concentration) were studied to obtain the optimum conditions for CV removal. The optimal values of these variables for the two modified Mnts yielded 100% dye-removal efficiency. The optimum conditions for CV adsorption on Mnt-BTAC and Mnt-BTAC-SDS, respectively, are temperatures of 25.00 and 33.29°C, pH values of 9 and 10.1, CV concentrations of 50.00 and 10.44 mg L–1 and adsorbent concentrations of 1.00 and 0.98 g L–1. In equilibrium studies of the two modified Mnts, the Temkin isotherm was selected as an appropriate model, and in kinetic studies of these Mnts, the fractal-like integrated kinetics Langmuir model was found to be the best model. The Mnt-BTAC-SDS component is an affordable adsorbent with high adsorption capacity for CV.

Keywords

adsorptionBTACcrystal violetdye removalmontmorilloniteoptimizationRSMwastewater treatment
Type
Article
Information
Clay Minerals , Volume 57 , Issue 1 , March 2022 , pp. 7 - 20
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Liva Dzene

References

Acisli, O., Khataee, A., Karaca, S. & Sheydaei, M. (2016) Modification of nanosized natural montmorillonite for ultrasound-enhanced adsorption of acid red 17. Ultrasonics Sonochemistry, 31, 116–121.CrossRefGoogle ScholarPubMed
Agarwal, S., Tyagi, I., Gupta, V. K., Dastkhoon, M., Ghaedi, M., Yousefi, F. & Asfaram, A. (2016) Ultrasound-assisted adsorption of sunset yellow CFC dye onto Cu doped ZnS nanoparticles loaded on activated carbon using response surface methodology based on central composite design. Journal of Molecular Liquids, 219, 332–340.CrossRefGoogle Scholar
Ali, I., Asim, M. & Khan, T.A. (2012) Low cost adsorbents for the removal of organic pollutants from wastewater. Journal of Environmental Management, 113, 170–183.CrossRefGoogle ScholarPubMed
Alipanahpour Dila, E., Ghaedi, M., Ghaedi, A., Asfaram, A., Jamshidi, M. & Purkait, M.K. (2016) Application of artificial neural network and response surface methodology for the removal of crystal violet by zinc oxide nanorods loaded on activate carbon: kinetics and equilibrium study. Journal of the Taiwan Institute of Chemical Engineers, 59, 210–220.Google Scholar
Amodu, O.S., Ojumu, T.V., Ntwampe, S.K. & Ayanda, O.S. (2015) Rapid adsorption of crystal violet onto magnetic zeolite synthesized from fly ash and magnetite nanoparticles. Journal of Encapsulation and Adsorption Sciences, 5, 191–203.CrossRefGoogle Scholar
Andrades, M.S., Rodríguez-Cruz, M.S., Sánchez-Martín, M.J. & Sánchez-Camazano, M. (2004) Effect of the modification of natural clay minerals with hexadecylpyridinium cation on the adsorption–desorption of fungicides. International Journal of Environmental Analytical Chemistry, 84, 133–141.CrossRefGoogle Scholar
Azizian, S. & Bashiri, H. (2008) Adsorption kinetics at the solid/solution interface: statistical rate theory at initial times of adsorption and close to equilibrium. Langmuir, 24, 11669–11676.CrossRefGoogle ScholarPubMed
Bashiri, H. & Javanmardi, A.H. (2021) Investigation of fractal-like characteristics according to new kinetic equation of desorption. Langmuir, 37, 2123–2128.CrossRefGoogle ScholarPubMed
Bashiri, H. & Nesari, S. (2019) Removal of alizarin yellow from water by activated carbon prepared from microwave radiation of rice husk: thermodynamic, equilibrium and kinetic study. Journal of Applied Chemistry 14, 335–352.Google Scholar
Bertolini, T.C.R., Izidoro, J.C., Magdalena, C.P. & Fungaro, D.A. (2013) Adsorption of crystal violet dye from aqueous solution onto zeolites from coal fly and bottom ashes. Orbital: The Electronic Journal of Chemistry, 5, 179–191.Google Scholar
Carrizosa, M.J., Koskinen, W.C., Hermosin, M.C. & Cornejo, J. (2001) Dicamba adsorption–desorption on organoclays. Applied Clay Science, 18, 223–231.CrossRefGoogle Scholar
Chen, L., Zhou, C.H., Fiore, S., Tong, D.S., Zhang, H., Li, C.S., Ji, S.F. & Yu, W.H. (2016) Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications. Applied Clay Science, 127–128, 143–163.CrossRefGoogle Scholar
Eris, S. & Bashiri, H. (2016) Kinetic study of the adsorption of dyes onto activated carbon. Progress in Reaction Kinetics and Mechanism, 41, 109–119.CrossRefGoogle Scholar
Falaki, Z. & Bashiri, H. (2021) Preparing an adsorbent from the unused solid waste of rosewater extraction for high efficient removal of crystal violet. Journal of the Iranian Chemical Society, 18, 2689–2702.CrossRefGoogle Scholar
Febrianto, J., Kosasih, A.N., Sunarso, J., Ju, Y.-H., Indraswati, N. & Ismadji, S. (2009) Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: a summary of recent studies. Journal of Hazardous Materials, 162, 616–645.CrossRefGoogle ScholarPubMed
Foo, K.Y. & Hameed, B.H. (2010) Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156, 2–10.CrossRefGoogle Scholar
Freundlich, H. (1907) Über die Adsorption in Lösungen. Zeitschrift für Physikalische Chemie, 57U, 385.CrossRefGoogle Scholar
Haerifar, M. & Azizian, S. (2012) Fractal-like adsorption kinetics at the solid/solution interface. Journal of Physical Chemistry C, 116, 13111–13119.CrossRefGoogle Scholar
Ho, Y.-S. (2006) Review of second-order models for adsorption systems. Journal of Hazardous Materials, 136, 681–689.CrossRefGoogle ScholarPubMed
Ishaq, M., Javed, F., Amad, I., Ullah, H., Hadi, F. & Sultan, S. (2016) Adsorption of crystal violet dye from aqueous solutions onto low-cost untreated and NaOH treated almond shell. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35, 97–106.Google Scholar
Kıranşan, M., Soltani, R.D.C., Hassani, A., Karaca, S. & Khataee, A. (2014) Preparation of cetyltrimethylammonium bromide modified montmorillonite nanomaterial for adsorption of a textile dye. Journal of the Taiwan Institute of Chemical Engineers, 45, 2565–2577.CrossRefGoogle Scholar
Koh, S.-M. & Dixon, J.B. (2001) Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene. Applied Clay Science, 18, 111–122.CrossRefGoogle Scholar
Lagergren, S. (1898) Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar, 24, 1–39.Google Scholar
Langmuir, I. (1916) The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American Chemical Society, 38, 2221–2295.CrossRefGoogle Scholar
Li, S. (2010) Removal of crystal violet from aqueous solution by sorption into semi-interpenetrated networks hydrogels constituted of poly(acrylic acid-acrylamide-methacrylate) and amylose. Bioresource Technology, 101, 2197–2202.CrossRefGoogle ScholarPubMed
Liu, B., Wang, X., Yang, B. & Sun, R. (2011) Rapid modification of montmorillonite with novel cationic Gemini surfactants and its adsorption for methyl orange. Materials Chemistry and Physics, 130, 1220–1226.CrossRefGoogle Scholar
Marczewski, A.W. (2010) Analysis of kinetic Langmuir model. Part I: integrated kinetic Langmuir equation (IKL): a new complete analytical solution of the Langmuir rate equation. Langmuir, 26, 15229–15238.CrossRefGoogle ScholarPubMed
Mousavi, S.M. & Nakhostin Panahi, P. (2016) Modeling and optimization of NH3-SCR performance of MnOx/γ-alumina nanocatalysts by response surface methodology. Journal of the Taiwan Institute of Chemical Engineers, 69, 68–77.CrossRefGoogle Scholar
Mousavi, S.M., Salari, D., Niaei, A., Panahi, P.N. & Shafiei, S. (2014) A modelling study and optimization of catalytic reduction of NO over CeO2–MnOx (0.25)–Ba mixed oxide catalyst using design of experiments. Environmental Technology, 35, 581–589.CrossRefGoogle ScholarPubMed
Nandi, B.K., Goswami, A., Das, A.K., Mondal, B. & Purkait, M.K. (2008) Kinetic and equilibrium studies on the adsorption of crystal violet dye using kaolin as an adsorbent. Separation Science and Technology, 43, 1382–1403.CrossRefGoogle Scholar
Park, Y., Ayoko, G.A., Kurdi, R., Horváth, E., Kristóf, J. & Frost, R.L. (2013) Adsorption of phenolic compounds by organoclays: implications for the removal of organic pollutants from aqueous media. Journal of Colloid and Interface Science, 406, 196–208.CrossRefGoogle ScholarPubMed
Santhana Krishna Kumar, A., Ramachandran, R., Kalidhasan, S., Rajesh, V. & Rajesh, N. (2012) Potential application of dodecylamine modified sodium montmorillonite as an effective adsorbent for hexavalent chromium. Chemical Engineering Journal, 211–212, 396–405.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019a) Adsorption of crystal violet dye by zeolite–montmorillonite: modeling, kinetic and equilibrium studies. Clay Minerals, 54, 357–368.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2019b) Removal of crystal violet dye by an efficient and low cost adsorbent: modeling, kinetic, equilibrium and thermodynamic studies. Korean Journal of Chemical Engineering, 36, 1575–1586.CrossRefGoogle Scholar
Sarabadan, M., Bashiri, H. & Mousavi, S.M. (2021) Modelling, kinetics and equilibrium studies of crystal violet adsorption on modified montmorillonite by sodium dodecyl sulfate and hyamine surfactants. Clay Minerals, 56, 16–27.CrossRefGoogle Scholar
Sarma, G.K., Sen Gupta, S. & Bhattacharyya, K.G. (2016) Adsorption of crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension. Journal of Environmental Management, 171, 1–10.CrossRefGoogle ScholarPubMed
Satapathy, M.K. & Das, P. (2014) Optimization of crystal violet dye removal using novel soil-silver nanocomposite as nanoadsorbent using response surface methodology. Journal of Environmental Chemical Engineering, 2, 708–714.CrossRefGoogle Scholar
Senthilkumaar, S., Kalaamani, P. & Subburaam, C.V. (2006) Liquid phase adsorption of crystal violet onto activated carbons derived from male flowers of coconut tree. Journal of Hazardous Materials, 136, 800–808.CrossRefGoogle ScholarPubMed
Shirzad-Siboni, M., Khataee, A., Hassani, A. & Karaca, S. (2015) Preparation, characterization and application of a CTAB-modified nanoclay for the adsorption of an herbicide from aqueous solutions: kinetic and equilibrium studies. Comptes Rendus Chimie, 18, 204–214.CrossRefGoogle Scholar
Simonin, J.-P. (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chemical Engineering Journal, 300, 254–263.CrossRefGoogle Scholar
Sips, R. (1948) On the structure of a catalyst surface. Journal of Chemical Physics, 16, 490–495.CrossRefGoogle Scholar
Temkin, M.J. & Pyzhev, V. (1940) Recent modification to Langmiur isotherms. Acta Physicochimica URSS, 12, 327–356.Google Scholar
Tran, H.N., You, S.-J. & Chao, H.-P. (2016) Thermodynamic parameters of cadmium adsorption onto orange peel calculated from various methods: a comparison study. Journal of Environmental Chemical Engineering, 4, 2671–2682.CrossRefGoogle Scholar
Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264.CrossRefGoogle Scholar
Weber, W.J. & Morris, J.C. (1963) Kinetics of adsorption on carbon from solution. Journal of the Sanitary Engineering Division, 89, 31–60.CrossRefGoogle Scholar
Yagub, M.T., Sen, T.K., Afroze, S. & Ang, H.M. (2014) Dye and its removal from aqueous solution by adsorption: a review. Advances in Colloid and Interface Science, 209, 172–184.CrossRefGoogle ScholarPubMed
Yang, H., Zhou, D., Chang, Z. & Zhang, L. (2014) Adsorption of crystal violet onto amino silica: optimization, equilibrium, and kinetic studies. Desalination and Water Treatment, 52, 6113–6121.CrossRefGoogle Scholar
Yang, X. & Al-Duri, B. (2005) Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon. Journal of Colloid and Interface Science, 287, 25–34.CrossRefGoogle ScholarPubMed
Zeldowitsch, J. (1934) Über den mechanismus der katalytischen oxydation von CO an MnO2. Acta Physicochimica URSS, 1, 449–464.Google Scholar
Zhu, R., Chen, Q., Liu, H., Ge, F., Zhu, L., Zhu, J. & He, H. (2014) Montmorillonite as a multifunctional adsorbent can simultaneously remove crystal violet, cetyltrimethylammonium, and 2-naphthol from water. Applied Clay Science, 88–89, 33–38.CrossRefGoogle Scholar