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Study of interactions between rhodamine B and a beidellite-rich clay fraction

Published online by Cambridge University Press:  06 August 2020

Hamida Belhanafi ,
Abdellah Bakhti Open the ORCID record for Abdellah Bakhti [Opens in a new window]  and
Noureddine Benderdouche
Hamida Belhanafi
Affiliation:
Laboratory of Biodiversity and Conservation of Soil and Water, Mostaganem University, B.P. 992 RP, Algeria
Abdellah Bakhti*
Affiliation:
Laboratory of Biodiversity and Conservation of Soil and Water, Mostaganem University, B.P. 992 RP, Algeria
Noureddine Benderdouche
Affiliation:
Laboratory of Structure, Elaboration and Application of Molecular Materials, Mostaganem University, B.P. 188, Algeria
*
*E-mail: bakhti02@yahoo.fr
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Abstract

The interaction between a basic dye, rhodamine B, and a separated fine fraction from natural clay was studied. Chemical analysis, X-ray diffraction and Fourier-transform infrared spectroscopy confirmed the predominance of beidellite in the fine clay fraction. The interaction of rhodamine B with the fine clay fraction showed that sorption was fast and followed a pseudo-second-order kinetic model. The comparison between sorbed rhodamine B amounts as a function of the various experimental parameters such as pH, sorbent mass, dye concentration and the presence of competing ions suggests that: (1) the sorption process is largely pH-dependent; (2) significant competition is observed between the dye and the Ca2+ and Mg2+ ions; (3) the sorption proceeds, principally, by a cation-exchange mechanism; and (4) the sorption capacity of the fine fraction in the presence of competing cations such as Ca2+ is ~0.28 mmol g–1.

Keywords

beidellitecation-exchange mechanisminteractionsrhodamine B
Type
Article
Information
Clay Minerals , Volume 55 , Issue 2 , June 2020 , pp. 194 - 202
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

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Footnotes

Associate Editor: Huaming Yang

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