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Synthesis and Characterization of ‘Epoxyphilic’ Montmorillonites

Published online by Cambridge University Press:  09 July 2018

A. Akelah ,
P. Kelly ,
S. Qutubuddin  and
A. Moet
A. Akelah
Affiliation:
Department of Macromolecular Science, Case Western Reserve University, Cleveland, OH 44106, USA
P. Kelly
Affiliation:
Department of Macromolecular Science, Case Western Reserve University, Cleveland, OH 44106, USA
S. Qutubuddin
Affiliation:
Department of Macromolecular Science, Case Western Reserve University, Cleveland, OH 44106, USA
A. Moet
Affiliation:
Department of Macromolecular Science, Case Western Reserve University, Cleveland, OH 44106, USA
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Abstract

‘Epoxyphilic’ montmorillonites were prepared containing various functional groups which can react with one or both of the components in amine-cured epoxy formulations. The preparation involves the ion exchange of six organic ammonium compounds containing either carboxylic acid, anhydride, phenolic hydroxyl, alcoholic hydroxyl, amide or amine functional groups. X-ray diffraction, elemental analysis and FTIR studies confirm the intercalation of the organic cations to form epoxyphilic montmorillonites. The adsorption behaviour of the modified montmorillonites are compared with the unmodified montmorillonite in an epoxy resin before and after the curing process.

Type
Research Article
Information
Clay Minerals , Volume 29 , Issue 2 , June 1994 , pp. 169 - 178
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

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References

Annabi-Bergaya, F., Cruz, M.I., Gatineau, L. & Fripiat, J.J. (1981) Adsorption of alcohols by smectites: IV. Models. Clay Miner, 16, 115–122.Google Scholar
Colthup, N.B., Daly, L.H. & Wiberley, S.E. (1990) Introduction to Infrared and Raman Spectroscopy. 3rd ed., Academic Press, Inc., San Diego.Google Scholar
Emerson, W.W. (1957) Organo-clay complexes. Natur, 180, 48–49.Google Scholar
Favre, H. & Lagaly, G. (1991) Organo-bentonites with quaternary alkylammonium ions. Clay Miner. 26,19-32. Greenland, D.J. (1963) Adsorption of polyvinyl alcohols by montmorillonite. J. Coll. Sci, 18, 647–664.Google Scholar
Grim, R.E. (1968) Clay Mineralogy. McGraw-Hill, New York.Google Scholar
Hawthorne, D.G., Hodgkin, J.H., Loft, B.C. & Solomon, D.H. (1974) Polymerization of vinyl monomers on mineral surfaces; a novel method of preparing reinforcing fillers. J. Macromol. Sci. Chem. A., 8, 649–657.Google Scholar
Helmer, B.M., Prescott, P.I. & Sennett, P. (1986) Surface modified kaolin in plastic. 31st Ann. Tech. Conf. Reinforced Plastics!Composites Inst., Soc. Plastics Ind. Section. Google Scholar
Hoffmann, R.W. & Brindley, G.W. (1960) Adsorption of non-ionic aliphatic molecules from aqueous solutions on montmorillonite: clay organic studies-II. Geochim. Cos- mochim. Act, 20, 15–29.Google Scholar
Jackson, M.L. (1969) Soil Chemical Analysis-Advanced Course. 2nd ed., Published by the author, Madison, Wisconsin.Google Scholar
Jordan, J.W. (1963) Organophilic clay-based thickeners. Clays Clay Miner, 10, 299–308.CrossRefGoogle Scholar
Kelly, P., Akelah, A., Qutubuddin, S. & Moet, A. (1994a) Swelling behavior of montmorillonite in epoxy. Clays Clay Miner, (submitted).Google Scholar
Kelly, P., Akelah, A., Qutubuddin, S. & Moet, A. (1994b) Reduction of residual stress in montmorillonite/epoxy materials. J. Mater. Sci. (in press).Google Scholar
Lee, H. & Neville, K. (1967) Handbook of Epoxy Resins. McGraw-Hill, New York.Google Scholar
Lee, J.F., Moreland, M.M. & Boyd, S.A. (1989) Shape selective adsorption of aromatic molecules from water by tetramethylammonium-smectite. J. Chem. Soc. Faraday Trans. 1, 85, 2953–2962.Google Scholar
Libby, P.W., Iannicelli, J. & McGill, C.R. (1976) Elastomer reinforcement with amino silane grafted kaolin. Amer. Chem. Soc., Div. Rubber Chem., Spring Meeting 18.Google Scholar
May, C. & Tanaka, Y. (1973) Epoxy Resins: Chemistry and Technology. Marcel Dekker, New York.Google Scholar
Nahin, P.G. (1963) Perspectives in applied organo-clay chemistry. Clays Clay Miner, 10, 257–271.Google Scholar
Newman, A.C.D. (editor) (1987) Chemistry of Clays and Clay Minerals. Mineralogical Society, London.Google Scholar
Pluddemann, E.P. (1978) Silane coupling agents, in: Additives for Plastics, Vol. 1 - State of the Art. (R.B. Seymour, editor). Academic Press, New York.Google Scholar
Theng, B.K.G. (1982) Clay-polymer interactions: summary and perspectives. Clays Clay Miner, 2, 1–10.Google Scholar
Usuki, A., Kojima, Y., Okada, A., Kawasumi, M., Fuku- shima, Y., Kurauchi, T. & Kamigaito, O. (1993) Synthesis of nylon 6-clay hybrid. J. Mater. Res, 8, 1179–1184.Google Scholar
Usuki, A., Mizutani, T., Fukushima, Y., Fujimoto, M., Fukumori, K., Kojima, Y., Sato, N., Kurauchi, T. & Kamigaito, O. (1989) Composite material containing a layered silicate. U.S. Patent 4,889,885. Google Scholar