Hostname: page-component-7dd5485656-kp629 Total loading time: 0 Render date: 2025-10-31T12:54:00.309Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of Citric Acid on the Formation of Short-Range Ordered Aluminosilicates

Published online by Cambridge University Press:  02 April 2024

K. Inoue  and
P. M. Huang
K. Inoue*
Affiliation:
Department of Soil Science, Saskatchewan Institute of Pedology, University of Saskatchewan, Saskatoon, Saskatchewan S7N 0W0, Canada
P. M. Huang
Affiliation:
Department of Soil Science, Saskatchewan Institute of Pedology, University of Saskatchewan, Saskatoon, Saskatchewan S7N 0W0, Canada
*
1Permanent address: Laboratory of Soil Science, Department of Agricultural Chemistry, Faculty of Agriculture, Iwate University, Morioka, Japan 020.
Get access Rights & Permissions [Opens in a new window]

Abstract

Reactions between hydroxy-Al ions and orthosilicic acid as influenced by citric acid were studied at an initial Si concentration of 1.6 × 10−3 M, Si/Al molar ratios of 0.5 and 1.0, OH/Al molar ratios of 1.0-3.0, and citric acid/Al molar ratios of 0-0.3. In the absence of citric acid and at OH/A1 ratios of 1.0-2.8, imogolite (>0.01 μm) was dominant in the precipitates. At citric acid/Al ratios of 0.01-0.1, imogolite and/or pseudoboehmite were dominant in the precipitates at OH/Al ratios of 1.0 and 2.0, and imogolite and/or ill-defined aluminosilicate complexes at OH/Al ratio of 2.8. Instead of allophane or “proto-imogolite” allophane being the predominant species in the precipitates, the formation of ill-defined aluminosilicate complexes at OH/Al ratio of 3.0 was steadily promoted by increasing the solution citric acid/Al ratios from 0 to 0.3. The freeze-dried soluble products (<0.01 μ) ranged from silica gel to “proto-imogolite,” depending upon the basicity of Al and the level of citric acid of the parent solution. The amount of “proto-imogolite” increased with increasing citric acid/Al ratios from 0 to 0.1 in solution. Complexing low molecular weight organic acids, such as citric acid, impeded the formation of the short-range ordered aluminosilicates, allophanes and imogolite.

Keywords

AllophaneAluminosilicateCitric acidHydroxy-AlImogoliteNoncrystallinePseudoboehmite

Information

Type
Research Article
Information
Clays and Clay Minerals , Volume 33 , Issue 4 , August 1985 , pp. 312 - 322
Copyright
Copyright © 1985, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Anderson, H. A., Berrow, M. L., Farmer, V. C., Hepburn, A., Russell, J. D. and Walker, A. D., 1982 A reassessment of podzol formation processes J. Soil Sci. 33 125–136.CrossRefGoogle Scholar
Bruckert, S., 1970 Effect of soluble organic compounds on pedogenesis in an acid environment. I. Field studies Ann. Agrori. 21 421–452.Google Scholar
Brydon, J. E. and Shimoda, S., 1972 Allophane and other amorphous constituents in a podzol from Nova Scotia Can. J. Soil Sci. 52 465–475.CrossRefGoogle Scholar
Cradwick, P. D. G., Farmer, V. C., Russell, J. D., Masson, C.R., Wada, K. and Yoshinaga, N., 1972 Imogolite, a hydrated aluminum silicate of tubular structure Nature Phys. Sci. 240 187–189.CrossRefGoogle Scholar
Farmer, V. C., Van Olphen, H. and Fripiat, J. J., 1979 Infrared spectroscopy Data Handbook for Clay Minerals and Other Non-Metallic Minerals Oxford Pergamon Press 285–337.Google Scholar
Farmer, V. C., 1981 Possible roles of a mobile hydroxy-aluminium orthosilicate complex (proto-imogolite) and other hydroxyaluminium and hydroxy-iron species in pod-zolization Migrations Organominérales dans les Sols Tempérés, Colloques Internationaux du C.N.R.S. No. 303 275–279.Google Scholar
Farmer, V. C., Fraser, A. R., Mortland, M. M. and Farmer, V. C., 1979 Synthetic imogolite, a tubular hydroxyaluminurn silicate Proc. Int. Clay Conf., Oxford, 1978 Elsevier Amsterdam 547–553.Google Scholar
Farmer, V. C., Fraser, A. R., Russell, J. D. and Yoshinaga, N., 1977 Recognition of imogolite structures in allo-phanic clays by infrared spectroscopy Clay Miner. 12 55–57.CrossRefGoogle Scholar
Farmer, V. C., Fraser, A. R. and Tait, J. M., 1977 Synthesis of imogolite J. Chem. Soc. Chem. Comm. 462–463.CrossRefGoogle Scholar
Farmer, V. C., Fraser, A. R. and Tait, J. M., 1979 Characterization of the chemical structures of natural and synthetic aluminosilicate gels and soils by infrared spectroscopy Geochim. Cosmochim. Acta 43 1417–1420.CrossRefGoogle Scholar
Farmer, V. C., Fraser, A. R., Tait, J. M., Palmieri, F., Violante, P., Nakai, M. and Yoshinaga, N., 1978 Imogolite and proto-imogolite in an Italian soil developed on volcanic ash Clay Miner. 13 271–274.CrossRefGoogle Scholar
Farmer, V. C., Russell, J. D. and Berrow, M. L., 1980 Imogolite and proto-imogolite allophane in spodic horizons: evidence for a mobile aluminium silicate complex in podzol formation J. Soil Sci. 31 673–684.CrossRefGoogle Scholar
Fanner, V. C., Russell, J. D. and Smith, B. F. L., 1983 Extraction of inorganic forms of translocated Al, Fe, and Si from a podzol Bs horizon J. Soil Sci. 34 571–576.Google Scholar
Henmi, T. and Wada, K., 1976 Morphology and composition of allophane Amer. Mineral. 61 379–390.Google Scholar
Higashi, T. and Ikeda, H., 1974 Dissolution of allophane by acid oxalate solution Clay Sci. Tokyo 4 205–211.Google Scholar
Hsu, P. H., 1963 Effect of initial pH, phosphate, and silicate on the determination of aluminum with aluminon Soil Sci. 96 230–238.CrossRefGoogle Scholar
Hsu, P. H., Dixon, J. B. and Weed, S. B., 1977 Aluminum hydroxides and oxyhydroxides Minerals in Soil Environments Madison, Wisconsin Soil Sci. Soc. Amer. 99–143.Google Scholar
Inoue, K., Yoshida, M. and Henmi, T., 1980 The occurrence of allophane in stream-deposits from Shishigahana at the northern foot of Mt. Chokai, Japan Clay Sci. Tokyo 5 267–276.Google Scholar
Inoue, K. and Huang, P. M., 1984 Influence of citric acid on the natural formation of imogolite Nature 308 58–60.CrossRefGoogle Scholar
Kodama, H. and Schnitzer, M., 1980 Effect of fulvic acid on the crystallization of aluminum hydroxides Geoderma 24 195–205.CrossRefGoogle Scholar
Kwong, N. K. K. F. and Huang, P. M., 1975 Influence of citric acid on the crystallization of aluminum hydroxides Clays & Clay Minerals 23 164–165.Google Scholar
Kwong, N., Kee, K. F. and Huang, P. M., 1977 Influence of citric acid on the hydrolytic reactions of aluminum Soil Sci. Soc. Amer. J. 41 692–697.CrossRefGoogle Scholar
Kwong, N. K. K. F. and Huang, P. M., 1979 The relative influence of low-molecular-weight, complexing organic acids on the hydrolysis and precipitation of aluminum Soil Sci. 128 337–342.CrossRefGoogle Scholar
McKeague, J. A. and Kodama, H., 1981 Imogolite in cemented horizons of some British Columbia soils Geoderma 25 189–197.CrossRefGoogle Scholar
Parfitt, R. L. and Henmi, T., 1980 Structure of some allophanes from New Zealand Clays & Clay Minerals 28 285–294.CrossRefGoogle Scholar
Ross, G. J. and Kodama, H., 1979 Evidence for imogolite in Canadian soils Clays & Clay Minerals 27 297–300.CrossRefGoogle Scholar
Schnitzer, M., Schnitzer, M. and Khan, S. U., 1978 Humic substances Chemistry and Reactions: Soil Organic Matter Elsevier Amsterdam 1–64.Google Scholar
Stevenson, F. J., McLaren, A. D. and Peterson, G. H., 1967 Organic acids in soils Soil Biochemistry New York Marcel Dekker 119–146.Google Scholar
Tait, J. M., Yoshinaga, N. and Mitchell, B. D., 1978 The occurrence of imogolite in some Scottish soils Soil Sci. Plant Nutr. Tokyo 24 145–151.CrossRefGoogle Scholar
Violante, A. and Violante, P., 1980 Influence of pH, concentration, and chelating power of organic anions on the synthesis of aluminum hydroxides and oxyhydroxides Clays & Clay Minerals 28 425–434.CrossRefGoogle Scholar
Violante, P. and Tait, J. M., 1979 Identification of imogolite in some volcanic soils from Italy Clay Miner. 14 155–158.CrossRefGoogle Scholar
Wada, K., Dixon, J. B. and Weed, S. B., 1977 Allophane and imogolite Minerals in Soil Environments Madison, Wisconsin Soil Sci. Soc. Amer. 603–638.Google Scholar
Wada, K., Mortland, M. M. and Fanner, V. C., 1979 Structural formulas of allophanes Proc. Int. Clay Conf., Oxford, 1978 Elsevier Amsterdam 537–545.Google Scholar
Wada, K. and Theng, B. K. G., 1980 Mineralogical characteristics of Andisols Soils with Variable Charge New Zealand New Zealand Soc. Soil Sci., Palmerston North 87–107.Google Scholar
Wada, K. and Greenland, D. J., 1970 Selective dissolution and differential infrared spectroscopy for characterization of “amorphous” constituents in soil clays Clay Miner. 8 241–254.CrossRefGoogle Scholar
Wada, K., Henmi, T., Yoshinaga, N. and Patterson, S. H., 1972 Imogolite and allophane formed in saprolite of basalt on Maui, Hawaii Clays & Clay Minerals 20 375–380.CrossRefGoogle Scholar
Wada, K. and Harward, M. E., 1974 Amorphous clay constituents of soils Adv. Agron. 26 211–260.CrossRefGoogle Scholar
Wada, S.-I., Eto, A. and Wada, K., 1979 Synthetic allophane and imogolite J. Soil Sci. 30 347–355.CrossRefGoogle Scholar
Weaver, R. M., Syers, J. K. and Jackson, M. L., 1968 Determination of silica in citrate-bicarbonate-dithionite extracts of soils Soil Sci. Soc. Amer. Proc. 32 497–501.CrossRefGoogle Scholar
Wells, N., Childs, C. W. and Downes, C.J., 1977 Silica Springs, Tongariro National Park, New Zealand—analyses of the spring water and characterization of the alumino-silicate deposit Geochim. Cosmochim. Acta 41 1497–1506.CrossRefGoogle Scholar
Young, A. W., Campbell, A. S. and Walker, T. W., 1980 Allophane isolated from a podzol developed on a non-vitric parent material Nature 284 46–48.CrossRefGoogle Scholar