Hostname: page-component-76fb5796d-r6qrq Total loading time: 0 Render date: 2024-04-29T08:33:58.998Z Has data issue: false hasContentIssue false
  • English
  • Français

Controlled Polymerization of Metanilic Anion within the Interlayer of NiAl Layered Double Hydroxide

Published online by Cambridge University Press:  01 January 2024

Xiaofei Tian ,
Min Wei ,
David G. Evans ,
Guoying Rao  and
Heli Yang
Xiaofei Tian
Affiliation:
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Min Wei*
Affiliation:
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
David G. Evans
Affiliation:
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Guoying Rao
Affiliation:
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Heli Yang
Affiliation:
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
*
*E-mail address of corresponding author: weimin@mail.buct.edu.cn
Get access Rights & Permissions [Opens in a new window]

Abstract

The controlled chemical oxidative polymerization of metanilic anion (m-NH2C6H4SO3−)$(m{\rm{ - N}}{{\rm{H}}_2}{{\rm{C}}_6}{{\rm{H}}_4}{\rm{SO}}_3^ - )$ within the interlayer of NiAl layered double hydroxide was performed using, for the first time, ammonium persulfate as the oxidizing agent. The quantity of oxidizing agent required for control of the interlayer polymerization was investigated systematically and it was found that interleaved polyaniline sulfonic (PANIS) was present in different oxidation states and protonation levels when different quantities of external oxidizing agents were added. A mechanism for the oxidative polymerization of metanilic anion in NiAl layered double hydroxide is proposed, based on the intercalation of the oxidizing agent and the interlayer polymerization of monomer. The resulting PANIS/NiAl LDH composites were characterized by powder X-ray diffraction, ultraviolet-visible absorption spectra, Fourier transform infrared and X-ray photoelectron spectroscopy.

Keywords

In Situ PolymerizationLayered Double HydroxidePolyaniline
Type
Research Article
Information
Clays and Clay Minerals , Volume 54 , Issue 4 , August 2006 , pp. 418 - 425
Copyright
Copyright © 2006, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Albuquerque, J.E. Mattoso, LHCR Faria, M. Masters, J.G. and MacDiarmid, A.G., (2004) Study of the interconversion of polyaniline oxidation states by optical absorption spectroscopy Synthetic Metals 146 1–10 10.1016/j.synthmet.2004.05.019.CrossRefGoogle Scholar
Brindley, G.W. and Kikkawa, S., (1979) A crystal-chemical study of Mg,Al and Ni,Al hydroxy-perchlorates and hydroxycarbonates American Mineralogist 64 836–843.Google Scholar
Challier, T. and Slade, R.C.T., (1994) Nanocomposite materials: polyaniline intercalated layered double hydroxides Journal of Materials Chemistry 4 367–371 10.1039/jm9940400367.CrossRefGoogle Scholar
Chen, W.-C. and Wen, T.-C., (2003) Electrochemical and capacitive properties of polyaniline-implanted porous carbon electrode for supercapacitors Journal of Power Sources 117 273–282 10.1016/S0378-7753(03)00158-7.CrossRefGoogle Scholar
Huber, T.A. (2003) A Literature Survey of Polyaniline, Part 1 Polyaniline as a Radar Absorbing Material. Defence R&D Canada — Atlantic, 014.Google Scholar
Isupov, V.P. Chupakhina, L.E. Ozerova, M.A. Kostrovsky, V.G. and Poluboyarov, V.A., (2001) Polymerization of m-NH2C6H4COO anions in the intercalation compounds of aluminium hydroxide [LiAl2(OH)6] [m-NH2C6H4COO].nH2O Solid State Ionics 141–142 231–236 10.1016/S0167-2738(01)00751-2.CrossRefGoogle Scholar
Kang, E.T. Neoh, K.G. and Tan, K.L., (1998) Polyaniline: A polymer with many interesting intrinsic redox states Progress in Polymer Science 23 277–324 10.1016/S0079-6700(97)00030-0.CrossRefGoogle Scholar
Leroux, F. and Besse, J.P., (2001) Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites Chemistry of Materials 13 3507–3515 10.1021/cm0110268.CrossRefGoogle Scholar
Li, F. Zhang, L. Evans, D.G. Forano, C. and Duan, X., (2004) Structure and thermal evolution of Mg—Al layered double hydroxide containing interlayer organic glyphosate anions Thermochimica Acta 424 15–23 10.1016/j.tca.2004.05.007.CrossRefGoogle Scholar
Liu, P. Liu, W. and Xue, Q., (2004) In situ chemical oxidative graft polymerization of aniline from silica nanoparticles Materials Chemistry and Physics 87 109–113 10.1016/j.matchemphys.2004.05.001.CrossRefGoogle Scholar
Liu, Y.-J. and Kanatzidis, M.G., (1995) Post-intercalative polymerization of aniline and its derivatives in layered metal phosphates Chemistry of Materials 7 1525–1533 10.1021/cm00056a019.CrossRefGoogle Scholar
Luca, V. and Thomson, S., (2000) Intercalation and polymerisation of aniline within a tubular aluminosilicate Journal of Materials Chemistry 10 2121–2126 10.1039/b000741m.CrossRefGoogle Scholar
Mohilner, D.M. Argersinger, W.J. and Adams, R.N., (1962) Investigation of kinetics and mechanism of anodic oxidation of aniline in aqueous sulfuric acid solution at a platinum electrode Journal of the American Chemical Society 84 3618–3620 10.1021/ja00878a003.CrossRefGoogle Scholar
Moujahid, E.M. Dubois, M. Besse, J.P. and Leroux, F., (2002) Role of atmospheric oxygen for the polymerization of interleaved aniline sulfonic acid in LDH Chemistry of Materials 14 3799–3807 10.1021/cm0211094.CrossRefGoogle Scholar
Moujahid, E.M. Leroux, F. Marc, D. and Besse, J.P., (2003) In situ polymerisation of monomers in layered double hydroxides Comptes Rendus Chimie 6 259–264 10.1016/S1631-0748(03)00002-X.CrossRefGoogle Scholar
Moujahid, E.M. Dubois, M. Besse, J.P. and Leroux, F., (2005) In situ polymerization of aniline sulfonic acid derivatives into LDH interlamellar space probed by ESR and electrochemical studies Chemistry of Materials 17 373–382 10.1021/cm0401701.CrossRefGoogle Scholar
Nascimento, G.M. Constantino, V.R.L. Landers, R. and Temperini, M.L.A., (2004) Aniline polymerization into montmorillonite clay: a spectroscopic investigation of the intercalated conducting polymer Macromolecules 37 9373–9385 10.1021/ma049054+.CrossRefGoogle Scholar
Stejskal, J. Kratochvíl, P. and Jenkins, A.D., (1996) The formation of polyaniline and the nature of its structures Polymer 37 367–369 10.1016/0032-3861(96)81113-X.CrossRefGoogle Scholar
Tronto, J. Sanchez, K.C. Crepaldi, E.L. Naal, Z. and Klein, S.I., (2004) Synthesis, characterization and electrochemical study of layered double hydroxides intercalated with 2-thiophenecarboxylate anions Journal of Physics and Chemistry of Solids 65 493–498 10.1016/j.jpcs.2003.09.021.CrossRefGoogle Scholar
Vieille, L. Moujahid, E.M. Taviot-Guého, C. Cellier, J. Besse, J.P. and Leroux, F., (2004) In situ polymerization of interleaved monomers: a comparative study between hydrotalcite and hydrocalumite host structures Journal of Physics and Chemistry of Solids 65 385–393 10.1016/j.jpcs.2003.08.029.CrossRefGoogle Scholar
Wei, X.L. Fahlman, M. and Epstein, A.J., (1999) XPS study of highly sulfonated polyaniline Macromolecules 32 3114–3117 10.1021/ma981386p.CrossRefGoogle Scholar
Whilton, N.T. Vickers, P.J. and Mann, S., (1997) Bioinorganic clays: synthesis and characterization of amino- and polyamino acid intercalated layered double hydroxides Journal of Materials Chemistry 7 1623–1629 10.1039/a701237c.CrossRefGoogle Scholar
Wilson, J. Olorunyolemi, T. Jaworski, A. Borum, L. Young, D. Siriwat, A. and Dickens, E., (1999) Surface and interfacial properties of polymer-intercalated layered double hydroxide nanocomposites Applied Clay Science 15 265–279 10.1016/S0169-1317(99)00023-X.CrossRefGoogle Scholar
Yun, S.K. and Pinnavaia, T.J., (1995) Water content and particle texture of synthetic hydrotalcite-like layered double hydroxides Chemistry of Materials 7 348–354 10.1021/cm00050a017.CrossRefGoogle Scholar