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The Properties of Clay Minerals in Soil Particles from Two Ultisols, China

Published online by Cambridge University Press:  01 January 2024

Zhi Yi Zhang ,
Li Huang ,
Fan Liu ,
Ming Kuang Wang ,
Qing Ling Fu  and
Jun Zhu
Zhi Yi Zhang
Affiliation:
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Li Huang*
Affiliation:
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Fan Liu
Affiliation:
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Ming Kuang Wang
Affiliation:
Department of Agricultural Chemistry, National Taiwan University, Taipei 10617, Taiwan
Qing Ling Fu
Affiliation:
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
Jun Zhu
Affiliation:
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of Yangtze River), Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, China
*
*E-mail address of corresponding author: huang_li62@aliyun.com
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Abstract

Soil aggregates consist of sand, silt, and clay size particles. Many of the clay size particles in soils are clay minerals, which actively influence soil behavior. The properties of clay minerals may change significantly as soil particle size decreases to the nanoscale; however, little information is available about these properties for the Ultisols in China. In the present study, the clay mineral components and structural characteristics of four particle-size fractions (i.e., <2000, 450–2000, 100–450, and 25–100 nm) of two Ultisol samples (Ult-1 and Ult-2) were investigated using elemental analysis, X-ray diffraction, Fouriertransform infrared spectroscopy, and thermal analysis. The molar SiO2 to Al2O3 ratios were lower in the nanoscale particle-size fraction (25–100 nm) than in the 450–2000 and <2000 nm fractions. This indicates greater desilicification and allitization of the smaller Ultisol particles. Furthermore, the Fe oxide and Al oxide contents increased and reached a maximum level in the 25–100 nm fraction of the two Ultisols. Goethite was mainly found in the 100–450 nm and 25–100 nm fractions. The dominant clay minerals in the Ultisol 25–100 nm fraction were kaolinite and illite with a small amount of a hydroxy-interlayered mineral in Ult-1 and gibbsite in Ult-2. The kaolinite crystallinity decreased as particle size decreased. The low crystallinity of the kaolinite in the A horizon 25–100 nm fraction was attributed to a reduction in the thickness of coherent scattering domains, as well as to decreases in OH groups and the dimensions of octahedral AlO6 sheets. A determination of the chemical and mineralogic properties of the different size fractions of the Ultisols is important to understand the desilicification and Al and Fe oxide enrichment mechanisms during soil formation. The significance of these results can help to reveal the nanoscale transformations of clay minerals. Analysis of clay mineral compositions in nanoparticles can provide the additional data needed to understand the adsorption and mobility of nutrients and pollutants.

Keywords

Clay MineralCrystallinityKaoliniteMean Crystal DimensionNanoparticlesUltisol
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 4 , August 2017 , pp. 273 - 285
Copyright
Copyright © Clay Minerals Society 2017

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References

Assemi, S. Sharma, S. Tadjiki, S. Prisbrey, K. Ranville, J. and Miller, J. D., 2015 Effect of surface charge and elemental composition on the swelling and delamination of montmorillonite nanoclays using sedimentation field-flow fractionation and mass spectroscopy Clays and Clay Minerals 63 457–468.CrossRefGoogle Scholar
Banfield, J.F. and Zhang, H.Z., 2001 Nanoparticles in the environment Nanoparticles and the Environment 44 1–58.Google Scholar
Bardy, M. Bonhomme, C. Fritsch, E. Maquet, J. Hajjar, R. Allard, T. Derenne, S. and Calas, G., 2007 Al speciation in tropical podzols of the upper Amazon Basin: a solid-state 27Al MAS and MQMAS NMR study Geochimica et Cosmochimica Acta 71 3211–3222.CrossRefGoogle Scholar
Chamley, H., 1989 Clay Sedimentology.CrossRefGoogle Scholar
Chiang, H.C. Wang, M.K. Houng, K.H. White, N. and Dixon, J., 1999 Mineralogy of B horizons in Alpine forest soils of Taiwan Soil Science 164 111–122.CrossRefGoogle Scholar
Churchman, G.J. Whitton, J.S. Claridge, G.G.C. and Theng, B.K.G., 1984 Intercalation method using formamide for differentiating halloysite from kaolinite Clays and Clay Minerals 32 241–248.CrossRefGoogle Scholar
Dahlgren, R.A. Boettinger, J.L. Huntington, G.L. and Amundson, R.G., 1997 Soil development along an elevational transect in the western Sierra Nevada, California Geoderma 78 207–236.CrossRefGoogle Scholar
Deepthy, R. and Balakrishnan, S., 2005 Climatic control on clay mineral formation: Evidence from weathering profiles developed on either side of the Western Ghats Journal of Earth System Science 114 545–556.CrossRefGoogle Scholar
Dohrmann, R., 2006 Problems in CEC determination of calcareous clayey sediments using the ammonium acetate method Journal of Plant Nutrition and Soil Science 169 330–334.CrossRefGoogle Scholar
Dudek, T. Cuadros, J. and Huertas, J., 2007 Structure of mixed-layer kaolinite-smectite and smectite-to-kaolinite transformation mechanism from synthesis experiments American Mineralogist 92 179–192.CrossRefGoogle Scholar
Egli, M. Mirabella, A. and Sartori, G., 2008 The role of climate and vegetation in weathering and clay mineral formation in late Quaternary soils of the Swiss and Italian Alps Geomorphology 102 307–324.CrossRefGoogle Scholar
Eisazadeh, A. Kassim, K.A. and Nur, H., 2012 Solid-state NMR and FTIR studies of lime stabilized montmorillonitic and lateritic clays Applied Clay Science 67-68 5–10.CrossRefGoogle Scholar
Fernandez, R. Martirena, F. and Scrivener, K.L., 2011 The origin of the pozzolanic activity of calcined clay minerals: a comparison between kaolinite, illite and montmorillonite Cement and Concrete Research 41 113–122.CrossRefGoogle Scholar
Gee, G.W. and Bauder, J.W., 1986 Particle-size analysis Methods of Soil Analysis 9 383–411.Google Scholar
He, Y. Li, D.C. Velde, B. Yang, Y.F. Huang, C.M. Gong, Z.T. and Zhang, G.L., 2008 Clay minerals in a soil chronosequence derived from basalt on Hainan Island, China and its implication for pedogenesis Geoderma 148 206–212.CrossRefGoogle Scholar
He, Y. Zeng, F. Lian, Z. Xu, J. and Brookes, P.C., 2015 Natural soil mineral nanoparticles are novel sorbents for pentachlorophenol and phenanthrene removal Environmental Pollution 205 43–51.CrossRefGoogle ScholarPubMed
Hong, H. Churchman, G.J. Gu, Y. Yin, K. and Wang, C., 2012 Kaolinite-smectite mixed-layer clays in the Jiujiang red soils and their climate significance Geoderma 173 75–83.CrossRefGoogle Scholar
Hu, P. and Yang, H., 2013 Insight into the physicochemical aspects of kaolins with different morphologies Applied Clay Science 74 58–65.CrossRefGoogle Scholar
Huang, C.Y., 2000 Soil Science Beijing. China Agriculture Press..Google Scholar
Huang, L. Wang, C.Y. Tan, W.F. Hu, H.Q. Cai, C.F. and Wang, M.K., 2010 Distribution of organic matter in aggregates of eroded Ultisols, Central China Soil and Tillage Research 108 59–67.CrossRefGoogle Scholar
Huang, P.M., Li, Y., and Sumner, M.E. (2012) Handbook of Soil Science: Properties and Processes, 2nded., (Sumner, M.E., editor). CRC Press, Taylor and Francis, Boca Raton, FL.Google Scholar
Hughes, J.C. and Brown, G., 1979 A crystallinity index for soil kaolinite and its relation to parent rock, climate and soil maturity European Journal of Soil Science 30 557–563.CrossRefGoogle Scholar
Jackson, M.L., 1979 Soil Chemical Analysis-Advanced Course, 2nd ed Madison, Wisconsin Author.Google Scholar
Jiang, J. Xu, R.-K. and Zhao, A.-Z., 2010 Comparison of the surface chemical properties of four soils derived from Quaternary red earth as related to soil evolution Catena 80 154–161.CrossRefGoogle Scholar
Kanket, W. Suddhiprakarn, A. Kheoruenromne, I. and Gilkes, R.J., 2005 Chemical and crystallographic properties of kaolin from Ultisols in Thailand Clays and Clay Minerals 53 478–489.CrossRefGoogle Scholar
Klug, H.P. and Alexander, L.E., 1974 X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials 960.Google Scholar
Lessovaia, S. Dultz, S. Polekhovsky, Y. Krupskaya, V. Vigasina, M. and Melchakova, L., 2012 Rock control of pedogenic clay mineral formation in a shallow soil from serpentinous dunite in the Polar Urals, Russia Applied Clay Science 64 4–11.CrossRefGoogle Scholar
Li, W. He, Y. Wu, J. and Xu, J., 2012 Extraction and characterization of natural soil nanoparticles from Chinese soils European Journal of Soil Science 63 754–761.CrossRefGoogle Scholar
Li, W. Zhu, X. Yan, H. Xing, B. Xu, J. and Brookes, P.C., 2013 Enhancement of water solubility and mobility of phenanthrene by natural soil nanoparticles Environmental Pollution 176 228–233.CrossRefGoogle ScholarPubMed
Madejová, J., 2003 FTIR techniques in clay mineral studies Vibrational Spectroscopy 31 1–10.CrossRefGoogle Scholar
Maia, A.B. Angélica, R.S. Neves, R.F. Pöllmann, H. Straub, C. and Saalwächter, K., 2014 Use of 29Si and 27Al MAS NMR to study thermal activation of kaolinites from Brazilian Amazon kaolin wastes Applied Clay Science 87 189–196.CrossRefGoogle Scholar
Mckeague, J.A. and Day, J.H., 1966 Dithionite and oxalateextractable Fe and Al as aids in differentiating various classes of soils Canadian Journal of Soil Science 46 13–22.CrossRefGoogle Scholar
Mehra, O.P. and Jackson, M.L., 1960 Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals 7 317–327.CrossRefGoogle Scholar
Melo, V.F. Singh, B. Schaefer, CEGR Novais, R.F. and Fontes, M.P.F., 2001 Chemical and mineralogical properties of kaolinite-rich Brazilian soils Soil Science Society of America Journal 65 1324–1333.CrossRefGoogle Scholar
Meunier, A., 2006 Why are clay minerals small? Clay Minerals 41 551–566.CrossRefGoogle Scholar
Mirabella, A. and Egli, M., 2003 Structural transformations of clay minerals in soils of a climosequence in an Italian alpine environment Clays and Clay Minerals 51 264–278.CrossRefGoogle Scholar
Nelson, D.W. Sommers, L.E., Sparks, D.L., 1996 Total carbon, organic carbon, and organic matter Methods of Soil Analysis. Part 3. Chemical Methods. No. 5 Madison, Wisconsin ASA and SSSA 961–1010.Google Scholar
Pai, C.W. Wang, M.K. and Houng, W.K.H., 1999 Smectites in iron-rich calcareous soil and black soils of Taiwan Clays and Clay Minerals 47 389–398.Google Scholar
Percival, H.J. Duncan, J.F. and Foster, P.K., 1974 Interpretation of the kaolinite-mullite reaction sequence from infrared absorption spectra Journal of the American Ceramic Society 57 57–61.CrossRefGoogle Scholar
Regelink, I.C. Weng, L. and Riemsdijk, W.H.V., 2011 The contribution of organic and mineral colloidal nanoparticles to element transport in a podzol soil Applied Geochemistry 26 S241–S244.CrossRefGoogle Scholar
Regelink, I.C. Weng, L. Koopmans, G.F. and Riemsdijk, W.H.V., 2013 Asymmetric flow field-flow fractionation as a new approach to analyse iron-(hydr)oxide nanoparticles in soil extracts Geoderma 202 134–141.CrossRefGoogle Scholar
Rhoades, J.D., Page, A.L., 1982 Cation exchange capacity Methods of Soil Analysis, part 2, 2nd ed Madison, Wisconsin ASA and SSSA 149–157.Google Scholar
Ríos, C.A. Williams, C.D. and Fullen, M.A., 2009 Nucleation and growth history of zeolite LTA synthesized from kaolinite by two different methods Applied Clay Science 42 446–454.CrossRefGoogle Scholar
Rocha, J. and Klinowski, J., 1990 29Si and 27Al magic-anglespinning NMR studies of the thermal transformation of kaolinite Physics and Chemistry of Minerals 17 179–186.CrossRefGoogle Scholar
Ryan, P.C. Huertas, F.J. Hobbs, F.C. and Pincus, L.N., 2016 Kaolinite and halloysite derived from sequential transformation of pedogenic smectite and kaolinite-smectite in a 120 ka tropical soil chronosequence Clays and Clay Minerals 64 488–516.CrossRefGoogle Scholar
Singh, B. and Gilkes, R.J., 1992 Properties of soil kaolinites from south-western Australia Journal of Soil Science 43 645–667.CrossRefGoogle Scholar
Szymański, W. Skiba, M. Nikorych, V.A. and Kuligiewicz, A., 2014 Nature and formation of interlayer fillings in clay minerals in Albeluvisols from the Carpathian Foothills, Poland Geoderma 235-236 396–409.CrossRefGoogle Scholar
Theng, B.K.G. and Yuan, G., 2008 Nanoparticles in the soil environment Elements 4 395–399.CrossRefGoogle Scholar
Tsao, T.M. Chen, Y.M. and Wang, M.K., 2011 Origin, separation and identification of environmental nanoparticles: a review Journal of Environmental Monitoring 13 1156–1163.CrossRefGoogle ScholarPubMed
US EPA., 1996 Microwave Assisted Acid Digestion of Siliceous and Organically Based Matrices. Method 3052, EPA SW-846, Ch 3.2 Washington, DC United States Environmental Protection Agency.Google Scholar
USDA Soil Survey Staff., 2014 Keys to Soil Taxonomy, 12th ed Washington, D.C United States Department of Agriculture.Google Scholar
Velde, B., 1992 Introduction to Clay Minerals: Chemistry, Origin, Uses and Environmental Significance London Springer.CrossRefGoogle Scholar
Viennet, J.C. Hubert, F. Ferrage, E. Tertre, E. Legout, A. and Turpault, M.P., 2015 Investigation of clay mineralogy in a temperate acidic soil of a forest using X-ray diffraction profile modeling: Beyond the HIS and HIV description Geoderma 241-242 75–86.CrossRefGoogle Scholar
Wada, K., Dixon, J.B. and Weed, S.B., 1989 Allophane and Imogolite Minerals in Soil Environments Madison, Wisconsin Soil Science Society of America 1051–1087.Google Scholar
Wilson, M.J., 1987 A Handbook of Determinative Methods in Clay Mineralogy New York Blackie.Google Scholar
Yin, K. Hong, H. Churchman, G.J. Li, R. Li, Z. Wang, C. and Han, W., 2013 Hydroxy-interlayered vermiculite genesis in Jiujiang late-Pleistocene red earth sediments and significance to climate Applied Clay Science 74 20–27.CrossRefGoogle Scholar
Zhang, Z.Y. Huang, L. Liu, F. Wang, M.K. Fu, Q.L. and Zhu, J., 2016 Characteristics of clay minerals in soil particles of two Alfisols in China Applied Clay Science 120 51–60.CrossRefGoogle Scholar
Zhou, C.H. and Keeling, J., 2013 Fundamental and applied research on clay minerals: From climate and environment to nanotechnology Applied Clay Science 74 3–9.CrossRefGoogle Scholar