Hostname: page-component-848d4c4894-x5gtn Total loading time: 0 Render date: 2024-05-21T06:35:52.355Z Has data issue: false hasContentIssue false

Traprock Transformation into Clayey Materials in Soil Environments of the Central Siberian Plateau, Russia

Published online by Cambridge University Press:  01 January 2024

Sofia N. Lessovaia*
Affiliation:
St. Petersburg State University, Universitetskaya nab. 7/9, 199034, St. Petersburg, Russia
Michael Plötze
Affiliation:
ETH Zurich, Institute for Geotechnical Engineering, CH-8093, Zurich, Switzerland
Svyatoslav Inozemzev
Affiliation:
Dokuchaev Soil Science Society, Pyzhevsky 7, 119017, Moscow, Russia
Sergey Goryachkin
Affiliation:
Institute of Geography, Russian Academy of Science, Staromonetnyi per. 119017, Moscow, Russia
*
*E-mail address of corresponding author: lessovaia@yahoo.com

Abstract

The study of hard rock conversion into fine earths and clayey materials in the pedosphere is important in understanding the relative proportions of recent soil features to features that were inherited from ancient epochs. Cold environments are widely thought to be areas of physical weathering, but the coexistence of physical and chemical processes have also been shown. To further examine mafic rock (dolerite) weathering in soil environments and the conversion into clayey materials, Entic Podzols formed in the cold continental climate were studied. The key study was located in the central part of the flood basalt complex, or traps (traprocks), of the Central Siberian Plateau (Russia). The qualitative mineralogy was studied using X-ray diffraction and the quantitative mineral composition was determined using X-ray diffraction and subsequent Rietveld analysis. The micromorphological characteristics of the soils were studied in thin sections. Dolerite fragments and fine earths were sampled from soil profiles underlain by dolerite. XRD analyses indicated that pyroxene and especially plagioclase contents in the dolerite fragments and fine earths decreased from the bottom to the top soil horizons mostly in the mature soil profiles that were affected by chemical weathering of dolerite. The dioctahedral and trioctahedral smectites in the soils were inherited from a dolerite previously subjected to chemical weathering. The smectite was conserved in the inherited aggregates and protected against dissolution even in acidic soil horizons. Recent pedogenesis processes fractured individual fragments, converted it into soil micromass, and slightly decreased the total smectite content of the <1 µm soil fraction. However, in soil samples collected from the bottom to the top horizons of a mature soil profile, trioctahedral smectite contents decreased as dioctahedral smectite contents increased. This suggests that dioctahedral smectites formed by pedogenic alteration of inherited trioctahedral smectites.

Type
Article
Copyright
Copyright © Clay Minerals Society 2016

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

This paper is published as part of a special section on the subject of ‘Clays in the Critical Zone,’ arising out of presentations made during the 2015 Clay Minerals Society-Euroclay Conference held in Edinburgh, UK.

References

Alekseev, A. Alekseeva, T. Ostroumov, V. Siegert, C. and Gradusov, B., 2003 Mineral transformation in permafrost-affected soils, North Kolyma Lowland, Russia Soil Science Society of America Journal 67 596605.Google Scholar
Bergmann, J. and Kleeberg, R., 1998 Rietveld analysis of disordered layer silicates Materials Science Forum 278-281 300305.CrossRefGoogle Scholar
Bergmann, J. Friedel, P. and Kleeberg, R., 1998 BGMN - a new fundamental parameters based Rietveld program for laboratory X-ray sources, it’s use in quantitative analysis and structure investigations CPD Newsletter 20 58.Google Scholar
Bish, D.L. Plötze, M., Christidis, G., 2011 X-ray Powder diffraction with emphasis on qualitative and quantitative analysis in industrial mineralogy Advances in the characterization of Industrial Minerals 3576.CrossRefGoogle Scholar
Borden, P.W. Ping, C-Lu McCarthy, P.J. and Naidu, S., 2010 Clay mineralogy in Arctic Tundra Gelisols, Northern Alaska Soil Science Society of America Journal 74 580592.CrossRefGoogle Scholar
Dainyak, L.G. Dritz, V.A. Kudryavtzev, D.I. Simanovitch, I.M. and Slonimskaya, M.V., 1981 Novaya mineral’naya raznovidnost’ trioktaedricheskech smektitov iz effuzivnych basaltov Tungusskoi sineklizy Lithology and Mineral Resources 6 123129 (New mineral variant of trioctahedral smectites from effusive basalts of Tungusskaya sineclise).Google Scholar
Ganor, J. Roueff, E. Erel, Y. and Blum, J.D., 2005 The dissolution kinetics of a granite and its minerals — Implications for comparison between laboratory and field dissolution rates Geochimica et Cosmochimica Acta 3 607621.CrossRefGoogle Scholar
Girty, G.H. Marsh, J. Meltzner, A. McConnell, J.R. Nygren, D. Nygren, J. Prince, G.M. Randall, K. Johnson, D. Heitman, B. and Nielsen, J., 2003 Assessing changes in elemental mass as a result of chemical weathering of granodiorite in a Mediterranean (hot summer) climate Journal of Sedimentary Research 73 434443.CrossRefGoogle Scholar
Gorbunov, N. (editor) (1971) Metody mineralogicheskogo i mikromorphologicheskogo izucheniya pochv (Methods of mineralogical and micromorphological study of soils). 1971. Nauka, Moscow, 175 pp (in Russian).Google Scholar
Hall, K. Thorn, C.E. Matsuoka, N. and Prick, A., 2002 Weathering in cold regions: some thoughts and perspectives Progress in Physical Geography 26 577603.CrossRefGoogle Scholar
Hodson, M.E., 2003 The influence of Fe-rich coatings on the dissolution of anorthite at pH 2.6 Geochimica et Cosmochimica Acta 67 33553363.CrossRefGoogle Scholar
ICDD. International Centre for Diffraction Data. Newtown Square, Pennsylvania, USA ().Google Scholar
IUSS Working Group WRB., World Reference Base for Soil Resources 2014, update 2015. International soil classification system for naming soils and creating legends for soil maps World Soil Resources Reports No. 106 2015 Rome FAO.Google Scholar
Lessovaia, S.N. Goryachkin, S.V. Desyatkin, R.V. and Okoneshnikova, M.V., 2013 Pedoweathering and mineralogical change in Cryosols in an ultracontinental climate (Central Yakutia, Russia) Acta Geodynamica et Geomaterialia 10 465473.CrossRefGoogle Scholar
Lessovaia, S. Dultz, S. Goryachkin, S. Plötze, M. Polekhovsky, Y.u. Andreeva, N. and Filimonov, A., 2014 Mineralogy and pore space characteristics of traprocks from Central Siberia, Russia: Prerequisite of weathering trends and soil formation Applied Clay Science 102 186195.CrossRefGoogle Scholar
Lessovaia, S. Dultz, S. Plötze, M. Andreeva, N. Polekhovsky, Y.u. Filimonov, A. and Momotova, O., 2016 Soil development on basic and ultrabasic rocks in cold environments of Russia traced by mineralogical composition and pore space characteristics Catena 137 596604.CrossRefGoogle Scholar
Lesovaya, S.N. Goryachkin, S.V. Pogozhev, E.Y.u. Polekhovskii, Y.u.S. Zavarzin, A.A. and Zavarzina, A.G., 2008 Soils on hard rocks in the northwest of Russia: chemical and mineralogical properties, genesis, and classification problems Eurasian Soil Science 41 363376.CrossRefGoogle Scholar
Meunier, A., 2005 Clays Berlin, Germany Springer.Google Scholar
Meunier, A. and Velde, B., 1979 Weathering mineral facies in altered granites: the importance of local small-scale equilibria Mineralogical Magazine 43 261268.CrossRefGoogle Scholar
Meunier, A. Sardini, P. Robinet, J.C. and Prêt, D., 2007 The petrography of weathering processes: facts and outlooks Clay Minerals 42 415435.CrossRefGoogle Scholar
Moore, D.M. and Reynolds, R.C., 1997 X-ray Diffraction and the Identification and Analysis of Clay Minerals New York Oxford University Press.Google Scholar
Nesbitt, H.W. and Wilson, R.E., 1992 Recent chemical weathering of basalts American Journal of Science 292 740777.CrossRefGoogle Scholar
Pokrovsky, O.S. Schott, J. Kudryavtzev, D.I. and Dupre, B., 2005 Basalt weathering in Central Siberia under permafrost conditions Geochimica et Cosmochimica Acta 69 56595680.CrossRefGoogle Scholar
Ross, P.-S. Peate, I. Ukstins, McClintock, M.K. Xu, Y.G. Skilling, I.P. White, J.D.L. and Houghton, B.F., 2005 Mafic volcaniclastic deposits in flood basalt provinces: a review Journal of Volcanology and Geothermal Research 145 281314.CrossRefGoogle Scholar
Schnoor, J.L., Stumm, W., 1990 Kinetics of chemical weathering: a comparison of laboratory and field weathering rates Aquatic Chemical Kinetics: Reaction Rates of Processes in Natural Waters Chichester, UK J. Wiley & Sons 475504.Google Scholar
Simas, F.N.B. Schaefer, CEGR Melo, V.F. Guerra, M.B.B. Saunders, M. and Gilkes, R.J., 2006 Clay-sized minerals in permafrost-affected soils (Cryosols) from King George Island, Antarctica Clays and Clay Minerals 54 721736.CrossRefGoogle Scholar
Sokolov, I.A. and Gradusov, B.P., 1978 Pochvoobrazovanie i vyvetrivanie na osnovnych porodach v usloviyach gumidnogo klimta Pochvovedenie 2 517 (Soil formation and weathering on basic rocks in conditions of cold humid climate).Google Scholar
Stoops, G., 2003 Guidelines for Analysis and Description of Soil and Regolith Thin Sections Madison, Wisconsin, USA Soil Science Society of America..Google Scholar
Stoops, G., 2007 Micromorphology of soils derived from volcanic ash in Europe: A review and synthesis European Journal of Soil Science 58 356377.CrossRefGoogle Scholar
Stoops, G. Marcelino, V. and Mees, F. e., 2010 Interpretation of Micromorphological Features of Soils and Regoliths Amsterdam Elsevier.Google Scholar
Thorn, C.E. Darmody, R.G. and Dixon, J.C., 2011 Rethinking weathering and pedogenesis in alpine periglacial regions: some Scandinavian evidence Geological Society, London, Special Publications 354 183193.CrossRefGoogle Scholar
Velde, B. and Meunier, A., 2008 The Origin of Clay Minerals in Soils and Weathered Rocks Berlin, Heidelberg, New York Springer-Verlag.CrossRefGoogle Scholar
Wahrhaftig, C., 1965 Stepped topography of the southern Sierra Nevada, California Geological Society of America Bulletin 76 11651190.CrossRefGoogle Scholar
Whitney, D.L. and Evans, B.W., 2010 Abbreviations for names of rock-forming minerals American Mineralogist 95 185187.CrossRefGoogle Scholar
Wilson, M.J. Jones, D., Wilson, R.C.L., 1983 Lichen weathering of minerals: implication for pedogenesis Residual Deposits: Surface Related Weathering Processes and Material Blackwell, London Geological Society 212.Google Scholar