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New LA-ICP-MS cryocell and calibration technique for sub-millimeter analysis of ice cores

  • Sharon B. Sneed (a1) (a2), Paul A. Mayewski (a1) (a2), W.G. Sayre (a1), Michael J. Handley (a1), Andrei V. Kurbatov (a1) (a2), Kendrick C. Taylor (a3), Pascal Bohleber (a1) (a4), Dietmar Wagenbach (a4), Tobias Erhardt (a5) and Nicole E. Spaulding (a1)...
Abstract

Ice cores provide a robust reconstruction of past climate. However, development of timescales by annual-layer counting, essential to detailed climate reconstruction and interpretation, on ice cores collected at low-accumulation sites or in regions of compressed ice, is problematic due to closely spaced layers. Ice-core analysis by laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) provides sub-millimeter-scale sampling resolution (on the order of 100 μm in this study) and the low detection limits (ng L−1) necessary to measure the chemical constituents preserved in ice cores. We present a newly developed cryocell that can hold a 1 m long section of ice core, and an alternative strategy for calibration. Using ice-core samples from central Greenland, we demonstrate the repeatability of multiple ablation passes, highlight the improved sampling resolution, verify the calibration technique and identify annual layers in the chemical profile in a deep section of an ice core where annual layers have not previously been identified using chemistry. In addition, using sections of cores from the Swiss/Italian Alps we illustrate the relationship between Ca, Na and Fe and particle concentration and conductivity, and validate the LA-ICP-MS Ca profile through a direct comparison with continuous flow analysis results.

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Copyright
Copyright © International Glaciological Society 2015 This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Corresponding author
Correspondence: Sharon B. Sneed <sharon.sneed@maine.edu>
References
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Alley, RB and 11 others (1997) Visual-stratigraphic dating of the GISP2 ice core: basis, reproducibility, and application. J. Geophys. Res., 102(C12), 26 36726 382 (doi: 10.1029/96JC03837)
Bigler, M, Svensson, A, Kettner, E, Vallelonga, P, Nielsen, ME and Steffensen, JP (2011) Optimization of high-resolution continuous flow analysis for transient climate signals in ice cores. Environ. Sci. Technol., 45(10), 44834489 (doi: 10.1021/es200118j)
De Angelis, M, Steffensen, JP, Legrand, M, Clausen, H and Hammer, C (1997) Primary aerosol (sea salt and soil dust) deposited in Greenland ice during the last climatic cycle: comparison with East Antarctic records. J. Geophys. Res., 102(C12), 26 68126 698 (doi: 10.1029/97JC01298)
Gray, AL (1985) Solid sample introduction by laser ablation for inductively coupled plasma source mass spectrometry. Analyst, 110(5), 551556 (doi: 10.1039/AN9851000551)
Guillong, M, Horn, I and Günther, D (2003) A comparison of 266 nm, 213 nm and 193 nm produced from a single solid state Nd: YAG laser for laser ablation ICP-MS. J. Anal. Atom. Spectrom., 18(10), 12241230 (doi: 10.1039/B305434A)
Hamilton, WL and Langway, CC Jr (1967) A correlation of microparticle concentrations with oxygen isotope ratios in 700 year old Greenland ice. Earth Planet. Sci. Lett., 3, 363366 (doi: 10.1016/0012-821X(67)90062-3)
Hammer, CU, Clausen, HB and Dansgaard, W (1981) Past volcanism and climate revealed by Greenland ice cores. J. Volcan. Geotherm. Res., 11(1), 310 (doi: 10.1016/0377-0273(81)90071-8)
Kaspari, S and 6 others (2004) Climate variability in West Antarctica derived from annual accumulation-rate records from ITASE firn/ice cores. Ann. Glaciol., 39, 585594 (doi: 10.3189/172756404781814447)
Kaufmann, PR and 7 others (2008) An improved continuous flow analysis system for high-resolution field measurements on ice cores. Environ. Sci. Technol., 42(21), 80448050 (doi: 10.1021/es8007722)
Laj, P and 7 others (1997) Distribution of Ca, Fe, K, and S between soluble and insoluble material in the Greenland Ice Core Project ice core. J. Geophys. Res., 102(C12), 26 61526 623 (doi: 10.1029/96JC02660)
Longerich, H (2008) Laser ablation–inductively coupled plasma– mass spectrometry (LA–ICP–MS); an introduction. In Sylvester, P ed. Laser ablation ICP-MS in the earth sciences: current practices and outstanding issues. (Short Course Series 40) Mineralogical Association of Canada, Vancouver, BC, 118
Mayewski, PA and 6 others (1997) Major features and forcing of high-latitude Northern Hemisphere atmospheric circulation using a 110,000-year-long glaciochemical series. J. Geophys. Res., 102(C12), 26 34526 366 (doi: 10.1029/96JC03365)
Meese, DA and 8 others (1994) The accumulation record from the GISP2 core as an indicator of climate change throughout the Holocene. Science, 266(5191), 16801682 (doi: 10.1126/science.266.5191.1680)
Meese, DA and 8 others (1997) The Greenland Ice Sheet Project 2 depth–age scale: methods and results. J. Geophys. Res., 102(C12), 26 41126 423 (doi: 10.1029/97JC00269)
Miller, JC (1993) A brief history of laser ablation. AIP Conf. Proc., 288, 619622 (doi: 10.1063/1.44865)
Müller, W, Shelley, M, Miller, P and Broude, S (2009) Initial performance metrics of a new custom-designed ArF excimer LA-ICPMS system coupled to a two-volume laser-ablation cell. J. Anal. Atom. Spectrom., 24(2), 209214 (doi: 10.1039/B805995K)
Müller, W, Shelley, JMG and Rasmussen, SO (2011) Direct chemical analysis of frozen ice cores by UV-laser ablation ICPMS.J. Anal. Atomic Spectrom., 26(12), 23912395 (doi: 10.1039/C1JA10242G)
O’Dwyer, J and 7 others (2000) Methanesulfonic acid in a Svalbard ice core as an indicator of ocean climate. Geophys. Res. Lett., 27(8), 11591162 (doi: 10.1029/1999GL011106)
Osterberg, EC, Handley, MJ, Sneed, SB, Mayewski, PA and Kreutz, KJ (2006) Continuous ice core melter system with discrete sampling for major ion, trace element, and stable isotope analyses. Environ. Sci. Technol., 40(10), 33553361 (doi: 10.1021/es052536w)
Ram, M, Illing, M, Weber, P, Koenig, G and Kaplan, M (1995) Polar ice stratigraphy from laser-light scattering: scattering from ice. Geophys. Res. Lett., 22(24), 35253527 (doi: 10.1029/95GL03270)
Reinhardt, H and 6 others (2001) Laser ablation inductively coupled plasma mass spectrometry: a new tool for trace element analysis in ice cores. Fresenius’ J. Anal. Chem., 370(5), 629636 (doi: 10.1007/s002160100853)
Reinhardt, H, Kriews, M, Miller, H, Lüdke, C, Hoffmann, E and Skole, J (2003) Application of LA–ICP–MS in polar ice core studies. Anal. Bioanal. Chem., 375(8), 12651275 (doi: 10.1007/s00216-003-1793-5)
Röthlisberger, R and 6 others (2000) Technique for continuous high-resolution analysis of trace substances in firn and ice cores. Environ. Sci. Technol., 34(2), 338342 (doi: 10.1021/es9907055)
Russo, RE, Mao, X, Liu, H, Gonzalez, J and Mao, SS (2002) Laser ablation in analytical chemistry – a review. Talanta, 57(3), 425451 (doi: 10.1016/S0039-9140(02)00053-X)
Ruth, U, Wagenbach, D, Bigler, M, Steffensen, JP, Röthlisberger, R and Miller, H (2002) High-resolution microparticle profiles at NorthGRIP, Greenland: case studies of the calcium–dust relationship. Ann. Glaciol., 35, 237242 (doi: 10.3189/172756402781817347)
Tadano, J, Kumakura, H and Ito, Y (2004) Coupling of focused laser pulse to surfaces of transparent materials studied by time-resolved imaging technique. Appl. Phys. A., 79(4–6), 10311033 (doi: 10.1007/s00339-004-2621-2)
Taylor, K and 6 others (1992) Ice-core dating and chemistry by direct-current electrical conductivity. J. Glaciol., 38(130), 325332
Taylor, KC and 9 others (1993) Electrical conductivity measurements from the GISP2 and GRIP Greenland ice cores. Nature, 366(6455), 549552 (doi: 10.1038/366549a0)
Taylor, KC, Alley, RB, Lamorey, GW and Mayewski, PA (1997) Electrical measurements on the Greenland Ice Sheet Project 2 core. J. Geophys. Res., 102(C12), 26 51126 517 (doi: 10.1029/96JC02500)
Wagenbach, D, Münnich, KO, Schotterer, U and Oeschger, H (1988) The anthropogenic impact on snow chemistry at Colle Gnifetti, Swiss Alps. Ann. Glaciol., 10, 183187
Warren, SG and Brandt, RE (2008) Optical constants of ice from the ultraviolet to the microwave: a revised compilation. J. Geophys. Res., 113(D14), D14220 (doi: 10.1029/2007JD009744)
Zielinski, GA, Mayewski, PA, Meeker, LD, Whitlow, SI and Twickler, MS (1996) 110,000-yr record of explosive volcanism from the GISP2 (Greenland) ice core. Quat. Res., 45(2), 109118 (doi: 10.1006/qres.1996.0013)
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