Hostname: page-component-8448b6f56d-xtgtn Total loading time: 0 Render date: 2024-04-24T12:26:14.359Z Has data issue: false hasContentIssue false
  • English
  • Français

A Combined Experimental and Theoretical Study of Lithiation Mechanism in ZnFe2O4 Anode Materials

Published online by Cambridge University Press:  20 March 2018

Lei Wang ,
Alison McCarthy ,
Kenneth J. Takeuchi ,
Esther S. Takeuchi  and
Amy C. Marschilok
Lei Wang
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Alison McCarthy
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794
Kenneth J. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794
Esther S. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, NY11973
Amy C. Marschilok*
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, NY11973
*
*corresponding author: amy.marschilok@stonybrook.edu.
Get access

Abstract

ZnFe2O4 (ZFO) represents a promising anode material for lithium ion batteries, but there is still a lack of deep understanding of the fundamental reduction mechanism associated with this material. In this paper, the complete visualization of reduction/oxidation products irrespective of their crystallinity was achieved experimentally through a compilation of in situ X-ray diffraction, synchrotron based powder diffraction, and ex-situ X-ray absorption fine structure data. Complementary theoretical modelling study further shed light upon the fundamental understanding of the lithiation mechanism, especially at the early stage from ZnFe2O4 up to LixZnFe2O4 (x = 2).

Keywords

ZnFeenergy storage
Type
Articles
Information
MRS Advances , Volume 3 , Issue 14: Nanomaterials , 2018 , pp. 773 - 778
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

ŧ

Equivalent contributions.

References

REFERENCES:

Guo, H., Zhang, Y., Marschilok, A. C., Takeuchi, K. J., Takeuchi, E. S. and Liu, P., Phys. Chem. Chem. Phys. 19 (38), 26322–26329 (2017).CrossRefGoogle Scholar
NuLi, Y. N., Chu, Y. Q. and Qin, Q. Z., J. Electrochem. Soc. 151 (7), A1077–A1083 (2004).CrossRefGoogle Scholar
Guo, X. W., Lu, X., Fang, X. P., Mao, Y., Wang, Z. X., Chen, L. Q., Xu, X. X., Yang, H. and Liu, Y. N., Electrochem. Commun. 12 (6), 847–850 (2010).CrossRefGoogle Scholar
Sharma, Y., Sharma, N., Rao, G. V. S. and Chowdari, B. V. R., Electrochim. Acta 53 (5), 2380–2385 (2008).CrossRefGoogle Scholar
Xing, Z., Ju, Z. C., Yang, J., Xu, H. Y. and Qian, Y. T., Nano Res. 5 (7), 477–485 (2012).CrossRefGoogle Scholar
Kresse, G. and Furthmuller, J., Comput. Mater. Sci. 6 (1), 15–50 (1996).CrossRefGoogle Scholar
Blochl, P. E., Phys. Rev. B 50 (24), 17953–17979 (1994).CrossRefGoogle Scholar
Perdew, J. P., Burke, K. and Ernzerhof, M., Phys. Rev. Lett. 77 (18), 3865–3868 (1996).CrossRefGoogle Scholar
Zhang, Y., Pelliccione, C. J., Brady, A. B., Guo, H., Smith, P. F., Liu, P., Marschilok, A. C., Takeuchi, K. J. and Takeuchi, E. S., Chem. Mater. 29 (10), 4282–4292 (2017).CrossRefGoogle Scholar