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Degradation of allura red dye using Fe-Zn metal nanoparticles obtained by phytosynthesis method.

Published online by Cambridge University Press:  27 October 2020

José Angel Sanjurjo-García ,
Sonia Martínez-Gallegos Open the ORCID record for Sonia Martínez-Gallegos [Opens in a new window] ,
Pablo Samuel Schabes-Retchkiman  and
José Luis García-Rivas
José Angel Sanjurjo-García
Affiliation:
Departamento de Materia Condensada. Instituto de Física, Universidad Nacional Autónoma de México, Cd de México, C.P. 04510, México. Tecnológico Nacional de México/ Instituto Tecnológico de Toluca/ División de Estudios de Posgrado e Investigación, Instituto Tecnológico de Toluca. Av. Tecnológico S/N Col Agrícola Bellavista, Metepec, México, C.P. 52149.
Sonia Martínez-Gallegos
Affiliation:
Tecnológico Nacional de México/ Instituto Tecnológico de Toluca/ División de Estudios de Posgrado e Investigación, Instituto Tecnológico de Toluca. Av. Tecnológico S/N Col Agrícola Bellavista, Metepec, México, C.P. 52149.
Pablo Samuel Schabes-Retchkiman
Affiliation:
Departamento de Materia Condensada. Instituto de Física, Universidad Nacional Autónoma de México, Cd de México, C.P. 04510, México.
José Luis García-Rivas
Affiliation:
Tecnológico Nacional de México/ Instituto Tecnológico de Toluca/ División de Estudios de Posgrado e Investigación, Instituto Tecnológico de Toluca. Av. Tecnológico S/N Col Agrícola Bellavista, Metepec, México, C.P. 52149.
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Abstract

In the present work, the photocatalytic activity of metal Fe-Zn nanoparticles was evaluated through the degradation of the synthetic AZO colorant allura red. A Phytosynthesis method developed here takes advantage for the first time of the plant extract of Hydrocotyle ranunculoides as the reducing agent. A fitted Folin-Ciocalteu assay showed about 40% of total polyphenolic compounds used in the nanoparticles generation. UV-Vis and TEM analysis allowed identification of the nanoparticles as oxides of Fe and Zn. Finally, during measurement of the photocatalytic activity a load of 0.5 g/L was applied on a 15 μM solution of allura red as standard model pollutant, while environmental oxygen was used as the initiating agent. Tests showed a 66% degradation of the azo-type dye obeying a degradation kinetics of the first order after short times.

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Articles
Information
MRS Advances , Volume 5 , Issue 62: International Materials Research Congress XXIX , 2020 , pp. 3283 - 3291
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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